高压物理学报

立方氮化硅及其冲击波合成

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贺红亮

高压物理学报 | 2007,21(1): 1-7

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高压物理学报 | 2007 , 21 (1) : 1 -7

立方氮化硅及其冲击波合成

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贺红亮（1963—），研究员，博士生导师，主要研究方向为高压材料科学与力学. E-mail：honglianghe@263.net

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贺红亮（1963—），研究员，博士生导师，主要研究方向为高压材料科学与力学. E-mail：honglianghe@263.net

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贺红亮

作者信息

中国工程物理研究院流体物理研究所冲击波物理与爆轰物理实验室，四川绵阳　621900

作者简介:

贺红亮（1963—），研究员，博士生导师，主要研究方向为高压材料科学与力学. E-mail：honglianghe@263.net

Cubic Silicon Nitride and Its Synthesis by Shock Wave Compression

Hong-Liang HE

Affiliations

Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, Mianyang 621900, China

出版时间: 2007-03-05

文章导航

摘要

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立方氮化硅是高温高压研究近期合成得到的一种新物相，与已经在工业上普遍使用的氮化硅的两种六方物相（α相和β相）相比，新物相的密度增加了26%，预期是一种新型功能材料。简要综述了立方氮化硅的研究进展和存在的问题，讨论了立方氮化硅的人工合成和相关物性研究、Ⅳ（A）族氮化物（Ge₃N₄、Sn₃N₄、C₃N₄）的高密度物相研究，以及后尖晶石相氮化物的实验和理论探索等问题。介绍了作者最近利用炸药爆轰加载技术开展的冲击波合成实验结果，以α相氮化硅为冲击压缩前驱体，实现了在单次冲击波压缩实验中合成出了克量级立方氮化硅粉体，为进一步开展立方氮化硅的性能研究奠定了基础。

关键词

立方氮化硅 / 冲击波压缩 / 合成

Abstract

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Cubic silicon nitride is a new polymorphous of Si₃N₄ synthesized under high pressure and high temperature. Compared to the two known hexagonal phases of α and β, the new phase is about 26% denser in density, and it is predicted to be a new multi-functional ceramic. The achievement and related concern of the cubic silicon nitride have been reviewed in this paper, including the progress in artificial synthesis, the study on its physical property, the synthesis of other Ⅳ(A) group denser nitrides (Ge₃N₄, Sn₃N₄, C₃N₄), and the explore of the possible post-spinel phase of nitride. By using a flyer impact technique with explosive detonation, we recently have synthesized the cubic silicon nitride from the precursor of α-Si₃N₄, and the mass production of the cubic phase has reached about 2 grams in each run of the shock wave compression test, which provides an economic way for further investigation of its potential performance in industriy.

Key words

cubic silicon nitride / shock compression / synthesis

引用本文

贺红亮. 立方氮化硅及其冲击波合成. 高压物理学报, 2007 , 21 (1) : 1 -7 .

Hong-Liang HE. Cubic Silicon Nitride and Its Synthesis by Shock Wave Compression[J]. Chinese Journal of High Pressure Physics, 2007 , 21 (1) : 1 -7 .

基金

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国家自然科学基金(50472102)
中国工程物理研究院科学技术基金(20050864)

参考文献

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文献

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参考文献引证文献

排序方式：

[1]

Zerr A, Miehe G, Serghious G, et al. Synthesis of Cubic Silicon Nitride[J]. Nature (London), 1999, 400: 340-342.

[2]

Brook R J. Superhard Ceramics[J]. Nature (London), 1999, 400: 312-315.

[3]

Mo S-D, Ouyang L, Ching W Y, et al. Interesting Properties of New Spinel Phase of Si₃N₄ and C₃N₄[J]. Phys Rev Lett, 1999, 83: 5046-5049.

[4]

Sekine T, He H L, Kobayashi T, et al. Shock-Induced Transformation of β-Si₃N₄ to a High-Pressure Cubic-Spinel Phase[J]. Appl Phys Lett, 2000, 76: 3706-3708.

[5]

Jiang J Z, Stahl K, Berg R W, et al. Structural Characterization of Cubic Silicon Nitride[J]. Europhys Lett, 2000, 51: 62-67.

[6]

Schwarz M, Miehe G, Zerr A, et al. Spinel-Si₃N₄: Multi-Anvil Press Synthesis and Structural Refinement[J]. Advanced Mater, 2000, 12: 883-887.

[7]

McMillan P F. New Materials from High-Pressure Experiments[J]. Nature materials, 2002, 1: 19-25.

[8]

Sekine T, Mitsuhashi T. High-Temperature Metastability of Cubic Spinel Si₃N₄[J]. Appl Phys Lett, 2001, 79: 2719-2721.

[9]

Jiang J Z, Kragh F, Frost D J, et al. Hardness and Thermal Stability of Cubic Silicon Nitride[J]. J Phys: Condens Matter, 2001, 13: L515-L520.

[10]

Jiang J Z, Lindelov H, Gerward L, et al. Compressibility and Thermal Expansion of Cubic Silicon Nitride[J]. Phys Rev B, 2002, 65: 161202(1)-161202(4).

[11]

Hintzen H T, Hendrix M R M M, Wondergem H, et al. Thermal Expansion of Cubic Si₃N₄ with the Spinel Structure[J]. J Alloys Compounds, 2003, 351: 40-42.

[12]

He H L, Sekine T, Kobayashi T, et al. Shock-Induced Phase Transition of β-Si₃N₄ to c-Si₃N₄[J]. Phys Rev B, 2000, 62(17): 11412-11417.

