Article(id=1297161266146075462, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, articleNumber=null, orderNo=null, doi=10.13550/j.jxhg.20250248, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1744214400000, receivedDateStr=2025-04-10, revisedDate=null, revisedDateStr=null, acceptedDate=1745769600000, acceptedDateStr=2025-04-28, onlineDate=1787196945939, onlineDateStr=2026-08-20, pubDate=1778774400000, pubDateStr=2026-05-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1787196945939, onlineIssueDateStr=2026-08-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1787196945939, creator=13701087609, updateTime=1787196945939, updator=13701087609, issue=Issue{id=1297161216049308076, tenantId=1146029695717560320, journalId=1296125381406982186, year='2026', volume='43', issue='5', pageStart='929', pageEnd='1184', issueExtLink='null', onlineDate='null', pubDate='1778774400000', pubDateStr='2026-05-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1787196933996, creator='13701087609', updateTime=1787202244949, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1297183491922354645, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1297183491922354646, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1087, endPage=1095, ext={EN=ArticleExt(id=1297161266330624839, articleId=1297161266146075462, tenantId=1146029695717560320, journalId=1296125381406982186, language=EN, title=Enzyme-inspired dye-incorporated iron-porphyrin metal organic framework for photocatalytic reduction of nitroarenes, columnId=null, journalTitle=Fine Chemicals, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Inspired by nitroreductase and the electron transfer process of its metabolite nitroaromatic or nitroheterocyclic compounds, dye 2,7-dichlorofluorescein, which was ring-opened through solvent-assisted ligand incorporation to form carboxylic acid ligand groups, was loaded into the channels of iron-porphyrin metal-organic framework PCN-222(Fe) for synthesis of DCF@PCN-222(Fe). The DCF@PCN-222(Fe) was characterized by ¹HNMR, XRD, SEM, EDX, UV-Vis, fluorescence spectrometer and XPS, and evaluated for its electrochemical properties via cyclic voltammetry (CV). With DCF@PCN-222(Fe) photo-catalyzing nitrobenzene reduction to aniline as a model reaction, the reaction conditions were optimized, the nitroaromatic hydrocarbon substrate was expanded and the cycling stability of the catalyst was evaluated. The results showed that DCF@PCN-222(Fe) still maintained the PCN-222(Fe) parent framework with a molar ratio of DCF to iron porphyrin ligand 1.6∶1, with its formula speculated as C₈₀H_46.4Cl_4.2FeN₄O_22.4Zr₃ and a relative molecular mass of 1878.47. DCF@PCN-222(Fe) exhibited UV-Vis absorption and fluorescence emission peaks at the same positions as DCF (532 and 556 nm, respectively), indicating electron transfer within the framework which can simulate the electron transfer process of nitroreductase. Under light irradiation, excited DCF transferred electrons to the iron-porphyrin center, from which the generated low-valent iron center transferred electrons to other electron acceptors, enabling the efficient reduction of nitrobenzene substrates. Under the optimal reaction conditions of room temperature, with 532 nm LED as light source, 2.5 μmol DCF@PCN-222(Fe) as photocatalyst, 1 mL methanol as solvent, catalytic reduction of 0.1 mmol nitrobenzene for 2 h, the aniline yield was 82% and reduced to 77% when the catalyst was used continuously for three times. Under the optimum reaction conditions, the reduction of nitrobenzene substrates with different para substituents catalyzed by DCF@PCN-222(Fe) showed yields from 64% to 91%.

