Article(id=1324026439221257071, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1324026415431164669, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1267632000000, receivedDateStr=2010-03-04, revisedDate=1282838400000, revisedDateStr=2010-08-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1793602102331, onlineDateStr=2026-11-02, pubDate=1308067200000, pubDateStr=2011-06-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793602102331, onlineIssueDateStr=2026-11-02, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793602102331, creator=13701087609, updateTime=1793602102331, updator=13701087609, issue=Issue{id=1324026415431164669, tenantId=1146029695717560320, journalId=1255847867265597444, year='2011', volume='25', issue='3', pageStart='193', pageEnd='288', issueExtLink='null', onlineDate='null', pubDate='1308067200000', pubDateStr='2011-06-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793602096660, creator='13701087609', updateTime=1793602819353, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1324029446684028999, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1324026415431164669, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1324029446684029000, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1324026415431164669, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=275, endPage=281, ext={EN=ArticleExt(id=1324026439565190000, articleId=1324026439221257071, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=p-V Equation of State of (Fe0.03Ni0.97)8 (Si0.79P0.21)3, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Perryite (Fe0.03Ni0.97)8 (Si0.79P0.21)3 sample was synthesized using the standard solid-state reaction. The X-ray diffraction results show that its space group is with the lattice parameters (a=b=0.663 8(1) nm, c=3.789 2(2) nm, V=1.446 15(6) nm3). In situ high-pressure X-ray diffraction experiments were carried out up to 21.3 GPa at room temperature. No phase transition was observed in the present pressure range. The unit-cell volumes show a smooth decrease with increasing pressure. The variation of the unit-cell volume with pressure was analyzed by Birch-Murnaghan equations of state. Results of the B-M equations of state yield a unit-cell volume (V0) of 1.441 4(24) nm3 at zero GPa, an isothermal bulk modulus (K0) of 220(7) GPa. Axial compressibility was fitted linearly by Murnaghan equations of state. We obtained Ka=257(9), Kc=165(4). The c-axis was more compressible than the a-axis.

, authors=Jing YANG, Xiang WU, Shan QIN, authorsList=Jing YANG, Xiang WU, Shan QIN, authorCompany=null, correspAuthors=Xiang WU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1324026442023052149, articleId=1324026439221257071, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=(Fe0.03Ni0.97)8(Si0.79P0.21)3的等温状态方程研究, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用固态高温烧结反应方法,成功合成出了陨硅镍铁石样品(Fe0.03Ni0.97)8(Si0.79P0.21)3。X射线衍射结果表明,合成样品的结构为,对应的晶胞参数为a=b=0.663 8(1)nm,c=3.789 2(2)nm,V=1.446 15(6)nm3。在室温下,对样品进行原位高压X射线衍射研究,实验最高压力达到21.3 GPa,随着压力的升高,晶胞体积逐渐减小,但并没有观察到结构相变。利用Birch-Murnaghan状态方程对体积与压力的关系进行拟合,获得常温常压下的体积V0=1.441 4(24)nm3,体积模量K0=220(7)GPa。晶轴与压力的关系利用Murnaghan状态方程拟合,获得a轴和c轴的模量分别为Ka=257(9)和Kc=165(4),c轴较a轴容易压缩。

, authors=杨晶, 巫翔, 秦善, authorsList=杨晶, 巫翔, 秦善, authorCompany=null, correspAuthors=巫翔, authorNote=

杨晶(1987—),女,硕士研究生,主要从事晶体结构和材料高压物性的研究. E-mail:

, correspAuthorsNote=
巫翔(1978—),男,博士,教授,主要从事晶体结构和材料高压物性的研究. E-mail:
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杨晶(1987—),女,硕士研究生,主要从事晶体结构和材料高压物性的研究. E-mail:

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(Fe0.03Ni0.97)8(Si0.79P0.21)3的等温状态方程研究
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杨晶 , 巫翔 , 秦善
高压物理学报 | 2011,25(3): 275-281
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高压物理学报 | 2011 , 25 (3) : 275 -281
(Fe0.03Ni0.97)8(Si0.79P0.21)3的等温状态方程研究
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杨晶 , 巫翔 , 秦善
作者信息
  • 北京大学地球与空间科学学院造山带与地壳演化教育部重点实验室,北京 100871
通讯作者:
巫翔(1978—),男,博士,教授,主要从事晶体结构和材料高压物性的研究. E-mail:
作者简介:

杨晶(1987—),女,硕士研究生,主要从事晶体结构和材料高压物性的研究. E-mail:

p-V Equation of State of (Fe0.03Ni0.97)8 (Si0.79P0.21)3
Jing YANG , Xiang WU , Shan QIN
Affiliations
  • School of Earth and Space Sciences, Peking University, Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, Beijing 100871, China
出版时间: 2011-06-15
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采用固态高温烧结反应方法,成功合成出了陨硅镍铁石样品(Fe0.03Ni0.97)8(Si0.79P0.21)3。X射线衍射结果表明,合成样品的结构为,对应的晶胞参数为a=b=0.663 8(1)nm,c=3.789 2(2)nm,V=1.446 15(6)nm3。在室温下,对样品进行原位高压X射线衍射研究,实验最高压力达到21.3 GPa,随着压力的升高,晶胞体积逐渐减小,但并没有观察到结构相变。利用Birch-Murnaghan状态方程对体积与压力的关系进行拟合,获得常温常压下的体积V0=1.441 4(24)nm3,体积模量K0=220(7)GPa。晶轴与压力的关系利用Murnaghan状态方程拟合,获得a轴和c轴的模量分别为Ka=257(9)和Kc=165(4),c轴较a轴容易压缩。

陨硅镍铁石  /  高压  /  状态方程

Perryite (Fe0.03Ni0.97)8 (Si0.79P0.21)3 sample was synthesized using the standard solid-state reaction. The X-ray diffraction results show that its space group is with the lattice parameters (a=b=0.663 8(1) nm, c=3.789 2(2) nm, V=1.446 15(6) nm3). In situ high-pressure X-ray diffraction experiments were carried out up to 21.3 GPa at room temperature. No phase transition was observed in the present pressure range. The unit-cell volumes show a smooth decrease with increasing pressure. The variation of the unit-cell volume with pressure was analyzed by Birch-Murnaghan equations of state. Results of the B-M equations of state yield a unit-cell volume (V0) of 1.441 4(24) nm3 at zero GPa, an isothermal bulk modulus (K0) of 220(7) GPa. Axial compressibility was fitted linearly by Murnaghan equations of state. We obtained Ka=257(9), Kc=165(4). The c-axis was more compressible than the a-axis.

perryite  /  high pressure  /  equation of state
杨晶, 巫翔, 秦善. (Fe0.03Ni0.97)8(Si0.79P0.21)3的等温状态方程研究. 高压物理学报, 2011 , 25 (3) : 275 -281 .
Jing YANG, Xiang WU, Shan QIN. p-V Equation of State of (Fe0.03Ni0.97)8 (Si0.79P0.21)3[J]. Chinese Journal of High Pressure Physics, 2011 , 25 (3) : 275 -281 .
  • 国家自然科学基金(40972029)
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2011年第25卷第3期
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  • 接收时间:2010-03-04
  • 首发时间:2026-11-02
  • 出版时间:2011-06-15
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  • 收稿日期:2010-03-04
  • 修回日期:2010-08-27
基金
国家自然科学基金(40972029)
作者信息
    北京大学地球与空间科学学院造山带与地壳演化教育部重点实验室,北京 100871

通讯作者:

巫翔(1978—),男,博士,教授,主要从事晶体结构和材料高压物性的研究. E-mail:
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
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