Article(id=1297161233992540755, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, articleNumber=null, orderNo=null, doi=10.13550/j.jxhg.20250257, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1744387200000, receivedDateStr=2025-04-12, revisedDate=null, revisedDateStr=null, acceptedDate=1748966400000, acceptedDateStr=2025-06-04, onlineDate=1787196938274, onlineDateStr=2026-08-20, pubDate=1778774400000, pubDateStr=2026-05-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1787196938274, onlineIssueDateStr=2026-08-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1787196938274, creator=13701087609, updateTime=1787196938274, updator=13701087609, issue=Issue{id=1297161216049308076, tenantId=1146029695717560320, journalId=1296125381406982186, year='2026', volume='43', issue='5', pageStart='929', pageEnd='1184', issueExtLink='null', onlineDate='null', pubDate='1778774400000', pubDateStr='2026-05-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1787196933996, creator='13701087609', updateTime=1787202244949, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1297183491922354645, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1297183491922354646, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=998, endPage=1007, ext={EN=ArticleExt(id=1297161234193867348, articleId=1297161233992540755, tenantId=1146029695717560320, journalId=1296125381406982186, language=EN, title=Preparation of coal gangue-based water retention agent for improving saline-alkali soil, columnId=null, journalTitle=Fine Chemicals, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Coal gangue-based water-retaining agent (CG-WRG) was prepared using coal gangue-based humic acid (CG-HA), sodium carboxymethyl cellulose (CMC-Na), sodium alginate (SA), and acrylic acid (AA) as raw materials, potassium persulfate (KPS) as initiator, and N,N'-methylenebisacrylamide (MBA) as crosslinking agent, and then characterized by FTIR and SEM. The influence of KPS dosage, MBA dosage, neutralization degree of AA and m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA) on the water absorbency and water retention of CG-WRG was evaluated through single-factor experiments, followed by exploration on the environmental adaptability of CG-WRG under different environmental conditions (temperature, pH, type and mass concentration of metal cations). The water and fertilizer retention effects were further studied through leaching experiments and water-fertilizer evaporation experiments in saline-alkali soil. The results showed that under the optimal CG-WRG preparation conditions of KPS dosage 0.25 g, MBA dosage 0.06 g, 65% neutralization AA 9.00 g, and m(AA)∶m(SA)∶m(CMC-Na) ∶m(CG-HA)=9∶1∶1∶1, the water absorbency of CG-WRG reached 370.1 g/g, and the water retention was 94.1 g/g. CG-WRG exhibited good water retention effects at temperatures ranging from 5 to 60 ℃, with a higher water absorbency (228.6 g/g) in the alkaline environment pH=11 than in the acidic environment pH=3 (154.4 g/g). The water retention of saline-alkali soil with 2% CG-WRG (based on the mass of saline-alkali soil)was 55%. After being buried in soil for 16 and 20 d, the degradation of CG-WRG was 10.3% and 15.8%, respectively. When the CG-WRG dosage was increased from 0.05% to 0.20%, the cumulative loss of potassium decreased by 37.1%~58.8%, and the loss of nitrogen decreased by 15.7%~30.4%. When the CG-WRG dosage reached 0.20%, the soil water content increased by 4.67% compared with the control group. When the CG-WRG dosage was 0.05%, the contents of and in the soil reached the maximum (7.935 and 1.529 mg). The seedling germination with CG-WRG addition was 90%, and the average root length was 2.7 cm, higher than that with no CG-WRG, which was 50% and 1.0 cm, respectively. In addition, the germination index of the CG-WRG addition group was 486%.

, authors=Yibo WANG1, 2, Guoping HAN2, Huidong XIE2, *, Lizhen XU1, Shujuan WANG1, *, Jia LIU3, authorsList=Yibo WANG, Guoping HAN, Huidong XIE, Lizhen XU, Shujuan WANG, Jia LIU, authorCompany=null, correspAuthors=Huidong XIE, Shujuan WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1297161235200500317, articleId=1297161233992540755, tenantId=1146029695717560320, journalId=1296125381406982186, language=CN, title=煤矸石源保水剂的制备及改良盐碱土性能, columnId=1297161221933913088, journalTitle=精细化工, columnName=功能材料, runingTitle=null, highlight=null, articleAbstract=

