Article(id=1325115260381831297, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1325114771112079843, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1288022400000, receivedDateStr=2010-10-26, revisedDate=1291824000000, revisedDateStr=2010-12-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1793861697526, onlineDateStr=2026-11-05, pubDate=1339689600000, pubDateStr=2012-06-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793861697526, onlineIssueDateStr=2026-11-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793861697526, creator=13701087609, updateTime=1793861697526, updator=13701087609, issue=Issue{id=1325114771112079843, tenantId=1146029695717560320, journalId=1255847867265597444, year='2012', volume='26', issue='3', pageStart='241', pageEnd='360', issueExtLink='null', onlineDate='null', pubDate='1339689600000', pubDateStr='2012-06-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793861580875, creator='13701087609', updateTime=1793861580875, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=319, endPage=324, ext={EN=ArticleExt(id=1325115263720497282, articleId=1325115260381831297, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Strong Shock-Compression of g-C3N4 Precursor for Direct Synthesis of β-C3N4, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Using a two-stage light gas gun and shock recovery technique, a series of experiments up to 40-65 GPa were carried out on the nitrogen-rich material of precursor g-C3N4. The powder X-ray diffractions (XRD) of recovered samples showed that the precursor g-C3N4 was stable under 51 GPa pressure, while only a new crystalline phase β-C3N4 was obtained during 51-65 GPa pressure. The results confirm that β-C3N4 can be synthesized directly from precursor g-C3N4. This paper is significant for the study of synthesizing pure superhard carbon nitrides.

, authors=Hai-Yun MA, Fu-Sheng LIU, Yong-Hong LI, Ming-Jian ZHANG, Xue-Dong XUE, Jun-Li WANG, authorsList=Hai-Yun MA, Fu-Sheng LIU, Yong-Hong LI, Ming-Jian ZHANG, Xue-Dong XUE, Jun-Li WANG, authorCompany=null, correspAuthors=Fu-Sheng LIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1325115265922506884, articleId=1325115260381831297, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=强冲击压缩条件下g-C3N4向β-C3N4直接转化, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

为了合成出理论预言的具有致密结构的超硬材料C3N4,运用二级轻气炮加载和冲击回收实验技术,以富含N的g-C3N4为前驱物,在40~65 GPa压力下完成了冲击合成实验。在低于51 GPa压力时,X射线衍射分析表明,在回收样品中未发现有新相生成,说明g-C3N4是稳定的;而在51~65 GPa范围内,回收样品中有新相生成,与理论计算结果对照发现,新相为β-C3N4相,且不含其它结晶相。证实利用冲击合成方法将g-C3N4直接转化为单纯β-C3N4是可能的,对纯净的超硬相碳氮化合物的合成研究具有参考意义。

, authors=马海云, 刘福生, 李永宏, 张明建, 薛学东, 王俊莉, authorsList=马海云, 刘福生, 李永宏, 张明建, 薛学东, 王俊莉, authorCompany=null, correspAuthors=刘福生, authorNote=

马海云(1984—),女,硕士研究生,主要从事高温高压下新材料的合成研究. E-mail:

, correspAuthorsNote=
刘福生(1966—),男,博士,教授,博士生导师,主要从事高压凝聚态物理、原子与分子物理以及冲击波技术研究. E-mail:
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马海云(1984—),女,硕士研究生,主要从事高温高压下新材料的合成研究. E-mail:

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强冲击压缩条件下g-C3N4向β-C3N4直接转化
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马海云 , 刘福生 , 李永宏 , 张明建 , 薛学东 , 王俊莉
高压物理学报 | 2012,26(3): 319-324
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高压物理学报 | 2012 , 26 (3) : 319 -324
强冲击压缩条件下g-C3N4向β-C3N4直接转化
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马海云 , 刘福生 , 李永宏, 张明建, 薛学东, 王俊莉
作者信息
  • 西南交通大学高压科学与技术实验室,四川 成都 610031
通讯作者:
刘福生(1966—),男,博士,教授,博士生导师,主要从事高压凝聚态物理、原子与分子物理以及冲击波技术研究. E-mail:
作者简介:

马海云(1984—),女,硕士研究生,主要从事高温高压下新材料的合成研究. E-mail:

Strong Shock-Compression of g-C3N4 Precursor for Direct Synthesis of β-C3N4
Hai-Yun MA , Fu-Sheng LIU , Yong-Hong LI, Ming-Jian ZHANG, Xue-Dong XUE, Jun-Li WANG
Affiliations
  • Key Laboratory of High Pressure Science and Technology, Southwest Jiaotong University, Chengdu 610031, China
出版时间: 2012-06-15
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为了合成出理论预言的具有致密结构的超硬材料C3N4,运用二级轻气炮加载和冲击回收实验技术,以富含N的g-C3N4为前驱物,在40~65 GPa压力下完成了冲击合成实验。在低于51 GPa压力时,X射线衍射分析表明,在回收样品中未发现有新相生成,说明g-C3N4是稳定的;而在51~65 GPa范围内,回收样品中有新相生成,与理论计算结果对照发现,新相为β-C3N4相,且不含其它结晶相。证实利用冲击合成方法将g-C3N4直接转化为单纯β-C3N4是可能的,对纯净的超硬相碳氮化合物的合成研究具有参考意义。

冲击波合成  /  超硬材料  /  热分解  /  C3N4

Using a two-stage light gas gun and shock recovery technique, a series of experiments up to 40-65 GPa were carried out on the nitrogen-rich material of precursor g-C3N4. The powder X-ray diffractions (XRD) of recovered samples showed that the precursor g-C3N4 was stable under 51 GPa pressure, while only a new crystalline phase β-C3N4 was obtained during 51-65 GPa pressure. The results confirm that β-C3N4 can be synthesized directly from precursor g-C3N4. This paper is significant for the study of synthesizing pure superhard carbon nitrides.

shock wave synthesis  /  superhard material  /  thermal decomposition  /  C3N4
马海云, 刘福生, 李永宏, 张明建, 薛学东, 王俊莉. 强冲击压缩条件下g-C3N4向β-C3N4直接转化. 高压物理学报, 2012 , 26 (3) : 319 -324 .
Hai-Yun MA, Fu-Sheng LIU, Yong-Hong LI, Ming-Jian ZHANG, Xue-Dong XUE, Jun-Li WANG. Strong Shock-Compression of g-C3N4 Precursor for Direct Synthesis of β-C3N4[J]. Chinese Journal of High Pressure Physics, 2012 , 26 (3) : 319 -324 .
  • 自然科学基金(10874141)
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2012年第26卷第3期
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  • 接收时间:2010-10-26
  • 首发时间:2026-11-05
  • 出版时间:2012-06-15
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  • 收稿日期:2010-10-26
  • 修回日期:2010-12-09
基金
自然科学基金(10874141)
作者信息
    西南交通大学高压科学与技术实验室,四川 成都 610031

通讯作者:

刘福生(1966—),男,博士,教授,博士生导师,主要从事高压凝聚态物理、原子与分子物理以及冲击波技术研究. E-mail:
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2种不同金属材料的力学参数
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属
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种数
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species
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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