Article(id=1242757053907842025, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1242757048333611957, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2021.12.004, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=1609516800000, receivedDateStr=2021-01-02, revisedDate=1613750400000, revisedDateStr=2021-02-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1774225970961, onlineDateStr=2026-03-23, pubDate=1639929600000, pubDateStr=2021-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1774225970961, onlineIssueDateStr=2026-03-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774225970961, creator=13701087609, updateTime=1774225970961, updator=13701087609, issue=Issue{id=1242757048333611957, tenantId=1146029695717560320, journalId=1149653034449285133, year='2021', volume='54', issue='12', pageStart='1', pageEnd='114', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1774225969632, creator=13701087609, updateTime=1774226074518, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1242757488324494073, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1242757048333611957, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1242757488324494074, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1242757048333611957, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=22, endPage=27, ext={EN=ArticleExt(id=1242757054402769903, articleId=1242757053907842025, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=Effect of Kilchoanite on Ceramization Properties of Ceramizable Silicone Rubber, columnId=1190369066675179686, journalTitle=Insulating Materials, columnName=Material Research, runingTitle=null, highlight=null, articleAbstract=
Ceramizable silicone rubber composites were prepared by using kilchoanite as ceramic filler, glass frit as flux, and nano silica as reinforcing agent. The effect of the content and size of kilchoanite on the tensile properties of the composites was studied. The ceramic specimens were obtained by sintering the composites at 1 000℃, and then the microstructure of its fracture surface was observed. The phase change of ceramic specimens was analyzed by X-ray diffraction, and its linear contraction and flexural strength were measured. The results show that the increase of the kilchoanite with the same particle size can reduce the tensile strength of the composites, while increase the elongation at break. Under the same content, the kilchoanite with a smaller size can improve the tensile strength of the composites. When the content of kilchoanite is too high or too low, the flexural strength and density of the ceramic specimens decrease. With the decrease of the size of kilchoanite, the flexural strength of the ceramic specimens increases, while the linear contraction also increases. The maximum flexural strength of the ceramic specimens can reach to 58.57 MPa by changing the content and size of kilchoanite.
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以斜方硅钙石为成瓷填料,低熔点玻璃粉为助熔剂,纳米二氧化硅(SiO2)为补强剂,制备了陶瓷化硅橡胶复合材料,研究了斜方硅钙石的含量和粒径对复合材料拉伸性能的影响。将复合材料在1 000℃烧结得到陶瓷试样,并观察陶瓷试样断面的显微结构,通过XRD分析了烧结后陶瓷试样的晶相变化,测量了陶瓷试样的线性收缩率和弯曲强度。结果表明:同一粒径的斜方硅钙石含量的增加会降低复合材料的拉伸强度同时提高断裂伸长率,同一含量下小粒径的斜方硅钙石有利于提高复合材料的拉伸强度。斜方硅钙石的含量过多或过少都会降低烧结后陶瓷试样的弯曲强度和致密度,而减小斜方硅钙石的粒径有利于提高陶瓷试样的弯曲强度,但同时也会增大线性收缩率。通过调整斜方硅钙石的含量和粒径,陶瓷试样的弯曲强度最高可达58.57 MPa。
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金海云(1971-),男(汉族),陕西西安人,教授,主要从事绝缘结构、电气材料、陶瓷材料和超疏水材料方面的研究。
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李鹏虎(1993-),男(汉族),陕西咸阳人,博士生,主要从事绝缘材料的性能以及陶瓷化硅橡胶的相关研究。
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1西安交通大学 电力设备电气绝缘国家重点实验室,陕西 西安 710049, bio={"content":"
李鹏虎(1993-),男(汉族),陕西咸阳人,博士生,主要从事绝缘材料的性能以及陶瓷化硅橡胶的相关研究。