以煤矸石中提取的腐植酸(CG-HA)、羧甲基纤维素钠(CMC-Na)、海藻酸钠(SA)和丙烯酸(AA)为原料,过硫酸钾(KPS)为引发剂,N,N′-亚甲基双丙烯酰胺(MBA)为交联剂,制备了煤矸石源保水剂(CG-WRG)。采用FTIR、SEM对CG-WRG进行了表征,通过单因素实验考察了KPS用量、MBA用量、AA中和度、m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA)对CG-WRG吸水倍率、保水倍率的影响,探究了不同环境条件(温度、pH、金属阳离子类型及质量浓度)对CG-WRG环境适应性的影响,通过其在盐碱土中的淋溶实验和水肥蒸发实验研究了其保水保肥效果。结果表明,CG-WRG的最佳制备条件为KPS用量0.25 g、MBA用量0.06 g、中和度为65%的AA用量9.00 g、m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA)=9∶1∶1∶1,在该条件下制备的CG-WRG吸水倍率可达370.1 g/g,保水倍率为94.1 g/g。CG-WRG在5~60 ℃都具有良好的保水效果,在碱性环境pH=11的吸水倍率(228.6 g/g)高于酸性环境pH=3(154.4 g/g)。CG-WRG用量为2%(以盐碱土质量计)的土壤持水率为55%。埋置在土壤中16和20 d后,CG-WRG的降解率分别为10.3%和15.8%。CG-WRG用量由0.05%增至0.20%时,钾元素5次累积损失量降幅达37.1%~58.8%,氮元素损失量降幅为15.7%~30.4%,且当CG-WRG用量为0.20%时,土壤含水率比空白组同比提升4.67%。当CG-WRG用量为0.05%时,土壤中含量达到最大(7.935和1.529 mg)。添加CG-WRG的幼苗发芽率为90%,平均根长为2.7 cm,发芽指数为486%,而不添加CG-WRG的幼苗发芽率为50%,平均根长为1.0 cm。

, authors=王逸博1, 2, 韩果萍2, 谢会东2, *, 徐立珍1, 王淑娟1, *, 刘嘉3, authorsList=王逸博, 韩果萍, 谢会东, 徐立珍, 王淑娟, 刘嘉, authorCompany=null, correspAuthors=谢会东, 王淑娟, authorNote=

王逸博(1997—),男,硕士生,E-mail:

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谢会东(1973—),男,教授,E-mail:
王淑娟(1972—),女,教授,E-mail:
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煤矸石源保水剂的制备及改良盐碱土性能
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王逸博 1, 2 , 韩果萍 2 , 谢会东 2, * , 徐立珍 1 , 王淑娟 1, * , 刘嘉 3
精细化工 | 功能材料 2026,43(5): 998-1007
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精细化工 |功能材料 2026 , 43 (5) : 998 -1007
煤矸石源保水剂的制备及改良盐碱土性能
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王逸博(1997—),男,硕士生,E-mail:

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王逸博1, 2 , 韩果萍2, 谢会东2, * , 徐立珍1, 王淑娟1, * , 刘嘉3
作者信息
  • 1.清华大学 能源与动力工程系,北京 100084
  • 2.西安建筑科技大学 化学与化工学院,陕西 西安 710055
  • 3.华清农业开发有限公司,北京 100084
通讯作者:
谢会东(1973—),男,教授,E-mail:
王淑娟(1972—),女,教授,E-mail:
作者简介:

王逸博(1997—),男,硕士生,E-mail:

Preparation of coal gangue-based water retention agent for improving saline-alkali soil
Yibo WANG1, 2 , Guoping HAN2, Huidong XIE2, * , Lizhen XU1, Shujuan WANG1, * , Jia LIU3
Affiliations
  • 1.Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
  • 2.School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, Shaanxi, China
  • 3.Tsinghua Agriculture Development Co., Ltd., Beijing 100084, China
出版时间: 2026-05-15 doi: 10.13550/j.jxhg.20250257
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以煤矸石中提取的腐植酸(CG-HA)、羧甲基纤维素钠(CMC-Na)、海藻酸钠(SA)和丙烯酸(AA)为原料,过硫酸钾(KPS)为引发剂,N,N′-亚甲基双丙烯酰胺(MBA)为交联剂,制备了煤矸石源保水剂(CG-WRG)。采用FTIR、SEM对CG-WRG进行了表征,通过单因素实验考察了KPS用量、MBA用量、AA中和度、m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA)对CG-WRG吸水倍率、保水倍率的影响,探究了不同环境条件(温度、pH、金属阳离子类型及质量浓度)对CG-WRG环境适应性的影响,通过其在盐碱土中的淋溶实验和水肥蒸发实验研究了其保水保肥效果。结果表明,CG-WRG的最佳制备条件为KPS用量0.25 g、MBA用量0.06 g、中和度为65%的AA用量9.00 g、m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA)=9∶1∶1∶1,在该条件下制备的CG-WRG吸水倍率可达370.1 g/g,保水倍率为94.1 g/g。CG-WRG在5~60 ℃都具有良好的保水效果,在碱性环境pH=11的吸水倍率(228.6 g/g)高于酸性环境pH=3(154.4 g/g)。CG-WRG用量为2%(以盐碱土质量计)的土壤持水率为55%。埋置在土壤中16和20 d后,CG-WRG的降解率分别为10.3%和15.8%。CG-WRG用量由0.05%增至0.20%时,钾元素5次累积损失量降幅达37.1%~58.8%,氮元素损失量降幅为15.7%~30.4%,且当CG-WRG用量为0.20%时,土壤含水率比空白组同比提升4.67%。当CG-WRG用量为0.05%时,土壤中含量达到最大(7.935和1.529 mg)。添加CG-WRG的幼苗发芽率为90%,平均根长为2.7 cm,发芽指数为486%,而不添加CG-WRG的幼苗发芽率为50%,平均根长为1.0 cm。

