Article(id=1323357963569725556, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1072022400000, receivedDateStr=2003-12-22, revisedDate=1078070400000, revisedDateStr=2004-03-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1793442725317, onlineDateStr=2026-10-31, pubDate=1094313600000, pubDateStr=2004-09-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793442725317, onlineIssueDateStr=2026-10-31, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793442725317, creator=13701087609, updateTime=1793442725317, updator=13701087609, issue=Issue{id=1323357842522124944, tenantId=1146029695717560320, journalId=1255847867265597444, year='2004', volume='18', issue='3', pageStart='193', pageEnd='288', issueExtLink='null', onlineDate='null', pubDate='1094313600000', pubDateStr='2004-09-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793442696457, creator='13701087609', updateTime=1793442871420, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1323358576437240742, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1323358576437240743, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=193, endPage=197, ext={EN=ArticleExt(id=1323357963733303413, articleId=1323357963569725556, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=The Structural Stability and Electrical Properties of Nanometer-Scale Sr2FeMoO6 Polycrystals under High Pressure, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Double perovskite structural compounds Sr2FeMoO6 powders with grain sizes of 50 nm (sample A) and 100 nm (sample B) have been synthesized using polymer-network gel method. Their structural stabilities and electrical properties under high pressure have been investigated. As compared with the result of bulk sample C with μm grain size obtained before, the sample A shows the largest bulk modulus B0 among the three and largest pressure region for the drop in the curve of resistance versus pressure. The results can be explained in terms of the effect of large amount grain boundaries in nanometer-scale materials. On the basis of the results of resistance and capacitance versus pressure, it is considered that both samples undergo an electronic structural transition under high pressure.

, authors=Jiang-Shan ZHANG1, 2, Bei E1, 3, Ri-Cheng YU1, Feng-Ying LI1, Xiao-Dong LI4, Yan-Chun LI4, Mai-Ning MA4, Jing LIU4, Zhen-Xing LIU1, Zhong-Xing BAO1, Chang-Gen FENG2, Chang-Qing JIN1, authorsList=Jiang-Shan ZHANG, Bei E, Ri-Cheng YU, Feng-Ying LI, Xiao-Dong LI, Yan-Chun LI, Mai-Ning MA, Jing LIU, Zhen-Xing LIU, Zhong-Xing BAO, Chang-Gen FENG, Chang-Qing JIN, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323357963968184438, articleId=1323357963569725556, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用高分子网络凝胶法,通过控制其化学反应过程,合成了高纯的多晶纳米级粉末Sr2FeMoO6样品A(50 nm)和样品B(100 nm)。对其在高压下的结构稳定性和电学性质进行了研究,并将样品A和样品B的实验结果与已报道的粒度达微米级的块状Sr2FeMoO6样品C的实验结果进行了对比。在实验测量范围内,样品A(50 nm)呈现出最大的体弹模量B0,并在电阻-压力曲线中,电阻下降区域表现出相对较缓的变化率,晶界效应可以用来很好地解释此结果。电学性质测量实验表明,样品在高压下发生了电子结构相变。

, authors=张江山1, 2, 鄂蓓1, 3, 禹日成1, 李凤英1, 李晓东4, 李延春4, 马麦宁4, 刘景4, 刘振兴1, 鲍忠兴1, 冯长根2, 靳常青1, authorsList=张江山, 鄂蓓, 禹日成, 李凤英, 李晓东, 李延春, 马麦宁, 刘景, 刘振兴, 鲍忠兴, 冯长根, 靳常青, authorCompany=null, correspAuthors=null, authorNote=

张江山(1959—),男,博士研究生,从事固体材料合成研究. E-mail:

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张江山(1959—),男,博士研究生,从事固体材料合成研究. E-mail:

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高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究
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张江山 1, 2 , 鄂蓓 1, 3 , 禹日成 1 , 李凤英 1 , 李晓东 4 , 李延春 4 , 马麦宁 4 , 刘景 4 , 刘振兴 1 , 鲍忠兴 1 , 冯长根 2 , 靳常青 1
高压物理学报 | 2004,18(3): 193-197
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高压物理学报 | 2004 , 18 (3) : 193 -197
高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究
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张江山(1959—),男,博士研究生,从事固体材料合成研究. E-mail:

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张江山(1959—),男,博士研究生,从事固体材料合成研究. E-mail:

