Article(id=1325115347367494217, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1325115299141398790, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1319126400000, receivedDateStr=2011-10-21, revisedDate=1330704000000, revisedDateStr=2012-03-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1793861718264, onlineDateStr=2026-11-05, pubDate=1365955200000, pubDateStr=2013-04-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793861718264, onlineIssueDateStr=2026-11-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793861718264, creator=13701087609, updateTime=1793861718264, updator=13701087609, issue=Issue{id=1325115299141398790, tenantId=1146029695717560320, journalId=1255847867265597444, year='2013', volume='27', issue='2', pageStart='153', pageEnd='311', issueExtLink='null', onlineDate='null', pubDate='1365955200000', pubDateStr='2013-04-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793861706767, creator='13701087609', updateTime=1793861706767, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=253, endPage=260, ext={EN=ArticleExt(id=1325115347854033482, articleId=1325115347367494217, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Pressure-Induced Phase Transition of [Emim][PF₆] and [Bmim][PF₆] Studied by Raman Scattering, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

In-situ pressure-induced phase transition of ionic liquids [Emim][PF₆] and [Bmim][PF₆] have been studied under high pressure and room temperature by using Raman spectroscopy and high-pressure diamond anvil cell (DAC) apparatus. With the increase of pressure, [Emim][PF₆] experiences the solid-solid phase transition at about 0.86 GPa, and [Bmim][PF₆] experiences the liquid-solid phase transition at about 0.62 GPa and the solid-solid phase transition at about 1.45 GPa. Furthermore, the decrease of pressure of [Bmim][PF₆] has also been discussed in details. Pressure-released Raman spectra shows that the phase transition of [Bmim][PF₆] is reversible under pressure up to 2 GPa.

, authors=Xiang ZHU, Yong-Qiang WANG, Zheng WANG, Xue-Rui CHENG, Chao-Sheng YUAN, Zhen-Ping CHEN, Lei SU, authorsList=Xiang ZHU, Yong-Qiang WANG, Zheng WANG, Xue-Rui CHENG, Chao-Sheng YUAN, Zhen-Ping CHEN, Lei SU, authorCompany=null, correspAuthors=Lei SU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1325115348961329739, articleId=1325115347367494217, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=室温离子液体[Emim][PF₆]和[Bmim][PF₆]压致相变的拉曼散射研究, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

室温条件下，采用拉曼光谱仪和四柱型金刚石压砧（DAC），对两种室温离子液体的压致相变进行了详细的研究。实验表明，对于常压下为固态的1-乙基-3-甲基咪唑六氟磷酸盐（[Emim][PF₆]，C₆H₁₁F₆N₂P）离子液体，压力增加到约0.86 GPa时，发生固-固相变；对于常压下为液态的1-丁基-3-甲基咪唑六氟磷酸盐（[Bmim][PF₆]，C₈H₁₅F₆N₂P）离子液体，压力增加到约0.62 GPa时，发生液-固相变，增加到约1.45 GPa时，发生固-固相变。此外，还对[Bmim][PF₆]加压后的卸压过程进行了详细分析，结果表明：离子液体[Bmim][PF₆]在0~2 GPa范围内的压致相变是可逆的。

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朱祥（1982—），男，硕士研究生，主要从事高压物理研究. E-mail：zhuxiang123zx@sina.com

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朱祥（1982—），男，硕士研究生，主要从事高压物理研究. E-mail：zhuxiang123zx@sina.com

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