高压物理学报

高压相变与时间的关系

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洪时明

高压物理学报 | 2013,27(2): 162-167

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高压物理学报 | 2013 , 27 (2) : 162 -167

高压相变与时间的关系

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洪时明（1947—），男，教授，博士生导师，主要从事高压合成材料、高压实验技术研究. E-mail：smhong2@163.com

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洪时明

作者信息

西南交通大学高温高压物理研究所，四川成都　610031

作者简介:

洪时明（1947—），男，教授，博士生导师，主要从事高压合成材料、高压实验技术研究. E-mail：smhong2@163.com

Time Dependence of High Pressure Induced Phase Transitions

Shi-Ming HONG

Affiliations

Laboratory of High Pressure Physics, Southwest Jiaotong University, Chengdu 610031, China

出版时间: 2013-04-15

文章导航

摘要

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为了研究压致相变的动力学行为，最期待的途径是将高时间分辨率的检测手段与精确的压缩技术相结合。实际上，在大压机上可采用间接的方法，即将回收样品的表征结果与样品所经历的压力、温度和时间进行对比。作为典型例子，根据过去的实验数据，讨论了C-H-O体系中金刚石的成核条件与时间的关系，证明延长保温保压时间有利于高压稳定相的形成。与此相反，一些亚稳相，如大块非晶硫、金属玻璃和非晶高分子材料等，则可通过快速压缩过程获得。实验结果表明：许多物质的相变动力学特征可以在1~10³ GPa/s量级的压缩速率中表现出来。在两类实验中，都可以建立包括压力、温度和时间3个维度的动力学相图。

关键词

高压相变 / 时间相关性 / 相变动力学

Abstract

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For investigating kinetic behavior of pressure induced phase transitions, it is the most expected to combine high time-resolved diagnostic probes with the precise compression techniques. In fact, an indirect way in large volume press is compare characterization results of recovered samples with their experienced conditions including pressure, temperature and time. As a typical example, relationship between p-T conditions and time for diamond nucleation in C-H-O system is discussed by previous experimental data, demonstrated that extending loading time under HP/HT is propitious to form high pressure stable phase. In contrast, some meta-stable phases, such as bulk amorphous sulfur, metallic glasses and amorphous polymers etc., were obtained by rapid compression process. The results indicated that many substances can show the kinetic features of phase transition in the scale of compression rate from 1 GPa to 1 TPa/s. The kinetic phase diagrams with three dimensions (pressure, temperature and time) could be established through both of the static or rapid compression experiments.

Key words

pressure induced phase transition / time dependence / kinetics of phase transition

引用本文

洪时明. 高压相变与时间的关系. 高压物理学报, 2013 , 27 (2) : 162 -167 .

Shi-Ming HONG. Time Dependence of High Pressure Induced Phase Transitions[J]. Chinese Journal of High Pressure Physics, 2013 , 27 (2) : 162 -167 .

基金

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国家自然科学基金(59972022; 10774123; 11004163; 10299040)

参考文献

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参考文献引证文献

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2013年第27卷第2期

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接收时间：2013-03-18
首发时间：2026-11-05
出版时间：2013-04-15

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收稿日期：2013-03-18

基金

国家自然科学基金(59972022; 10774123; 11004163; 10299040)

作者信息

西南交通大学高温高压物理研究所，四川成都　610031

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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