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张江山1, 2 , 鄂蓓1, 3, 禹日成1, 李凤英1, 李晓东4, 李延春4, 马麦宁4, 刘景4, 刘振兴1, 鲍忠兴1, 冯长根2, 靳常青1
作者信息
  • 1.中国科学院物理研究所,北京 100080
  • 2.北京理工大学机电工程学院,北京 100081
  • 3.长春工业大学材料学院,吉林 长春 130012
  • 4.中国科学院高能物理研究所,北京 100039
作者简介:

张江山(1959—),男,博士研究生,从事固体材料合成研究. E-mail:

The Structural Stability and Electrical Properties of Nanometer-Scale Sr2FeMoO6 Polycrystals under High Pressure
Jiang-Shan ZHANG1, 2 , Bei E1, 3, Ri-Cheng YU1, Feng-Ying LI1, Xiao-Dong LI4, Yan-Chun LI4, Mai-Ning MA4, Jing LIU4, Zhen-Xing LIU1, Zhong-Xing BAO1, Chang-Gen FENG2, Chang-Qing JIN1
Affiliations
  • 1.Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China
  • 2.School of Mechano-Electronics Engineering, Beijing Institute of Technology, Beijing 100081, China
  • 3.Department of Material, Changchun University of Techonology, Changchun 130012, China
  • 4.Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China
出版时间: 2004-09-05
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采用高分子网络凝胶法,通过控制其化学反应过程,合成了高纯的多晶纳米级粉末Sr2FeMoO6样品A(50 nm)和样品B(100 nm)。对其在高压下的结构稳定性和电学性质进行了研究,并将样品A和样品B的实验结果与已报道的粒度达微米级的块状Sr2FeMoO6样品C的实验结果进行了对比。在实验测量范围内,样品A(50 nm)呈现出最大的体弹模量B0,并在电阻-压力曲线中,电阻下降区域表现出相对较缓的变化率,晶界效应可以用来很好地解释此结果。电学性质测量实验表明,样品在高压下发生了电子结构相变。

钙钛矿结构  /  巨磁阻效应  /  晶界效应

Double perovskite structural compounds Sr2FeMoO6 powders with grain sizes of 50 nm (sample A) and 100 nm (sample B) have been synthesized using polymer-network gel method. Their structural stabilities and electrical properties under high pressure have been investigated. As compared with the result of bulk sample C with μm grain size obtained before, the sample A shows the largest bulk modulus B0 among the three and largest pressure region for the drop in the curve of resistance versus pressure. The results can be explained in terms of the effect of large amount grain boundaries in nanometer-scale materials. On the basis of the results of resistance and capacitance versus pressure, it is considered that both samples undergo an electronic structural transition under high pressure.

perovskite structure  /  magnetoresistance  /  grain boundary effect
张江山, 鄂蓓, 禹日成, 李凤英, 李晓东, 李延春, 马麦宁, 刘景, 刘振兴, 鲍忠兴, 冯长根, 靳常青. 高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究. 高压物理学报, 2004 , 18 (3) : 193 -197 .
Jiang-Shan ZHANG, Bei E, Ri-Cheng YU, Feng-Ying LI, Xiao-Dong LI, Yan-Chun LI, Mai-Ning MA, Jing LIU, Zhen-Xing LIU, Zhong-Xing BAO, Chang-Gen FENG, Chang-Qing JIN. The Structural Stability and Electrical Properties of Nanometer-Scale Sr2FeMoO6 Polycrystals under High Pressure[J]. Chinese Journal of High Pressure Physics, 2004 , 18 (3) : 193 -197 .
  • 国家自然科学基金(10274099; 50328102)
  • 国家重点基础研究发展项目(2002CB613301)
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2004年第18卷第3期
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  • 接收时间:2003-12-22
  • 首发时间:2026-10-31
  • 出版时间:2004-09-05
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  • 收稿日期:2003-12-22
  • 修回日期:2004-03-01
基金
国家自然科学基金(10274099; 50328102)
国家重点基础研究发展项目(2002CB613301)
作者信息
    1.中国科学院物理研究所,北京 100080
    2.北京理工大学机电工程学院,北京 100081
    3.长春工业大学材料学院,吉林 长春 130012
    4.中国科学院高能物理研究所,北京 100039
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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