Article(id=1322971711360082498, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1322971592304763246, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1215532800000, receivedDateStr=2008-07-09, revisedDate=1252252800000, revisedDateStr=2009-09-07, acceptedDate=null, acceptedDateStr=null, onlineDate=1793350635613, onlineDateStr=2026-10-30, pubDate=1260806400000, pubDateStr=2009-12-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793350635613, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793350635613, creator=13701087609, updateTime=1793350635613, updator=13701087609, issue=Issue{id=1322971592304763246, tenantId=1146029695717560320, journalId=1255847867265597444, year='2009', volume='23', issue='6', pageStart='401', pageEnd='480', issueExtLink='null', onlineDate='null', pubDate='1260806400000', pubDateStr='2009-12-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793350607229, creator='13701087609', updateTime=1793350607229, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=467, endPage=470, ext={EN=ArticleExt(id=1322971715608912455, articleId=1322971711360082498, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Thermodynamic Analysis of Cubic Boron Nitride Synthesized under HPHT, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

We analyzed the relationships between growth condition and phase transition probability, and critical crystal radius respectively by thermodynamics. Then we calculated the critical grain radius r_k for forming cBN crystal under high pressure and high temperature (HPHT). Under 6.0 GPa, 1 600 ℃, the r_k is around 15 nm. In the thermodynamically stable region of cBN, the results show that under the same pressure, r_k is increasing with the elevated temperature; under the same temperature, r_k is decreasing with increasing pressure, and the smaller r_k is, the higher phase transition probability is. These results are well consistent with experimental data.

, authors=Xiao-Rui JI¹, Da-Peng YANG², Xiao-Hong YANG¹, Tie-Chen ZHANG^{3, 4}, authorsList=Xiao-Rui JI, Da-Peng YANG, Xiao-Hong YANG, Tie-Chen ZHANG, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322971719002104395, articleId=1322971711360082498, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高温高压合成立方氮化硼的热力学分析, columnId=0, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

从热力学角度计算出了以六角氮化硼为原料、用高压触媒法合成立方氮化硼时所形成稳定的临界晶粒半径r_k的大小，当p=6.0 GPa、T=1 600 ℃时，r_k≈15 nm。分析了r_k的大小与合成温度、压力的关系，以及在给定压力下立方氮化硼晶粒转化率与温度的关系。结果表明：在立方氮化硼稳定区，在相同压力下，r_k随温度的升高而增大；在相同温度下，r_k随压力的升高而减小，r_k越小立方氮化硼晶粒的转化率越高。计算结果与实际合成实验所得结果完全一致。

, authors=吉晓瑞¹, 杨大鹏², 杨晓红¹, 张铁臣^{3, 4}, authorsList=吉晓瑞, 杨大鹏, 杨晓红, 张铁臣, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=ojJCABMFhcdRK1pMw5fAfA==, magXml=fndmfgx0SDoohwpoU3bEAg==, pdfUrl=null, pdf=O68efdZMS7/D66CP+EHAVQ==, pdfFileSize=327286, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=8HoavvFmiRyv4KZjvuJuFg==, mapNumber=null, fund=null)}, authors=[Author(id=1322971725633299035, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1322971711360082498, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=xiaoruiji@yahoo.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322971726883201629, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1322971711360082498, authorId=1322971725633299035, language=EN, stringName=Xiao-Rui JI, firstName=Xiao-Rui, middleName=null, lastName=JI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.Department of Preparatory Course, Shenyang Institute of Engineering, Shenyang 110136, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322971728221184607, tenantId=1146029695717560320, journalId=1255847867265597444, articleId=1322971711360082498, authorId=1322971725633299035, language=CN, stringName=吉晓瑞, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.沈阳工程学院基础教学部，辽宁 沈阳　110136, bio={"content":"

吉晓瑞（1980—），男，博士，讲师，主要从事高温高压下的材料合成研究. E-mail：xiaoruiji@yahoo.cn

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吉晓瑞（1980—），男，博士，讲师，主要从事高温高压下的材料合成研究. E-mail：xiaoruiji@yahoo.cn

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