高压物理学报

高温高压下Fe-Ni-C系合成金刚石的研究

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李和胜 , 李木森

高压物理学报 | 2007,21(4): 401-408

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高压物理学报 | 2007 , 21 (4) : 401 -408

高温高压下Fe-Ni-C系合成金刚石的研究

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李和胜, 李木森

作者信息

^1.山东大学材料科学与工程学院，山东济南　250061

^2.山东省超硬材料工程技术研究中心，山东邹城　273500

通讯作者:

李木森（1952—），男，教授，博士生导师，主要从事超硬材料相关领域的研究. E-mail：msli@sdu.edu.cn

作者简介:

李和胜（1981—），男，博士研究生，主要从事高温高压合成金刚石及性能检测等研究. E-mail：heshengli329@mail.sdu.edu.cn

Study on Synthesizing Diamond from Fe-Ni-C System at High Temperature and High Pressure

He-Sheng LI, Mu-Sen LI

Affiliations

^1.School of Materials Science and Engineering, Shandong University, Jinan 250061, China

^2.Shandong Engineering Research Centre for Super-Hard Materials, Zoucheng 273500, China

出版时间: 2007-12-05

文章导航

摘要

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以工业纯单质铁粉和单质镍粉为主要原料，采用粉末冶金方法制备了Fe-Ni-C系反应体系，在六面顶压机上进行了金刚石合成实验。Raman光谱和X射线衍射结果表明，采用这种方法获得的粒径为200~500 μm，呈六-八面体聚形的晶体为立方金刚石单晶。通过对常规力学性能的检测发现，金刚石的品位较高，超过SMD25级锯片级金刚石的要求。分析认为，高温高压下金刚石自Fe-Ni-C系形核是一个触媒不断溶解催化碳原子的过程。大量的实验结果可以证实，金刚石在Fe-Ni-C系长大所需的碳原子来自于在γ-（Fe，Ni）吸引作用下、从（Fe，Ni）₃C中不断脱溶的碳。金属包覆膜在这一过程中不但起到了输送碳原子的作用，还以独特的方式促成了碳原子由sp²π杂化态向sp³杂化态的转变。

关键词

人造金刚石 / 铁基触媒 / 粉末冶金 / 高温高压

Abstract

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The synthesizing diamond experiment was carried out with iron-based catalysts made by powder metallurgy using industrial iron and nickel powder as stuff at cubic high pressure apparatus. By employing Raman spectroscopy and X-ray diffraction, it can be proved that the crystal gotten from the experiment whose grain size is 200~500 μm is cubic diamond single crystal. The results of the mechanical property test indicate that the quality of diamond exceeds the standard of SMD25. By analysis, it can be judged that the process of diamond nucleation is the one that the molten alloy dissolves and catalyses the carbon atoms. Based on a lot of results, it can be illustrated that the carbon, which is needed for diamond growth, comes from the (Fe, Ni)₃C under the absorption of γ-(Fe, Ni) and the film is not only the diffuse path of carbon, but also the catalysts of structure deformation.

Key words

synthetic diamond / iron-based catalysts / powder metallurgy / high temperature and high pressure

引用本文

李和胜, 李木森. 高温高压下Fe-Ni-C系合成金刚石的研究. 高压物理学报, 2007 , 21 (4) : 401 -408 .

He-Sheng LI, Mu-Sen LI. Study on Synthesizing Diamond from Fe-Ni-C System at High Temperature and High Pressure[J]. Chinese Journal of High Pressure Physics, 2007 , 21 (4) : 401 -408 .

基金

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国家自然科学基金(50772060)

参考文献

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参考文献引证文献

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2007年第21卷第4期

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接收时间：2006-11-16
首发时间：2026-11-01
出版时间：2007-12-05

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出版历史

收稿日期：2006-11-16
修回日期：2007-01-29

基金

国家自然科学基金(50772060)

作者信息

^1.山东大学材料科学与工程学院，山东济南　250061

^2.山东省超硬材料工程技术研究中心，山东邹城　273500

通讯作者:

李木森（1952—），男，教授，博士生导师，主要从事超硬材料相关领域的研究. E-mail：msli@sdu.edu.cn

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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