Article(id=1297161232037990506, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, articleNumber=null, orderNo=null, doi=10.13550/j.jxhg.20250074, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1737734400000, receivedDateStr=2025-01-25, revisedDate=null, revisedDateStr=null, acceptedDate=1742140800000, acceptedDateStr=2025-03-17, onlineDate=1787196937808, onlineDateStr=2026-08-20, pubDate=1778774400000, pubDateStr=2026-05-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1787196937808, onlineIssueDateStr=2026-08-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1787196937808, creator=13701087609, updateTime=1787196937808, updator=13701087609, issue=Issue{id=1297161216049308076, tenantId=1146029695717560320, journalId=1296125381406982186, year='2026', volume='43', issue='5', pageStart='929', pageEnd='1184', issueExtLink='null', onlineDate='null', pubDate='1778774400000', pubDateStr='2026-05-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1787196933996, creator='13701087609', updateTime=1787202244949, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1297183491922354645, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1297183491922354646, tenantId=1146029695717560320, journalId=1296125381406982186, issueId=1297161216049308076, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1021, endPage=1029, ext={EN=ArticleExt(id=1297161233732489323, articleId=1297161232037990506, tenantId=1146029695717560320, journalId=1296125381406982186, language=EN, title=Preparation and properties of nitrogen-doped carbon dots with carbon black from waste tires powder pyrolysis as carbon source, columnId=null, journalTitle=Fine Chemicals, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Extensive accumulation of waste tires, which is hard to decompose naturally, have led to serious resource waste and environmental pollution. Carbon element, primarily contained in waste tire, making them an ideal precursor for the synthesis of carbon dots. N-doped carbon dots (N-CDs) were synthesized by acid-free one-step hydrothermal synthesis method using waste tires powder pyrolysic carbon black (CBp) as carbon source and ammonium persulfate (APS)-triethanolamine (TEA) oxidation-reduction system as oxidant and N element as doping agent, respectively. The synthesis conditions of N-CDs were optimized by orthogonal experiments, while the composition, structure and fluorescence properties of N-CDs were characterized by FTIR, XPS, TEM and steady-state fluorescence spectrometer. A fluorescent ink for anti-counterfeiting was further prepared from N-CDs and evaluated for its performance. The results showed that N-CDs exhibited a basic spherical structure with a particle size of 3~6 nm. Under excitation at 325 nm, N-CDs displayed a maximum fluorescence emission intensity at 410 nm, indicating its wavelength-dependent fluorescence emission property. The photoluminescence quantum yield of N-CDs was 5.14%, which was 12.5 times higher than that of carbon dots (CDs) synthesized by chemical oxidation method using nitric acid as oxidant. The anti-counterfeiting fluorescent ink emitted blue-green fluorescence under a 365 nm UV light, and luminescence phenomenon still remained stable and obvious after 7-day storage.

, authors=Tingting WU^{1, 2}, Jinghao OUYANG^{1, 2}, Yao LI^{1, 2}, Feng YANG^{1, 2, *}, authorsList=Tingting WU, Jinghao OUYANG, Yao LI, Feng YANG, authorCompany=null, correspAuthors=Feng YANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1297161234072227948, articleId=1297161232037990506, tenantId=1146029695717560320, journalId=1296125381406982186, language=CN, title=废轮胎粉热解炭黑为碳源的氮掺杂碳点的制备及性能, columnId=1297161221933913088, journalTitle=精细化工, columnName=功能材料, runingTitle=null, highlight=null, articleAbstract=

废轮胎难以自然降解，大量堆积会造成严重的资源浪费和环境污染，其主要由碳元素构成，是合成碳点的理想前体。以废轮胎粉热解炭黑（CBp）为碳源、过硫酸铵（APS）-三乙醇胺（TEA）氧化-还原体系为氧化剂和N掺杂剂，采用无酸一步水热合成法制备了氮掺杂碳点（N-CDs）。采用正交实验确定了N-CDs的最佳合成工艺，利用FTIR、XPS、TEM和稳态荧光光谱仪对N-CDs组成、结构和荧光性能进行了表征。将N-CDs制成防伪用荧光墨水，考察了其性能。结果表明，N-CDs基本呈球形，粒径为3~6 nm。在325 nm波长激发下，N-CDs在410 nm处的荧光发射强度最大，其发射荧光具有激发波长依赖性。N-CDs的光致发光量子产率为5.14%，是以硝酸为氧化剂的化学氧化法合成的碳点（CDs）的12.5倍。N-CDs制成的防伪用荧光墨水在365 nm的紫外灯照射下发射蓝绿色荧光，保存7 d后，其发光仍稳定明显。

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吴婷婷（2002—），女，硕士生，E-mail: 2945117885@qq.com。

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吴婷婷（2002—），女，硕士生，E-mail: 2945117885@qq.com。

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