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The (Sr, Ca)_n+1Cu_nO_2n (Cl, O)₂ superconducting homologous series have been briefly introduced. The emphasis is on the special charge reservoir block of the oxyhalide high T_c superconductror (HTSC), which consists of the halide layer instead of the routine oxide layer. Consequently the apical oxygen related to the p-type HTSC is missed in the compound whereas the apical chlorine bridges the conducting layer and the charge reservoir. In the context a novel hole doping mechanism named “apical oxygen doping” was introduced through partially substituting oxygen for chlorine. This chemical doping leads to an 80 K superconducting transition in the high pressure synthesized double layered (Sr, Ca)₃Cu₂O₄ (Cl, O)₂ oxyhalide. Not only the high T_c, the oxyhalide cuprate superconductor also demonstrates the comparable physical properties to those of the full oxide HTSC, indicating the promising prospects to develop new high T_c oxyhalide superconductors.

, authors=Chang-Qing JIN, authorsList=Chang-Qing JIN, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323358065659085604, articleId=1323358064195273506, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高温高压合成顶角氧掺杂型高温超导系列, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

简要介绍了（Sr，Ca）_n+1Cu_nO_2n（Cl，O）₂，即三元数法的Cl-“02n”（或四元数Cl-02（n-1）n）超导系列，简称Cl-系超导体。和通常的高温超导体不同，Cl-系的电荷库由卤化物构成，而非通常的氧化物。即Cl-系的导电区和电荷库由顶角氯连接，根据这一结构特点用"顶角氧"掺杂，高压合成了T_c≈80 K的（Sr，Ca）₃Cu₂O₄（Cl，O）₂超导体。该化合物具有和全氧化物高温超导体可比的超导性能，表明高温高压合成全新的卤氧超导新材料的潜力，以及开发卤氧化物高温超导体群的研究前景。

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靳常青（1965—），男，理学博士，研究员，博士生导师，主要研究方向为高压物理、功能材料物理和超导体. E-mail：cqjin@aphy.iphy.ac.cn

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靳常青（1965—），男，理学博士，研究员，博士生导师，主要研究方向为高压物理、功能材料物理和超导体. E-mail：cqjin@aphy.iphy.ac.cn

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