保水剂  /  煤矸石  /  盐碱土  /  淋溶  /  以废治废  /  功能材料

Coal gangue-based water-retaining agent (CG-WRG) was prepared using coal gangue-based humic acid (CG-HA), sodium carboxymethyl cellulose (CMC-Na), sodium alginate (SA), and acrylic acid (AA) as raw materials, potassium persulfate (KPS) as initiator, and N,N'-methylenebisacrylamide (MBA) as crosslinking agent, and then characterized by FTIR and SEM. The influence of KPS dosage, MBA dosage, neutralization degree of AA and m(AA)∶m(SA)∶m(CMC-Na)∶m(CG-HA) on the water absorbency and water retention of CG-WRG was evaluated through single-factor experiments, followed by exploration on the environmental adaptability of CG-WRG under different environmental conditions (temperature, pH, type and mass concentration of metal cations). The water and fertilizer retention effects were further studied through leaching experiments and water-fertilizer evaporation experiments in saline-alkali soil. The results showed that under the optimal CG-WRG preparation conditions of KPS dosage 0.25 g, MBA dosage 0.06 g, 65% neutralization AA 9.00 g, and m(AA)∶m(SA)∶m(CMC-Na) ∶m(CG-HA)=9∶1∶1∶1, the water absorbency of CG-WRG reached 370.1 g/g, and the water retention was 94.1 g/g. CG-WRG exhibited good water retention effects at temperatures ranging from 5 to 60 ℃, with a higher water absorbency (228.6 g/g) in the alkaline environment pH=11 than in the acidic environment pH=3 (154.4 g/g). The water retention of saline-alkali soil with 2% CG-WRG (based on the mass of saline-alkali soil)was 55%. After being buried in soil for 16 and 20 d, the degradation of CG-WRG was 10.3% and 15.8%, respectively. When the CG-WRG dosage was increased from 0.05% to 0.20%, the cumulative loss of potassium decreased by 37.1%~58.8%, and the loss of nitrogen decreased by 15.7%~30.4%. When the CG-WRG dosage reached 0.20%, the soil water content increased by 4.67% compared with the control group. When the CG-WRG dosage was 0.05%, the contents of and in the soil reached the maximum (7.935 and 1.529 mg). The seedling germination with CG-WRG addition was 90%, and the average root length was 2.7 cm, higher than that with no CG-WRG, which was 50% and 1.0 cm, respectively. In addition, the germination index of the CG-WRG addition group was 486%.

water retention agents  /  coal gangue  /  saline-alkali soil  /  leaching  /  treating waste with waste  /  functional materials
王逸博, 韩果萍, 谢会东, 徐立珍, 王淑娟, 刘嘉. 煤矸石源保水剂的制备及改良盐碱土性能. 精细化工, 2026 , 43 (5) : 998 -1007 . DOI: 10.13550/j.jxhg.20250257
Yibo WANG, Guoping HAN, Huidong XIE, Lizhen XU, Shujuan WANG, Jia LIU. Preparation of coal gangue-based water retention agent for improving saline-alkali soil[J]. Fine Chemicals, 2026 , 43 (5) : 998 -1007 . DOI: 10.13550/j.jxhg.20250257
  • 国家重点研发计划项目(2022YFF1303304)
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doi: 10.13550/j.jxhg.20250257
  • 接收时间:2025-04-12
  • 首发时间:2026-08-20
  • 出版时间:2026-05-15
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  • 收稿日期:2025-04-12
  • 录用日期:2025-06-04
基金
国家重点研发计划项目(2022YFF1303304)
作者信息
    1.清华大学 能源与动力工程系,北京 100084
    2.西安建筑科技大学 化学与化工学院,陕西 西安 710055
    3.华清农业开发有限公司,北京 100084

通讯作者:

谢会东(1973—),男,教授,E-mail:
王淑娟(1972—),女,教授,E-mail:
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2种不同金属材料的力学参数

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genus
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占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
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Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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