高压物理学报

地表柯石英的实验室模拟合成及其形成机制的研究

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刘曙娥 ¹^,² , 许大鹏 ¹ , 刘晓梅 ¹^,² , 苏文辉 ¹^,⁴ , 薜燕峰 ¹ , 孙敬姝 ¹^,²

高压物理学报 | 2006,20(2): 163-171

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高压物理学报 | 2006 , 20 (2) : 163 -171

地表柯石英的实验室模拟合成及其形成机制的研究

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刘曙娥¹^,², 许大鹏¹, 刘晓梅¹^,², 苏文辉¹^,⁴, 薜燕峰¹, 孙敬姝¹^,²

作者信息

^1.吉林大学稀土固体物理研究中心，吉林长春　130023

^2.哈尔滨工业大学凝聚态科学与技术研究中心，黑龙江省高校凝聚态科学与技术重点实验室，黑龙江哈尔滨　150001

^3.中国科学院国际材料物理中心，辽宁沈阳　110015

^4.中国高等科学技术中心（世界实验室），北京　100080

通讯作者:

苏文辉（1936—），男，教授，博士生导师，从事极端条件凝聚态物理学和无机材料合成物理与化学研究. E-mail：suwenhui@hit.edu.cn

作者简介:

刘曙娥（1977—），女，博士研究生，主要从事高压合成研究.

Modelling Synthesis in Laboratory of Coesite in the Earth's Crust and Its Formation Mechanism

Shu-E LIU¹^,², Da-Peng XU¹, Xiao-Mei LIU¹^,², Wen-Hui SU¹^,⁴, Yan-Feng XUE¹, Jing-Shu SUN¹^,²

Affiliations

^1.Center for Rare-Earth Solid State Physics, Jilin University, Changchun 130023, China

^2.Center for the Condensed-Matter Science and Technology, Harbin Institute of Technology, and Key Laboratory of Condensed-Matter Science and Technology, Heilongjiang Provincial Universities, Harbin 150001, China

^3.International Center for Materials Physics, Academia Sinica, Shenyang 110015, China

^4.Center for Condensed Matter and Radiation Physics, China Center of Advanced Science and Technology (World Laboratory), Beijing 100080, China

出版时间: 2006-06-05

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摘要

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静高压合成柯石英的压力和温度的实验条件是提出地球板块折返假说的基础，然而，静高压没有反映局部碰撞和剪切应力的因素。考虑这些因素，提出了一种利用高能机械球磨与静高压相结合的、可以模拟地表柯石英合成的实验室研究方法，发现了一种由机械碰撞引起的α-石英中间亚稳相，其静高压致晶化成柯石英的条件为3.0 GPa、923 K、<1.0 min。如果沿袭传统的板块折返假设，对应此条件的板块俯冲深度应比Jr. L. Coes的结果浅20 km。发现了10 s量级的柯石英的短时间快速合成现象。由本方法合成的柯石英的Raman峰，涵盖了以前得到的天然柯石英和人工合成的柯石英的Raman信息。阐明了由本方法合成的柯石英在地质科学上的涵义，并提出了另一种可能的地表柯石英形成机制。

关键词

石英-柯石英 / 高能机械球磨 / 静高压 / 地球板块折返 / Raman谱

Abstract

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The factors of collision and shear stress in the coesite formation has not been considered in the condition of high static pressure that was the base of the hypothesis of subduction-return of slab in the Earth. After considered these factors, a laboratory method of combining the high-energy mechanical ball milling (HEMBM) and high static pressure was suggested in this paper for modelling synthesis of coesite in the Earth's crust. A mechanical collision-induced intermediate phase of α-quartz has been discovered. Its condition of easily crystallizing into coesite induced by high static pressure is 3.0 GPa, 932 K, and < 1.0 min. The Raman peaks for the coesite synthesized by the present method have covered over the all information of those natural and synthesized coesite obtained before. This implicated that the coesite in the Earth's crust and subduction-return of slab maybe not come from as deep as common accepted value because of its lower pressure 3.0 GPa than that suggested by Jr. L. Coes. However, according to the fact discovered in this paper that the coesite could be synthesized under a condition of very short time (about 10 s) by the high static pressure after pre-treated of HEMBM, the intermediate phase of α-quartz could be transformed into coesite instantaneously by the interaction of an earthquake wave and/or stress. Therefore we suggest some other possible formation mechanisms for coesite in the Earth's crust and show that the coesite in the Earth's crust could record some information about the collision dynamics of plates and an earthquake wave.

Key words

quartz-coesite / high-energy mechanical ball milling / high static pressure / Raman spectroscopy / subduction-return of slab

引用本文

刘曙娥, 许大鹏, 刘晓梅, 苏文辉, 薜燕峰, 孙敬姝. 地表柯石英的实验室模拟合成及其形成机制的研究. 高压物理学报, 2006 , 20 (2) : 163 -171 .

Shu-E LIU, Da-Peng XU, Xiao-Mei LIU, Wen-Hui SU, Yan-Feng XUE, Jing-Shu SUN. Modelling Synthesis in Laboratory of Coesite in the Earth's Crust and Its Formation Mechanism[J]. Chinese Journal of High Pressure Physics, 2006 , 20 (2) : 163 -171 .

基金

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国家自然科学基金(10374022)

参考文献

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参考文献引证文献

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2006年第20卷第2期

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接收时间：2005-01-18
首发时间：2026-11-01
出版时间：2006-06-05

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收稿日期：2005-01-18
修回日期：2005-04-25

基金

国家自然科学基金(10374022)

作者信息

^1.吉林大学稀土固体物理研究中心，吉林长春　130023

^2.哈尔滨工业大学凝聚态科学与技术研究中心，黑龙江省高校凝聚态科学与技术重点实验室，黑龙江哈尔滨　150001

^3.中国科学院国际材料物理中心，辽宁沈阳　110015

^4.中国高等科学技术中心（世界实验室），北京　100080

通讯作者:

苏文辉（1936—），男，教授，博士生导师，从事极端条件凝聚态物理学和无机材料合成物理与化学研究. E-mail：suwenhui@hit.edu.cn

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https://castjournals.cast.org.cn/joweb/gywlxb/CN/1323703565931381717

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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