Article(id=1323358007979024919, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1058716800000, receivedDateStr=2003-07-21, revisedDate=1084809600000, revisedDateStr=2004-05-18, acceptedDate=null, acceptedDateStr=null, onlineDate=1793442735905, onlineDateStr=2026-10-31, pubDate=1102176000000, pubDateStr=2004-12-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793442735905, onlineIssueDateStr=2026-10-31, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793442735905, creator=13701087609, updateTime=1793442735905, updator=13701087609, issue=Issue{id=1323357962957369719, tenantId=1146029695717560320, journalId=1255847867265597444, year='2004', volume='18', issue='4', pageStart='289', pageEnd='384', issueExtLink='null', onlineDate='null', pubDate='1102176000000', pubDateStr='2004-12-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793442725171, creator='13701087609', updateTime=1793442877122, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1323358600374133673, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1323358600374133674, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357962957369719, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=368, endPage=373, ext={EN=ArticleExt(id=1323358008180351512, articleId=1323358007979024919, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Raman Spectroscopic Studies on Methanol as Pressure Gauge, columnId=1322942130796245184, journalTitle=Chinese Journal of High Pressure Physics, columnName=Research Note, runingTitle=null, highlight=null, articleAbstract=

This paper mainly studies Raman spectroscopy of C—H stretching vibrational mode of methanol at 2 835 cm^-1 from 169.2 up to 713.8 MPa under the temperature of 301 K using cubic zirconium oxide Anvil Cell. The result shows that methanol is stable at the experimental pressure, and the Raman shift of methanol at 2 835 cm^-1 shows a linear dependence with pressure. The correlation between pressure and frequency shift of the 2 835 cm^-1 Raman line of methanol is described by p=-3.508 9·[(Δν_p)_{2 835}]² + 135.17 (Δν_p)_{2 835}+54.397, where 0.1<p (MPa) ≤ 713.8. So methanol can be used as a reliable pressure gauge in high hydrostatic experiments.

, authors=Er-Wei QIAO, Hai-Fei ZHENG, Qiang SUN, authorsList=Er-Wei QIAO, Hai-Fei ZHENG, Qiang SUN, authorCompany=null, correspAuthors=Hai-Fei ZHENG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323358008486535705, articleId=1323358007979024919, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=甲醇作为压标的拉曼研究, columnId=1322942131614134466, journalTitle=高压物理学报, columnName=研究简报, runingTitle=null, highlight=null, articleAbstract=

利用立方氧化锆压腔研究了甲醇在温度301 K、压力169.2~713.8 MPa下C—H伸缩振动ν_{2 835}的拉曼特征，实验结果表明：在试验的压力范围内甲醇稳定，其拉曼位移和压力具有很好的线性关系。加上常压下的数据，拟合后得出压力与甲醇2 835 cm^-1拉曼线频率位移的关系为：p=-3.508 9 [（Δν_p）_{2 835}]² + 135.17（Δν_p）_{2 835}+54.397（0.1~713.8 MPa）。因此在实验的压力范围内甲醇作为压标非常合适。

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