Article(id=1323358081983316968, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1044979200000, receivedDateStr=2003-02-12, revisedDate=1058716800000, revisedDateStr=2003-07-21, acceptedDate=null, acceptedDateStr=null, onlineDate=1793442753548, onlineDateStr=2026-10-31, pubDate=1102176000000, pubDateStr=2004-12-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793442753548, onlineIssueDateStr=2026-10-31, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793442753548, creator=13701087609, updateTime=1793442753548, updator=13701087609, issue=Issue{id=1323357962957369719, tenantId=1146029695717560320, journalId=1255847867265597444, year='2004', volume='18', issue='4', pageStart='289', pageEnd='384', issueExtLink='null', onlineDate='null', pubDate='1102176000000', pubDateStr='2004-12-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793442725171, creator='13701087609', updateTime=1793442877122, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1323358600374133673, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1323358600374133674, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=359, endPage=363, ext={EN=ArticleExt(id=1323358082411135977, articleId=1323358081983316968, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Analysis of Graphite-Hexagonal Boron Nitride (g-hBN) Micro-Crystal Mixture Treated under High-Pressure and High-Temperature, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

For further research of the regularity of B-C-N material prepared by ball-milling method, the micro-crystal mixture of graphite-hexagonal boron nitride (g-hBN) is heat-treated under the pressure of 4.5~5.8 GPa and the temperature of 800 ℃~1 300 ℃. XRD, XPS and FT-IR analysis of the heat-treated products shows: at 4.5 GPa and 800 ℃, there is partial crystallization of hexagonal boron nitride (hBN) in samples, but the graphite keeps the status of micro-crystallization; and at 1 300 ℃, samples not only have crystallization of hBN but also have ternary compound of B-C-N, which is analogous to graphite structure. We considered that the new compound was approximate to BC3N when we had compared with correlative information of studies. When the pressure is up to 5.8 GPa and the temperature stays at 1 300 ℃, the changes of result are less.

, authors=Xiang-Jie LUO1, Bo-Cheng LUO2, Fang PENG1, Hao CHEN1, Li-Ye DING1, authorsList=Xiang-Jie LUO, Bo-Cheng LUO, Fang PENG, Hao CHEN, Li-Ye DING, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323358082813789162, articleId=1323358081983316968, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高压热处理石墨-六角氮化硼微晶混合物的结果分析, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

为了进一步研究用球磨法制备B-C-N物质的规律性,在4.5~5.8 GPa压力、800~1 300 ℃温度条件下,对用球磨法获得的石墨-六角氮化硼微晶混合物进行高压热处理。热处理后产物的XRD、XPS及FT-IR测试表明:在4.5 GPa、800 ℃时,样品中出现部分hBN晶化现象,但石墨仍然保持微晶状态;当温度升到1 300 ℃时,样品中不仅存在晶化的hBN,而且出现一种类石墨结构的B-C-N三元化合物。与相关研究资料对比后认为:这一新化合物近似于BC3N。压力增加到5.8 GPa而温度保持1 300 ℃时,结果变化不大。

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罗湘捷(1942—),男,教授. E-mail:

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高压热处理石墨-六角氮化硼微晶混合物的结果分析
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罗湘捷 1 , 罗伯诚 2 , 彭放 1 , 陈豪 1 , 丁立业 1
高压物理学报 | 2004,18(4): 359-363
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高压物理学报 | 2004 , 18 (4) : 359 -363
高压热处理石墨-六角氮化硼微晶混合物的结果分析
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罗湘捷1 , 罗伯诚2, 彭放1, 陈豪1, 丁立业1
作者信息
  • 1.四川大学原子与分子物理研究所,四川 成都 610065
  • 2.四川大学原子核科学与技术研究所,教育部辐射物理及技术重点实验室,四川 成都 610064
作者简介:

罗湘捷(1942—),男,教授. E-mail:

Analysis of Graphite-Hexagonal Boron Nitride (g-hBN) Micro-Crystal Mixture Treated under High-Pressure and High-Temperature
Xiang-Jie LUO1 , Bo-Cheng LUO2, Fang PENG1, Hao CHEN1, Li-Ye DING1
Affiliations
  • 1.Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
  • 2.Institute of Atomic Nucleus Science and Technology, Key Laboratory of Radiation Physics and Technology of Education Department, Sichuan University, Chengdu 610064, China
出版时间: 2004-12-05
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为了进一步研究用球磨法制备B-C-N物质的规律性,在4.5~5.8 GPa压力、800~1 300 ℃温度条件下,对用球磨法获得的石墨-六角氮化硼微晶混合物进行高压热处理。热处理后产物的XRD、XPS及FT-IR测试表明:在4.5 GPa、800 ℃时,样品中出现部分hBN晶化现象,但石墨仍然保持微晶状态;当温度升到1 300 ℃时,样品中不仅存在晶化的hBN,而且出现一种类石墨结构的B-C-N三元化合物。与相关研究资料对比后认为:这一新化合物近似于BC3N。压力增加到5.8 GPa而温度保持1 300 ℃时,结果变化不大。

石墨-六角氮化硼  /  微晶  /  高温高压  /  类石墨BC3N

For further research of the regularity of B-C-N material prepared by ball-milling method, the micro-crystal mixture of graphite-hexagonal boron nitride (g-hBN) is heat-treated under the pressure of 4.5~5.8 GPa and the temperature of 800 ℃~1 300 ℃. XRD, XPS and FT-IR analysis of the heat-treated products shows: at 4.5 GPa and 800 ℃, there is partial crystallization of hexagonal boron nitride (hBN) in samples, but the graphite keeps the status of micro-crystallization; and at 1 300 ℃, samples not only have crystallization of hBN but also have ternary compound of B-C-N, which is analogous to graphite structure. We considered that the new compound was approximate to BC3N when we had compared with correlative information of studies. When the pressure is up to 5.8 GPa and the temperature stays at 1 300 ℃, the changes of result are less.

graphite-hexagonal boron nitride  /  micro-crystallite  /  high-temperature and high-pressure  /  graphite-like BC3N
罗湘捷, 罗伯诚, 彭放, 陈豪, 丁立业. 高压热处理石墨-六角氮化硼微晶混合物的结果分析. 高压物理学报, 2004 , 18 (4) : 359 -363 .
Xiang-Jie LUO, Bo-Cheng LUO, Fang PENG, Hao CHEN, Li-Ye DING. Analysis of Graphite-Hexagonal Boron Nitride (g-hBN) Micro-Crystal Mixture Treated under High-Pressure and High-Temperature[J]. Chinese Journal of High Pressure Physics, 2004 , 18 (4) : 359 -363 .
  • 国家自然科学基金(59972021)
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罗湘捷, 彭放, 陈豪, 等. 石墨-六角氮化硼微晶混合物与水高压反应产物分析[J]. 高压物理学报, 2003, 17(2): 106-110.
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2004年第18卷第4期
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  • 接收时间:2003-02-12
  • 首发时间:2026-10-31
  • 出版时间:2004-12-05
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  • 收稿日期:2003-02-12
  • 修回日期:2003-07-21
基金
国家自然科学基金(59972021)
作者信息
    1.四川大学原子与分子物理研究所,四川 成都 610065
    2.四川大学原子核科学与技术研究所,教育部辐射物理及技术重点实验室,四川 成都 610064
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