Article(id=1323703503062970846, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323703473736397109, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1126195200000, receivedDateStr=2005-09-09, revisedDate=1132156800000, revisedDateStr=2005-11-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793525108351, onlineDateStr=2026-11-01, pubDate=1141488000000, pubDateStr=2006-03-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793525108351, onlineIssueDateStr=2026-11-01, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793525108351, creator=13701087609, updateTime=1793525108351, updator=13701087609, issue=Issue{id=1323703473736397109, tenantId=1146029695717560320, journalId=1255847867265597444, year='2006', volume='20', issue='1', pageStart='1', pageEnd='112', issueExtLink='null', onlineDate='null', pubDate='1141488000000', pubDateStr='2006-03-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793525101360, creator='13701087609', updateTime=1793525101360, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=20, endPage=24, ext={EN=ArticleExt(id=1323703503239131615, articleId=1323703503062970846, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=A New Carbon Nitride Phase Synthesized by Shock Compression, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

To synthesize a carbon nitride with high density existing by theoretical prediction, a series of shock recovery experiments up to ≈50 GPa were carried out on two nitrogen-rich materials of a C-N-O amorphous precursor and dicyandiamide. The powder X-ray diffractions (XRD) of recovered samples show that the carbon nitride composite phases are formed consisting of β-C₃N₄ and a new crystalline phase. The new phase is indexed as a monoclinic cell with a=0.981 nm, b=0.723 nm, c=0.561 nm, β=95.2° and V_cell=0.396 6 nm³. We considered that this new phase is formed to survive as metastable species by extremely high quenching rate (≈10⁹ K/s) after transient shock-induced reaction of these organic precursors and so shock compression may provide a novel synthesis route for various carbon nitride phases from appropriate rich-nitrogen organic materials.

, authors=Jian-Jun LIU¹, T SEKINE², T KOBAYASHI², authorsList=Jian-Jun LIU, T SEKINE, T KOBAYASHI, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323703503448846816, articleId=1323703503062970846, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=一种新的氮化碳相的冲击波合成, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

为了合成理论预测存在的高密度氮化碳相，以富氮的C-N-O非晶材料和晶态的双氰胺为前体，在低于50 GPa的冲击压力范围内进行了一系列冲击回收实验。回收产物的XRD衍射表明，形成了由β-C₃N₄和一种新的氮化碳相组成的复合相。该新相的衍射峰可以完全指标化为一个单斜晶胞，晶胞常数为a=0.981 nm，b=0.723 nm，c=0.561 nm，β=95.2°，晶胞体积V_cell=0.396 6 nm³。根据实验结果可以认为，氮化碳复合相的形成是前体有机分子在瞬态的冲击波化学反应后，经历了极高速的冲击淬火过程（约10⁹ K/s），作为一种高压亚稳相而被保存下来。冲击压缩富氮的有机物前体，是合成氮化碳相的一种新方法。

, authors=刘建军¹, 关根利守², 小林敬道², authorsList=刘建军, 关根利守, 小林敬道, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=sttFZOVUUC7FBGTCJS99GQ==, magXml=zjMzsoQ3uaOTcDyhkPtKeQ==, pdfUrl=null, pdf=jSzkFpOkVIq+wx+jbd2xkQ==, pdfFileSize=383463, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=xkR/bW+JSi15S0FPQFMtCQ==, mapNumber=null, fund=null)}, authors=[Author(id=1323703505378226664, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1323703503062970846, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=liujj@mail.buct.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1323703505478889962, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1323703503062970846, authorId=1323703505378226664, language=EN, stringName=Jian-Jun LIU, firstName=Jian-Jun, middleName=null, lastName=LIU, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.Faculty of Sciences, Beijing University of Chemical Technology, Beijing 100029, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1323703505566970347, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1323703503062970846, authorId=1323703505378226664, language=CN, stringName=刘建军, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.北京化工大学理学院，北京　100029, bio={"content":"

刘建军（1971—），男，博士，副教授，主要研究方向为动、静压合成新材料. E-mail：liujj@mail.buct.edu.cn；ljj-717@163.com

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刘建军（1971—），男，博士，副教授，主要研究方向为动、静压合成新材料. E-mail：liujj@mail.buct.edu.cn；ljj-717@163.com

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