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The reaction of Li3N-B2O3 and Mg-B2O3 under different pressure and temperature has been studied and the phase of the resultant has been analyzed by X-ray diffraction (XRD) method. XRD results show that when the starting material is Mg-B2O3, the major production is Mg3B2O6; When the starting material is Li3N-B2O3, cBN appears in the production. These results indicate that if the content of B2O3 is the same in the starting material, we will get different results, in the case of using Mg and Li3N as the catalyst respectively.

, authors=Zuo-Peng SU, Tie-Chen ZHANG, Yong-Hui DU, authorsList=Zuo-Peng SU, Tie-Chen ZHANG, Yong-Hui DU, authorCompany=null, correspAuthors=Tie-Chen ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323703604489629825, articleId=1323703602547667070, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高压高温下B2O3与Mg和Li3N的反应, columnId=null, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

通过B2O3与Mg和Li3N分别在不同温度压力条件下的反应,用X射线方法研究了生成物的物相。当采用Mg与B2O3为原料时,其产物是Mg3B2O6;用Li3N与B2O3反应时,产物中除了Li3BO3,还有立方氮化硼(cBN)生成。这表明,当原料中含有相同数量B2O3时,用Mg和Li3N分别作触媒合成立方氮化硼,将得到不同的结果。

, authors=苏作鹏, 张铁臣, 杜勇慧, authorsList=苏作鹏, 张铁臣, 杜勇慧, authorCompany=null, correspAuthors=张铁臣, authorNote=

苏作鹏(1979—),男,博士研究生. E-mail:

, correspAuthorsNote=
张铁臣(1943—),男,教授,博士生导师,主要研究方向为高温高压下材料合成. E-mail:
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高压高温下B2O3与Mg和Li3N的反应
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苏作鹏 , 张铁臣 , 杜勇慧
高压物理学报 | 2006,20(3): 277-280
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高压物理学报 | 2006 , 20 (3) : 277 -280
高压高温下B2O3与Mg和Li3N的反应
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苏作鹏 , 张铁臣 , 杜勇慧
作者信息
  • 吉林大学超硬材料国家重点实验室,吉林 长春 130012
通讯作者:
张铁臣(1943—),男,教授,博士生导师,主要研究方向为高温高压下材料合成. E-mail:
作者简介:

苏作鹏(1979—),男,博士研究生. E-mail:

The Reaction of Li3N-B2O3 and Mg-B2O3 under High-Temperation and High-Pressure
Zuo-Peng SU , Tie-Chen ZHANG , Yong-Hui DU
Affiliations
  • National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
出版时间: 2006-09-05
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通过B2O3与Mg和Li3N分别在不同温度压力条件下的反应,用X射线方法研究了生成物的物相。当采用Mg与B2O3为原料时,其产物是Mg3B2O6;用Li3N与B2O3反应时,产物中除了Li3BO3,还有立方氮化硼(cBN)生成。这表明,当原料中含有相同数量B2O3时,用Mg和Li3N分别作触媒合成立方氮化硼,将得到不同的结果。

触媒  /  B2O3  /  立方氮化硼

The reaction of Li3N-B2O3 and Mg-B2O3 under different pressure and temperature has been studied and the phase of the resultant has been analyzed by X-ray diffraction (XRD) method. XRD results show that when the starting material is Mg-B2O3, the major production is Mg3B2O6; When the starting material is Li3N-B2O3, cBN appears in the production. These results indicate that if the content of B2O3 is the same in the starting material, we will get different results, in the case of using Mg and Li3N as the catalyst respectively.

catalyst  /  B2O3  /  cubic boron nitride
苏作鹏, 张铁臣, 杜勇慧. 高压高温下B2O3与Mg和Li3N的反应. 高压物理学报, 2006 , 20 (3) : 277 -280 .
Zuo-Peng SU, Tie-Chen ZHANG, Yong-Hui DU. The Reaction of Li3N-B2O3 and Mg-B2O3 under High-Temperation and High-Pressure[J]. Chinese Journal of High Pressure Physics, 2006 , 20 (3) : 277 -280 .
  • 国家自然科学基金资助项目(10299040)
参考文献 引证文献
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[2]
Mishima O, Tanaka J, Yamaoka S, et al. High-Temperature Cubic Boron Nitride P-N Junction Diode Made at High Pressure[J]. Science, 1987, 238: 181-183.
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Tomikawa T, Nishibayashi Y, Shikata S. P-N Junction Diode by B-Doped Diamond Heteroepitaxially Grown on Si-Doped c-BN[J]. Diamond and Relat Mater, 1994, 3: 1398.
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Zhang T Ch, Wang Ch X, Gao Ch X. Cubic Boron Nitride Crystal-Diamond Film Heterojunction P-N Diode[J]. Chinese Journal of High Pressure Physics, 1999, 13(3): 169. (in Chinese)
张铁臣, 王成新, 高春晓. 立方氮化硼单晶-金刚石膜异质P-N结[J]. 高压物理学报, 1999, 13(3): 169.
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Bello I, Chong Y M, Leung K M, et al. Cubic Boron Nitride Films for Industrial Applications[J]. Diamond Relat Mater, 2005, 14: 1784-1790.
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Sato T, Hiraok H, Endo T. Effect of Oxygen on the Growth of Cubic Boron Nitride Using Mg3N2 as Catalyst[J]. J Materials Sci, 1981, 16: 2227.
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Singal S K, Park J K. Synthesis of Cubic Boron Nitride from Amorphous Boron Nitride Containing Oxide Impurity Using Mg-Al Alloy Catalyst Solvent[J]. J Crystal Growth, 2004, 260: 217-557.
2006年第20卷第3期
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  • 接收时间:2005-09-27
  • 首发时间:2026-11-01
  • 出版时间:2006-09-05
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  • 收稿日期:2005-09-27
  • 修回日期:2006-05-15
基金
国家自然科学基金资助项目(10299040)
作者信息
    吉林大学超硬材料国家重点实验室,吉林 长春 130012

通讯作者:

张铁臣(1943—),男,教授,博士生导师,主要研究方向为高温高压下材料合成. E-mail:
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
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红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
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