, authors=Yang AN¹, Xu ZHANG¹, Renhai LIU¹, Yusheng SHI², Chunying DUAN³, Tiexin ZHANG^{1, *}, authorsList=Yang AN, Xu ZHANG, Renhai LIU, Yusheng SHI, Chunying DUAN, Tiexin ZHANG, authorCompany=null, correspAuthors=Tiexin ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1297161266712306505, articleId=1297161266146075462, tenantId=1146029695717560320, journalId=1296125381406982186, language=CN, title=酶启发2,7-二氯荧光素修饰铁卟啉金属有机框架的制备及光催化硝基芳烃还原, columnId=1297161266410316616, journalTitle=精细化工, columnName=催化与分离提纯技术, runingTitle=null, highlight=null, articleAbstract=

受硝基还原酶启发，模拟其代谢硝基芳香或者硝基杂环化合物的电子传递过程，通过溶剂辅助配体交换促使染料分子2,7-二氯荧光素（DCF）的内酯开环，并将暴露出来的羧酸基团配位负载于铁卟啉金属有机框架（MOFs）PCN-222(Fe)的锆氧簇节点上，设计、制备了基于MOFs的光催化材料DCF@PCN-222(Fe)。采用¹HNMR、XRD、SEM、EDX、UV-Vis、荧光光谱仪、XPS对DCF@PCN-222(Fe)进行了表征。通过循环伏安（CV）测试了DCF@PCN-222(Fe)的电化学性能。以DCF@PCN-222(Fe)光催化硝基苯还原制备苯胺为模型反应，优化了反应条件，拓展硝基芳烃底物，考察了催化剂的循环稳定性。结果表明，DCF@PCN-222(Fe)仍保持PCN-222(Fe)母体框架结构，其内部DCF与铁卟啉配体的物质的量比为1.6∶1，推测其化学式为C₈₀H_46.4Cl_4.2FeN₄O_22.4Zr₃，相对分子质量1878.47。DCF@PCN-222(Fe)具有与DCF相同的最大紫外吸收峰（532 nm）和荧光发射峰（556 nm），其存在框架内电子转移，可模拟硝基还原酶的电子传递过程，光照下，DCF将电子传递给铁卟啉中心，生成的低价铁中心在厌氧条件下可将电子传递给硝基苯电子受体。DCF@PCN-222(Fe)光催化硝基苯制备苯胺最佳反应条件为：室温下以532 nm LED为光源、2.5 μmol DCF@PCN-222(Fe)为光催化剂、1 mL甲醇为溶剂、催化还原0.1 mmol硝基苯、反应时间2 h。在该条件下，苯胺产率为82%。催化剂连续使用3次后，苯胺产率降为77%。在最优反应条件下，DCF@PCN-222(Fe)催化含有不同对位取代基的硝基苯底物的还原，产物产率64%~91%。

, authors=安洋¹, 张旭¹, 刘壬海¹, 史雨生², 段春迎³, 张铁欣^{1, *}, authorsList=安洋, 张旭, 刘壬海, 史雨生, 段春迎, 张铁欣, authorCompany=null, correspAuthors=张铁欣, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=7bB3BJ8jQYG3VSQQbfPKyw==, magXml=yGSzIhK6CMOKUc8ExO70nw==, pdfUrl=null, pdf=jl92nLvrtgNBRTxSrui3SQ==, pdfFileSize=2479027, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=pOgrhVIKkI6NI+bNY+ognQ==, mapNumber=null, fund=null)}, authors=[Author(id=1297161267244983124, tenantId=1146029695717560320, journalId=1296125381406982186, articleId=1297161266146075462, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=1939400757@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1297161267324674902, tenantId=1146029695717560320, journalId=1296125381406982186, articleId=1297161266146075462, authorId=1297161267244983124, language=EN, stringName=Yang AN, firstName=Yang, middleName=null, lastName=AN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1297161267395978071, tenantId=1146029695717560320, journalId=1296125381406982186, articleId=1297161266146075462, authorId=1297161267244983124, language=CN, stringName=安洋, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1．大连理工大学 精细化工国家重点实验室，辽宁 大连　116024, bio={"content":"

安洋（1992—），男，博士生，E-mail: 1939400757@qq.com。

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安洋（1992—），男，博士生，E-mail: 1939400757@qq.com。

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