Article(id=1323358147561267848, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323358104632570190, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1036425600000, receivedDateStr=2002-11-05, revisedDate=1041436800000, revisedDateStr=2003-01-02, acceptedDate=null, acceptedDateStr=null, onlineDate=1793442769184, onlineDateStr=2026-10-31, pubDate=1062691200000, pubDateStr=2003-09-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793442769184, onlineIssueDateStr=2026-10-31, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793442769184, creator=13701087609, updateTime=1793442769184, updator=13701087609, issue=Issue{id=1323358104632570190, tenantId=1146029695717560320, journalId=1255847867265597444, year='2003', volume='17', issue='3', pageStart='161', pageEnd='240', issueExtLink='null', onlineDate='null', pubDate='1062691200000', pubDateStr='2003-09-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793442758949, creator='13701087609', updateTime=1793442847375, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1323358475585204938, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323358104632570190, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1323358475585204939, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323358104632570190, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=173, endPage=179, ext={EN=ArticleExt(id=1323358147737428617, articleId=1323358147561267848, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Study of Equation of State of the Dense Fluid He+H₂ Mixtures, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The mixing rule and the variational perturbation theory together with van der Waals one-fluid model have been used to study the equation of state of the dense fluid He+H₂ mixtures with different H₂∶He compositions in this work. The first-order quantum correction is included. To test the model and computational code, the isotherm of the fluid He+H₂ mixtures at 300 K is calculated by using the existing α-exp-6 optimization potential parameters. The calculated isotherm for the fluid He+H₂ mixtures is in agreement with the experimental data and molecular dynamics simulations. Then the equation of state of the fluid He+H₂ mixtures with different He∶H₂ (He∶H₂=1∶1, 1∶3, 3∶1) compositions have been further investigated in the pressure range 0~60 GPa and temperature in the range 50~7000 K. Comparisons of the present results with Monte-Carlo simulations indicate that the quantum corrections for the calculation of the thermodynamic properties become significant at lower temperatures.

, authors=Qi-Feng CHEN^{1, 2}, Ling-Cang CAI², Dong-Quan CHEN¹, Fu-Qian JING², Xian-Geng ZHAO¹, authorsList=Qi-Feng CHEN, Ling-Cang CAI, Dong-Quan CHEN, Fu-Qian JING, Xian-Geng ZHAO, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323358147930366602, articleId=1323358147561267848, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高密度流体He+H₂混合物物态方程研究, columnId=null, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

选择高密度流体He+H₂混合物作为研究对象，用Ree混合规则和van der Waals单组分流体变分微扰理论加量子力学一级修正模型编制计算程序。作为对计算模型及其程序的检验，首先用已有的α-exp-6优化势参数，计算了T=300 K的He+H₂混合物的等温相平衡线，得到了与实验值和分子动力学（MD）数值模拟一致的结果，然后进一步计算了0~60 GPa和50~7000 K压力温度范围内的流体He+H₂混合物（He∶H₂分别为1∶1、1∶3、3∶1摩尔比）的高压物态方程。与Monte-Carlo模拟数据所进行的比较表明，在低温下，量子力学修正对热力学量的计算是重要的。

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陈其峰（1962—），男，博士，教授，主要从事物态方程和原子分子碰撞理论研究工作.

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陈其峰（1962—），男，博士，教授，主要从事物态方程和原子分子碰撞理论研究工作.

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