Article(id=1323705185356349784, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323705144138932923, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1159286400000, receivedDateStr=2006-09-27, revisedDate=1167408000000, revisedDateStr=2006-12-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1793525509441, onlineDateStr=2026-11-01, pubDate=1173024000000, pubDateStr=2007-03-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793525509441, onlineIssueDateStr=2026-11-01, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793525509441, creator=13701087609, updateTime=1793525509441, updator=13701087609, issue=Issue{id=1323705144138932923, tenantId=1146029695717560320, journalId=1255847867265597444, year='2007', volume='21', issue='1', pageStart='1', pageEnd='112', issueExtLink='null', onlineDate='null', pubDate='1173024000000', pubDateStr='2007-03-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793525499614, creator='13701087609', updateTime=1793525499614, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=15, endPage=19, ext={EN=ArticleExt(id=1323705185511539033, articleId=1323705185356349784, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=High Temperature and High Pressure Synthesis and Study of 0212-Type Ca₃Cu₂O_4+δCl_2-y, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Using the apical oxygen doping mechanism, i.e. a partial substitution of divalence O for the monovalence Cl, we synthesized Ca₃Cu₂O_4+δCl_2-y with Ag₂O under high temperature and high pressure. From X-ray diffraction composition analysis, we confirmed that Ca₃Cu₂O_4+δCl_2-y crystallizes into a 0212 structure. With increasing the content of Ag₂O, we found that lattice parameters a shrinked but c increased. It suggested that it should be hole doping. We also investigated the temperature dependence of the electrical resistivity and DC magnetic susceptibility for two samples, but we didn't observe superconductivity. It maybe resulted from the too low density of hole carrier.

, authors=Da-Xiao YANG^{1, 2}, Qing-Qing LIU¹, Wei-Bo GAO¹, Wen YU^{1, 2}, Feng-Ying LI¹, Chang-Qing JIN¹, authorsList=Da-Xiao YANG, Qing-Qing LIU, Wei-Bo GAO, Wen YU, Feng-Ying LI, Chang-Qing JIN, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323705185721254234, articleId=1323705185356349784, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=0212型Ca₃Cu₂O_4+δCl_2-y化合物高温高压合成与研究, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

利用“顶角氧掺杂”机制，即以二价氧部分替代顶角一价氯，用Ag₂O做氧源，在高温高压下制备了单相的Ca₃Cu₂O_4+δCl_2-y样品。X射线衍射分析发现，随着Ag₂O含量的增加，Ca₃Cu₂O_4+δCl_2-y样品的晶格常数a逐渐变小，c逐渐增大，体现了空穴掺杂的本质。进行了电阻率和磁化率测量，没有发现超导性，可能是空穴载流子没有达到合适的浓度所致。

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^2.University of Science & Technology of Beijing, Beijing 100083, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1323705187726131560, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1323705185356349784, authorId=1323705187579330915, language=CN, stringName=杨达晓, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=^{1, 2}, address=^1.中国科学院物理研究所，北京　100080
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杨达晓（1981—），男，硕士研究生，主要研究方向为高温超导材料. E-mail：fyangdx@sohu.com

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杨达晓（1981—），男，硕士研究生，主要研究方向为高温超导材料. E-mail：fyangdx@sohu.com

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