Article(id=1322946645654123156, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1322946627157238386, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1239724800000, receivedDateStr=2009-04-15, revisedDate=1243267200000, revisedDateStr=2009-05-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344659484, onlineDateStr=2026-10-30, pubDate=1250265600000, pubDateStr=2009-08-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344659484, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344659484, creator=13701087609, updateTime=1793344659484, updator=13701087609, issue=Issue{id=1322946627157238386, tenantId=1146029695717560320, journalId=1255847867265597444, year='2009', volume='23', issue='4', pageStart='241', pageEnd='320', issueExtLink='null', onlineDate='null', pubDate='1250265600000', pubDateStr='2009-08-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793344655074, creator='13701087609', updateTime=1793344655074, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=305, endPage=309, ext={EN=ArticleExt(id=1322946645813506709, articleId=1322946645654123156, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Raman Scattering Studies of n-Octane under High Pressure, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

High pressure Raman spectra of n-octane were investigated by diamond anvil cell (DAC) at pressure up to 7 GPa and ambient temperature. The result shows that the liquid-solid phase transition of n-octane takes place around 0.8 GPa. Within the experimental pressure range, the Raman shift of n-octane moves to higher frequency, while the peak intensity decreases, and the width of peaks broaden with increasing pressure. A turning point is observed in the curve of pressure-dependent Raman shift when the pressure increases up to 6.8 GPa. This result indicates that a solid-solid phase transition for n-octane has been finished at this pressure. The pressure-induced phase transition pressure in alkanes decreases with the length of their chains increasing.

, authors=Xiao-Xin WU¹, Min LI², Fang-Fei LI², Qiang ZHOU², Wei GAO², Qi-Liang CUI², Guang-Tian ZOU², authorsList=Xiao-Xin WU, Min LI, Fang-Fei LI, Qiang ZHOU, Wei GAO, Qi-Liang CUI, Guang-Tian ZOU, authorCompany=null, correspAuthors=Wei GAO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322946646006444694, articleId=1322946645654123156, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=正辛烷的高压拉曼光谱研究, columnId=null, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用金刚石对顶砧高压装置，在室温下对正辛烷（C₈H₁8）进行了原位高压拉曼光谱研究，实验的最高压力为13 GPa。在实验的压力范围内，正辛烷的拉曼峰位随压力的升高均向高频移动，峰强逐渐减弱，峰形变宽。常态为液态的正辛烷在0.8 GPa时，拉曼频移随压力的变化曲线出现了拐点，发生了液-固相变；在6.8 GPa时，伴随着原拉曼峰的消失或劈裂，以及新拉曼峰的出现，此时正辛烷可能发生了固-固相变。该相变压力低于已有的低碳数正烃烷的压致相变结果。正烃烷的压致相变压力点，具有随着结构链长的增加，其相变压力降低的规律。

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武晓鑫（1987—），女，大学本科，主要研究方向为材料物理. E-mail：xxpuppy@126.com

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武晓鑫（1987—），女，大学本科，主要研究方向为材料物理. E-mail：xxpuppy@126.com

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