Article(id=1323704688683655196, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323704676520177870, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1146326400000, receivedDateStr=2006-04-30, revisedDate=1160236800000, revisedDateStr=2006-10-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1793525391026, onlineDateStr=2026-11-01, pubDate=1188921600000, pubDateStr=2007-09-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793525391026, onlineIssueDateStr=2026-11-01, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793525391026, creator=13701087609, updateTime=1793525391026, updator=13701087609, issue=Issue{id=1323704676520177870, tenantId=1146029695717560320, journalId=1255847867265597444, year='2007', volume='21', issue='3', pageStart='225', pageEnd='336', issueExtLink='null', onlineDate='null', pubDate='1188921600000', pubDateStr='2007-09-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793525388126, creator='13701087609', updateTime=1793525388126, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=305, endPage=310, ext={EN=ArticleExt(id=1323704688859815965, articleId=1323704688683655196, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Pure titanate nanotubes and titanate nanotubes doped with Eu3+ ions were synthesized by hydrothermal method. In this process, the preparation of nanotubes is synchronously finished by doping with Eu3+ ions. The morphology, structure, thermal stability and luminescence property of titanate nanotubes were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), and photoluminescence instrument. The results show that the method is simple, stable and high-yield. The structure of the nanotube could be approximately indexed by (H, Na)2Ti3O7 or (H, Na)2(Ti, Eu)3O7. Treatment of high temperature will bring into big changes to structures of titanate nanotubes. When the calcine temperature is higher than 450 ℃, tubulous structure of titanate nanotube was destroyed and transformed into structure of anatase phase. Sample of TNT-Eu shows strong luminescence property. There exist three peaks (393.5 nm, 593 nm, 614 nm) in its luminescence spectrum which are associated to 5D0-7F1 and 5D0-7F2 Eu3+ electronic transition respectively.

, authors=Gong-Bao SONG, Mei-Li WANG, Lan-Dong MIAO, Jian LI, Bao-Shu ZHANG, authorsList=Gong-Bao SONG, Mei-Li WANG, Lan-Dong MIAO, Jian LI, Bao-Shu ZHANG, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323704689073725470, articleId=1323704688683655196, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=Eu3+离子掺杂钛酸盐纳米管的直接水热合成与发光性能, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用纳米管制备和离子掺杂同步进行的直接水热合成方法,合成了纯钛酸盐纳米管(TNT)和Eu3+离子掺杂的纳米管(TNT-Eu);并利用X射线衍射(XRD)、透射电子显微镜(TEM)、光致发光谱仪研究了纳米管的形貌特征、物相组成、热稳定性和发光性能。结果显示:这种方法简便易行、稳定性好、产率高。钛酸盐纳米管物相可近似表示为(H,Na)2Ti3O7或(H,Na)2(Ti,Eu)3O7。高温处理对钛酸盐纳米管的结构产生很大的影响,450 ℃下纳米管的层状结构被破坏,晶体结构转化为锐钛矿型的TiO2。TNT-Eu样品的发光性能较强,出现的393.5 nm、593 nm、614 nm的谱带归属于5D0-7F1和5D0-7F2电子的跃迁。

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宋功保(1966—),男,博士,研究员,主要从事功能材料的制备、表征和性能研究. E-mail:

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Eu3+离子掺杂钛酸盐纳米管的直接水热合成与发光性能
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宋功保 , 王美丽 , 苗兰冬 , 李健 , 张宝述
高压物理学报 | 2007,21(3): 305-310
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高压物理学报 | 2007 , 21 (3) : 305 -310
Eu3+离子掺杂钛酸盐纳米管的直接水热合成与发光性能
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宋功保 , 王美丽, 苗兰冬, 李健, 张宝述
作者信息
  • 西南科技大学建筑材料四川省重点实验室,四川 绵阳 621010
作者简介:

宋功保(1966—),男,博士,研究员,主要从事功能材料的制备、表征和性能研究. E-mail:

Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions
Gong-Bao SONG , Mei-Li WANG, Lan-Dong MIAO, Jian LI, Bao-Shu ZHANG
Affiliations
  • Key Laboratory of Building Materials of Sichuan Province, Southwest University of Science and Technology, Mianyang 621010, China
出版时间: 2007-09-05
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采用纳米管制备和离子掺杂同步进行的直接水热合成方法,合成了纯钛酸盐纳米管(TNT)和Eu3+离子掺杂的纳米管(TNT-Eu);并利用X射线衍射(XRD)、透射电子显微镜(TEM)、光致发光谱仪研究了纳米管的形貌特征、物相组成、热稳定性和发光性能。结果显示:这种方法简便易行、稳定性好、产率高。钛酸盐纳米管物相可近似表示为(H,Na)2Ti3O7或(H,Na)2(Ti,Eu)3O7。高温处理对钛酸盐纳米管的结构产生很大的影响,450 ℃下纳米管的层状结构被破坏,晶体结构转化为锐钛矿型的TiO2。TNT-Eu样品的发光性能较强,出现的393.5 nm、593 nm、614 nm的谱带归属于5D0-7F1和5D0-7F2电子的跃迁。

直接水热合成  /  钛酸盐纳米管  /  Eu3+离子  /  掺杂  /  发光性能

Pure titanate nanotubes and titanate nanotubes doped with Eu3+ ions were synthesized by hydrothermal method. In this process, the preparation of nanotubes is synchronously finished by doping with Eu3+ ions. The morphology, structure, thermal stability and luminescence property of titanate nanotubes were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), and photoluminescence instrument. The results show that the method is simple, stable and high-yield. The structure of the nanotube could be approximately indexed by (H, Na)2Ti3O7 or (H, Na)2(Ti, Eu)3O7. Treatment of high temperature will bring into big changes to structures of titanate nanotubes. When the calcine temperature is higher than 450 ℃, tubulous structure of titanate nanotube was destroyed and transformed into structure of anatase phase. Sample of TNT-Eu shows strong luminescence property. There exist three peaks (393.5 nm, 593 nm, 614 nm) in its luminescence spectrum which are associated to 5D0-7F1 and 5D0-7F2 Eu3+ electronic transition respectively.

direct hydrothermal synthesis  /  titanate nanotube  /  Eu3+ ion  /  doping  /  luminescence property
宋功保, 王美丽, 苗兰冬, 李健, 张宝述. Eu3+离子掺杂钛酸盐纳米管的直接水热合成与发光性能. 高压物理学报, 2007 , 21 (3) : 305 -310 .
Gong-Bao SONG, Mei-Li WANG, Lan-Dong MIAO, Jian LI, Bao-Shu ZHANG. Direct Hydrothermal Synthesis and Luminescence Property of Titanate Nanotubes Doped with Eu3+ Ions[J]. Chinese Journal of High Pressure Physics, 2007 , 21 (3) : 305 -310 .
  • 四川省教育厅重点项目和重点专项(2005D006)
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2007年第21卷第3期
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  • 接收时间:2006-04-30
  • 首发时间:2026-11-01
  • 出版时间:2007-09-05
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  • 收稿日期:2006-04-30
  • 修回日期:2006-10-08
基金
四川省教育厅重点项目和重点专项(2005D006)
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    西南科技大学建筑材料四川省重点实验室,四川 绵阳 621010
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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