Article(id=1309634767075762711, tenantId=1146029695717560320, journalId=1227999776411738115, issueId=1309634747681304819, articleNumber=null, orderNo=null, doi=10.12048/j.issn.1674-229X.2026.01.004, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1740326400000, receivedDateStr=2025-02-24, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1790170860308, onlineDateStr=2026-09-23, pubDate=1769270400000, pubDateStr=2026-01-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790170860308, onlineIssueDateStr=2026-09-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790170860308, creator=13701087609, updateTime=1790170860308, updator=13701087609, issue=Issue{id=1309634747681304819, tenantId=1146029695717560320, journalId=1227999776411738115, year='2026', volume='36', issue='1', pageStart='1', pageEnd='80', issueExtLink='null', onlineDate='null', pubDate='1769270400000', pubDateStr='2026-01-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1790170855683, creator='13701087609', updateTime=1790219109143, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1309837137445482891, tenantId=1146029695717560320, journalId=1227999776411738115, issueId=1309634747681304819, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1309837137445482892, tenantId=1146029695717560320, journalId=1227999776411738115, issueId=1309634747681304819, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=16, endPage=18, ext={EN=ArticleExt(id=1309634767298060824, articleId=1309634767075762711, tenantId=1146029695717560320, journalId=1227999776411738115, language=EN, title=Calculating Freezing Point of NaCl-NH
4Cl-H
2O Ternary System by SEHM Model, columnId=null, journalTitle=Pharmacy Today, columnName=null, runingTitle=null, highlight=null, articleAbstract=
OBJECTIVE To predict the freezing point of the NaCl-NH4Cl-H2O ternary system using the semi-empirical hydration model (SEHM).
METHODS The freezing point of the ternary system was computed from the solution concentration based on the SEHM model, and compared with values obtained from air humidity cryoscopy and cooling curve cryoscopy (FPD-4A cryoscope).
RESULTS The freezing points calculated by the SEHM model showed good agreement with those measured by air humidity cryoscopy and cooling curve cryoscopy. However, the cooling curve method was limited to dilute solutions due to the limited measurement range of the instrument.
CONCLUSION The SEHM model provides a reliable approach for calculating the freezing point of the NaCl-NH4Cl-H2O ternary system based on solution concentration.
, authors=Xiaoxiao WEI
1, Xiancheng ZHAN
2, *, authorsList=Xiaoxiao WEI, Xiancheng ZHAN, authorCompany=null, correspAuthors=Xiancheng ZHAN, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1309634767809765914, articleId=1309634767075762711, tenantId=1146029695717560320, journalId=1227999776411738115, language=CN, title=采用半经验水化模型(SEHM)计算NaCl-NH
4Cl-H
2O三元体系溶液的冰点, columnId=1228268589086606089, journalTitle=今日药学, columnName=论著, runingTitle=null, highlight=null, articleAbstract=
目的 运用半经验水化模型(SEHM)预测NaCl-NH4Cl-H2O三元体系的冰点。
方法 以NaCl-NH4Cl-H2O三元体系为研究体系,基于SEHM模型从溶液浓度推算其冰点,并将计算结果与空气湿度冰点法、步冷曲线法(FPD-4A冰点仪)的测定值进行对比。
结果 SEHM模型计算得到的冰点值与空气湿度冰点法及步冷曲线法的测量结果基本吻合;但步冷曲线法受限于仪器测量范围,仅适用于低浓度溶液。
结论 采用SEHM模型可通过溶液浓度有效计算NaCl-NH4Cl-H2O三元体系的冰点。
, authors=魏箫箫
1, 詹先成
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