Article(id=1323357874700821103, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1068998400000, receivedDateStr=2003-11-17, revisedDate=1079452800000, revisedDateStr=2004-03-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793442704128, onlineDateStr=2026-10-31, pubDate=1094313600000, pubDateStr=2004-09-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793442704128, onlineIssueDateStr=2026-10-31, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793442704128, creator=13701087609, updateTime=1793442704128, updator=13701087609, issue=Issue{id=1323357842522124944, tenantId=1146029695717560320, journalId=1255847867265597444, year='2004', volume='18', issue='3', pageStart='193', pageEnd='288', issueExtLink='null', onlineDate='null', pubDate='1094313600000', pubDateStr='2004-09-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793442696457, creator='13701087609', updateTime=1793442871420, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1323358576437240742, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1323358576437240743, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1323357842522124944, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=220, endPage=224, ext={EN=ArticleExt(id=1323357874881176176, articleId=1323357874700821103, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Study of the Products of C3N6H6 Treated at High Temperature and High Pressure, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

A black-brown powder was synthesized from melamine (C3N6H6) by means of high temperature and high pressure. Based on the analysis of X-ray diffraction patterns, the powder is composed of some un-decomposed raw material, carbon and intermediate phases. The existence of the intermediate phase with long periodicity along one direction is confirmed from transmission electron microscopy observation; Scanning electron microscopy shows many block tissues, in which a few holes exist; The atomic ratio of carbon and nitrogen is determined as 3.27∶1 in the powder from the measurement of Energy Dispersive X-ray Analysis. The high content of C is caused by the existence of carbon decomposed from the raw materials. In addition, the chemical bond states are investigated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. As a result, the main bond styles in the powder are described as C (sp2) N and C (sp2) —N.

, authors=Li-De YAO1, 2, Ri-Cheng YU1, Feng-Ying LI1, Zhen-Xing LIU1, Ji-Xue LI2, Chang-Qing JIN1, authorsList=Li-De YAO, Ri-Cheng YU, Feng-Ying LI, Zhen-Xing LIU, Ji-Xue LI, Chang-Qing JIN, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1323357875246080625, articleId=1323357874700821103, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高温高压下C3N6H6分解产物的研究, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用高温高压方法分解缩聚三聚氰胺(C3N6H6),得到一种棕黑色粉末。经过X射线粉末衍射分析,产物主要由未完全分解的原料、碳和分解过程中的过渡相组成。透射电镜观察结果显示,过渡相在某一方向具有长周期结构;在扫描电镜下观察形貌,产物为片状组织,且其中有少量气孔;X射线能散结果表明,C∶N≈3.27∶1(原子比);此外,进行了红外吸收谱和X射线光电子能谱测试,产物主要键合状态是C(sp2)N和C(sp2)—N。

, authors=姚立德1, 2, 禹日成1, 李凤英1, 刘振兴1, 李吉学2, 靳常青1, authorsList=姚立德, 禹日成, 李凤英, 刘振兴, 李吉学, 靳常青, authorCompany=null, correspAuthors=null, authorNote=

姚立德(1976—),男,硕士研究生,主要研究方向为巨磁致电阻材料的高压合成及其物性研究,电荷有序态在高压下的变化. E-mail:

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姚立德(1976—),男,硕士研究生,主要研究方向为巨磁致电阻材料的高压合成及其物性研究,电荷有序态在高压下的变化. E-mail:

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姚立德(1976—),男,硕士研究生,主要研究方向为巨磁致电阻材料的高压合成及其物性研究,电荷有序态在高压下的变化. E-mail:

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高温高压下C3N6H6分解产物的研究
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姚立德 1, 2 , 禹日成 1 , 李凤英 1 , 刘振兴 1 , 李吉学 2 , 靳常青 1
高压物理学报 | 2004,18(3): 220-224
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高压物理学报 | 2004 , 18 (3) : 220 -224
高温高压下C3N6H6分解产物的研究
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姚立德(1976—),男,硕士研究生,主要研究方向为巨磁致电阻材料的高压合成及其物性研究,电荷有序态在高压下的变化. E-mail:

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姚立德1, 2 , 禹日成1, 李凤英1, 刘振兴1, 李吉学2, 靳常青1
作者信息
  • 1.中国科学院物理研究所,北京 100080
  • 2.长春工业大学材料科学与工程学院,吉林 长春 130012
作者简介:

姚立德(1976—),男,硕士研究生,主要研究方向为巨磁致电阻材料的高压合成及其物性研究,电荷有序态在高压下的变化. E-mail:

Study of the Products of C3N6H6 Treated at High Temperature and High Pressure
Li-De YAO1, 2 , Ri-Cheng YU1, Feng-Ying LI1, Zhen-Xing LIU1, Ji-Xue LI2, Chang-Qing JIN1
Affiliations
  • 1.Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China
  • 2.Department of Material, Changchun University of Techonology, Changchun 130012, China
出版时间: 2004-09-05
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采用高温高压方法分解缩聚三聚氰胺(C3N6H6),得到一种棕黑色粉末。经过X射线粉末衍射分析,产物主要由未完全分解的原料、碳和分解过程中的过渡相组成。透射电镜观察结果显示,过渡相在某一方向具有长周期结构;在扫描电镜下观察形貌,产物为片状组织,且其中有少量气孔;X射线能散结果表明,C∶N≈3.27∶1(原子比);此外,进行了红外吸收谱和X射线光电子能谱测试,产物主要键合状态是C(sp2)N和C(sp2)—N。

碳氮晶体  /  高温高压  /  C3N6H6  /  键合状态

A black-brown powder was synthesized from melamine (C3N6H6) by means of high temperature and high pressure. Based on the analysis of X-ray diffraction patterns, the powder is composed of some un-decomposed raw material, carbon and intermediate phases. The existence of the intermediate phase with long periodicity along one direction is confirmed from transmission electron microscopy observation; Scanning electron microscopy shows many block tissues, in which a few holes exist; The atomic ratio of carbon and nitrogen is determined as 3.27∶1 in the powder from the measurement of Energy Dispersive X-ray Analysis. The high content of C is caused by the existence of carbon decomposed from the raw materials. In addition, the chemical bond states are investigated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. As a result, the main bond styles in the powder are described as C (sp2) N and C (sp2) —N.

carbon nitride  /  high temperature and high pressure  /  C3N6H6  /  bond styles
姚立德, 禹日成, 李凤英, 刘振兴, 李吉学, 靳常青. 高温高压下C3N6H6分解产物的研究. 高压物理学报, 2004 , 18 (3) : 220 -224 .
Li-De YAO, Ri-Cheng YU, Feng-Ying LI, Zhen-Xing LIU, Ji-Xue LI, Chang-Qing JIN. Study of the Products of C3N6H6 Treated at High Temperature and High Pressure[J]. Chinese Journal of High Pressure Physics, 2004 , 18 (3) : 220 -224 .
  • 国家自然科学基金
  • 国家重点基础研究发展规划项目(2002CB613301)
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  • 接收时间:2003-11-17
  • 首发时间:2026-10-31
  • 出版时间:2004-09-05
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  • 收稿日期:2003-11-17
  • 修回日期:2004-03-17
基金
国家自然科学基金
国家重点基础研究发展规划项目(2002CB613301)
作者信息
    1.中国科学院物理研究所,北京 100080
    2.长春工业大学材料科学与工程学院,吉林 长春 130012
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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