[13]

Kiefer B, Shieh S R, Duffy T S, et al. Strength, Elasticity, and Equation of State of the Nanocrystalline Cubic Silicon Nitride γ-Si₃N₄ to 68 GPa[J]. Phys Rev B, 2005, 72(1): 014102(1)-014102(9).

[14]

Zerr A, Kempf M, Schwarz M, et al. Elastic Moduli and Hardness of Cubic Silicon Nitride[J]. J Am Ceram Soc, 2002, 85: 86-90.

[15]

Mori-Sánchez P, Marqués M, Beltrán A, et al. Origin of the Low Compressibility in Hard Nitride Spinels[J]. Phys Rev B, 2003, 68(6): 064115(1)-064115(5).

[16]

He J L, Guo L C, Yu D L, et al. Hardness of cubic Spinel Si₃N₄[J]. Appl Phys Lett, 2004, 85(23): 5571-5573.

[17]

Dong J J, Deslippe J, Sankey O F, et al. Theoretical Study of the Ternary Spinel Nitride System Si₃N₄-Ge₃N₄[J]. Phys Rev B, 2003, 67(9): 094104(1)-094104(7).

[18]

Tanaka I, Mizoguchi T, Sekine T, et al. Electron Energy Loss Near-Edge Structures of Cubic Si₃N₄[J]. Appl Phys Lett, 2001, 78: 2134-2136.

[19]

Sekine T, Tansho M, Kanzaki M. Si Magic-Angle-Spinning Nuclear-Magnetic-Resonance Study of Spinel-Type Si₃N₄[J]. Appl Phys Lett, 2001, 78: 3050-3051.

[20]

Fang C M, de Wijs G A, Hintzen H T, et al. Phonon Spectrum and Thermal Properties of Cubic Si₃N₄ from First-Principles Calculations[J]. J Appl Phys, 2003, 93: 5175-5180.

[21]

Oba F, Tazuyoshi K, Adachi H, et al. n- and p-Type Dopants for Cubic Silicon Nitride[J]. Appl Phys Lett, 2001, 78: 1557-1579.

[22]

Serghiou G, Miehe G, Tschauner O, et al. Synthesis of a Cubic Ge₃N₄ Phase at High Pressures and Temperatures[J]. J Chem Phys, 1999, 111: 4659-4662.

[23]

Leinenweber K, O'Keeffe M, Somayazulu M, et al. Synthesis and Structure Refinement of the Spinel, γ-Ge₃N₄[J]. Chem Eur J, 1999, 5: 3076-3080.

[24]

He H L, Sekine T, Kobayashi T, et al. Phase Transformation of Germanium Nitride (Ge₃N₄) under Shock Wave[J]. J Appl Phys, 2001, 90: 4403-4406.

[25]

Shemkunas M P, Wolf G H, Leinenweber K, et al. Rapid Synthesis of Crystalline Spinel Tin Nitride by a Solid-State Metathesis Reaction[J]. J Am Ceram Soc, 2002, 85: 101-104.

[26]

Liu A Y, Cohen M L. Prediction of New Low Compressibility Solids[J]. Science, 1989, 245: 841-842.

[27]

Teter D M, Hemley R J. Low-Compressibility Carbon Nitrides[J]. Science, 1996, 271: 53-55.

[28]

Matsumoto S, Xie E-Q, Izumi F. On the Validity of the Formation of Crystalline Carbon Nitrides, C₃N₄[J]. Diamond Relat Mater, 1999, 8: 1175-1182.

[29]

Malkow T. Critical Observations in the Research of Carbon Nitride[J]. Mater Sci Eng, 2000, A292: 112-124.

[30]

Ching W Y, Mo S-D, Tanaka I, et al. Prediction of Spinel Structure and Properties of Single and Double Nitrides[J]. Phys Rev B, 2001, 63: 064102(1)-064102(4).

[31]

Sanchez P M, Marques M, Beltran A, et al. Origin of the Low Compressibility in Hard Nitride Spinels[J]. Phys Rev B, 2003, 68: 064115(1)-064115(5).

[32]

Schnick W. The First Nitride Spinels-New Synthetic Approaches to Binary Group 14 Nitrides[J]. Angew Chem Int Ed, 1999, 38: 3309-3310.

[33]

Fei Y, Frost D J, Mao H K, et al. In Situ Structure Determination of the High-Pressure Phase of Fe₃O₄[J]. Am Miner, 1999, 84: 203-206.

[34]

Shim S-H, Duffy T S, Shen G Y. The Post-Spinel Transformation in Mg₂SiO₄ and Its Relation to the 660 km Seismic Discontinuity[J]. Nature (London), 2001, 411: 571-574.

[35]

Tatsumi K, Tanaka I, Adachi H, et al. Theoretical Prediction of Post-Spinel Phase of Silicon Nitride[J]. J Am Ceram Soc, 2002, 85: 7-10.

[36]

Liu Y Sh, Yao H, Zhang F P, et al. Experiment Research on Shock Synthesis of Cubic Silicon Nitride[J]. Journal of Inorganic Materials, 2007, 22(1): 159-162. (in Chinese)

刘雨生, 姚怀, 张福平, 等. 立方氮化硅的冲击波合成实验研究[J]. 无机材料学报, 2007, 22(1): 159-162.

[37]

DeCarli P S, Jamieson J C. Formation of Diamond by Explosive Shock[J]. Science, 1961, 133: 1821-1823.

2007年第21卷第1期

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接收时间：2006-07-11
首发时间：2026-11-01
出版时间：2007-03-05

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收稿日期：2006-07-11
修回日期：2007-01-03

基金

国家自然科学基金(50472102)

中国工程物理研究院科学技术基金(20050864)

作者信息

中国工程物理研究院流体物理研究所冲击波物理与爆轰物理实验室，四川绵阳　621900

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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