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Effect of kilchoanite content on tensile properties of composites, figureFileSmall=H0K+pMTit9aCVtmbTgjZpQ==, figureFileBig=Myn46Et/kLk1AEDFlfApcQ==, tableContent=null), ArticleFig(id=1245106602110468876, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图1, caption=
斜方硅钙石含量对复合材料拉伸性能的影响, figureFileSmall=H0K+pMTit9aCVtmbTgjZpQ==, figureFileBig=Myn46Et/kLk1AEDFlfApcQ==, tableContent=null), ArticleFig(id=1245106602236298001, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=EN, label=Fig.2, caption=
Microstructures of ceramic specimens with different content of kilchoanite, figureFileSmall=HFtO2U0BDPqvop2fDzzltg==, figureFileBig=wLeUt2gMVm2rb7kHeETfuw==, tableContent=null), ArticleFig(id=1245106602374710039, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图2, caption=
不同斜方硅钙石含量的陶瓷试样的显微形貌照片, figureFileSmall=HFtO2U0BDPqvop2fDzzltg==, figureFileBig=wLeUt2gMVm2rb7kHeETfuw==, tableContent=null), ArticleFig(id=1245106602513122076, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=EN, label=Fig.3, caption=
XRD patterns of ceramic specimens with different content of kilchoanite, figureFileSmall=0ddKysoTXqID2hkxtOnUVg==, figureFileBig=lZtB6z9ojl/leRC283i5Hw==, tableContent=null), ArticleFig(id=1245106602601202465, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图3, caption=
不同斜方硅钙石含量的陶瓷试样的XRD谱图, figureFileSmall=0ddKysoTXqID2hkxtOnUVg==, figureFileBig=lZtB6z9ojl/leRC283i5Hw==, tableContent=null), ArticleFig(id=1245106602689282854, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=EN, label=Fig.4, caption=
Effect of kilchoanite content on ceramization properties of ceramic specimens, figureFileSmall=6Iihms8GoBvH5SvZzAmXnw==, figureFileBig=WOVtr9Z+Vg1gmcncf9o10g==, tableContent=null), ArticleFig(id=1245106602789946154, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图4, caption=
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Effect of kilchoanite size on tensile strength of composites, figureFileSmall=v5PRYUJOt7tVbPDgMwMkCw==, figureFileBig=m/2ynSg6Q6tNOieUQLqjRg==, tableContent=null), ArticleFig(id=1245106602982884149, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图5, caption=
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Effect of kilchoanite size on ceramization properties of ceramic specimens, figureFileSmall=dGr+AQHmE0g2vVP3FYXi5Q==, figureFileBig=L4HGGyfNXVNSTHNCahTuYg==, tableContent=null), ArticleFig(id=1245106603150656315, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=CN, label=图6, caption=
斜方硅钙石粒径对陶瓷试样成瓷性能的影响, figureFileSmall=dGr+AQHmE0g2vVP3FYXi5Q==, figureFileBig=L4HGGyfNXVNSTHNCahTuYg==, tableContent=null), ArticleFig(id=1245106603259708223, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1242757053907842025, language=EN, label=Tab.1, caption=
Formulation of the ceramizable silicone rubber, figureFileSmall=null, figureFileBig=null, tableContent=
| 组分 | 含量/g |
|---|
| 硅橡胶 | 100 |
| 羟基硅油 | 3 |
| 纳米SiO2 | 30 |
| 斜方硅钙石 | x |
| 玻璃粉 | 30 |
| DCBP | 1.5 |
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陶瓷化硅橡胶的配方
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| 组分 | 含量/g |
|---|
| 硅橡胶 | 100 |
| 羟基硅油 | 3 |
| 纳米SiO2 | 30 |
| 斜方硅钙石 | x |
| 玻璃粉 | 30 |
| DCBP | 1.5 |
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Properties of ceramic specimens sintered at different temperatures, figureFileSmall=null, figureFileBig=null, tableContent=
| 烧结温度/℃ | 线性收缩率/% | 弯曲强度/MPa |
|---|
| 600 | 8.75 | 4.06 |
| 700 | 15.00 | 24.84 |
| 800 | 21.25 | 46.76 |
| 900 | 22.50 | 50.55 |
| 1 000 | 23.75 | 54.56 |
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不同烧结温度下陶瓷试样的性能
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| 烧结温度/℃ | 线性收缩率/% | 弯曲强度/MPa |
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| 600 | 8.75 | 4.06 |
| 700 | 15.00 | 24.84 |
| 800 | 21.25 | 46.76 |
| 900 | 22.50 | 50.55 |
| 1 000 | 23.75 | 54.56 |
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