Article(id=1322943306560319546, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1322943296305247200, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1215964800000, receivedDateStr=2008-07-14, revisedDate=1224000000000, revisedDateStr=2008-10-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343863381, onlineDateStr=2026-10-30, pubDate=1239724800000, pubDateStr=2009-04-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343863381, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343863381, creator=13701087609, updateTime=1793343863381, updator=13701087609, issue=Issue{id=1322943296305247200, tenantId=1146029695717560320, journalId=1255847867265597444, year='2009', volume='23', issue='2', pageStart='81', pageEnd='160', issueExtLink='null', onlineDate='null', pubDate='1239724800000', pubDateStr='2009-04-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343860936, creator='13701087609', updateTime=1793343860936, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=87, endPage=90, ext={EN=ArticleExt(id=1322943306740674619, articleId=1322943306560319546, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=High Pressure Synthesis and Electric Transport Properties of La-Filled CoSb3 Skutterudite Thermoelectric Materials, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=null, runingTitle=null, highlight=null, articleAbstract=

La-filled skutterudite compounds LaxCo4Sb12 (0<x≤1.0) were successfully synthesized at 3.5 GPa and 900 K. The X-ray diffraction results indicate that all synthesized samples exist as a single phase with a crystal structure of CoSb3. The composition-dependent electric transport properties of La-filled CoSb3 have been studied at room temperature. The lattice parameters of the samples increase gradually with the increasing of La content. No La phase is found in the range of x from 0.1 to 1.0. The La-filled skutterudite is p type semiconductor. The electrical resistivity and Seebeck coefficient increase firstly with the increasing of La content and then decrease. When the La content x is 0.3, the electrical resistivity and Seebeck coefficient both reach the maximum value. The maximum power factor is obtained when the La content x is 0.5.

, authors=Yi-Ping JIANG1, 2, Xiao-Peng JIA1, Hong-An MA1, Tai-Chao SU1, Nan DONG1, Le DENG1, authorsList=Yi-Ping JIANG, Xiao-Peng JIA, Hong-An MA, Tai-Chao SU, Nan DONG, Le DENG, authorCompany=null, correspAuthors=Hong-An MA, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943306988138556, articleId=1322943306560319546, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=高压合成La填充型CoSb3方钴矿热电材料及其电输运性能, columnId=null, journalTitle=高压物理学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用高温高压手段,在压力3.5 GPa、温度900 K的条件下,成功合成出La填充型方钴矿热电材料LaxCo4Sb12(0<x≤1.0),系统地研究了样品的晶体结构和电输运性能随填充分数x的变化关系。研究结果表明:在最大填充分数x为0~1.0的范围内,随着La填充分数的增加,样品的晶胞常数稍有增大,晶体结构仍为典型的方钴矿结构,没有La杂质相出现。室温下样品的电输运性能测试结果表明:La填充型方钴矿为p型半导体;样品的电阻率和Seebeck系数随La含量的增加均呈现出先增加后逐渐降低的趋势;当填充分数x为0.3时,样品的Seebeck系数和电阻率均达到了最大值;功率因子在x=0.5时达到了最大值。

, authors=姜一平1, 2, 贾晓鹏1, 马红安1, 宿太超1, 董楠1, 邓乐1, authorsList=姜一平, 贾晓鹏, 马红安, 宿太超, 董楠, 邓乐, authorCompany=null, correspAuthors=马红安, authorNote=

姜一平(1978—),女,博士研究生,主要从事热电材料的高压合成研究.

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马红安(1974—),男,博士,教授,主要从事超硬和功能材料的高压合成研究. E-mail:
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高压合成La填充型CoSb3方钴矿热电材料及其电输运性能
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姜一平 1, 2 , 贾晓鹏 1 , 马红安 1 , 宿太超 1 , 董楠 1 , 邓乐 1
高压物理学报 | 2009,23(2): 87-90
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高压物理学报 | 2009 , 23 (2) : 87 -90
高压合成La填充型CoSb3方钴矿热电材料及其电输运性能
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姜一平(1978—),女,博士研究生,主要从事热电材料的高压合成研究.

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姜一平(1978—),女,博士研究生,主要从事热电材料的高压合成研究.

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姜一平1, 2, 贾晓鹏1, 马红安1 , 宿太超1, 董楠1, 邓乐1
作者信息
  • 1.吉林大学超硬材料国家重点实验室,吉林 长春 130012
  • 2.北华大学物理学院,吉林 吉林 132013
通讯作者:
马红安(1974—),男,博士,教授,主要从事超硬和功能材料的高压合成研究. E-mail:
作者简介:

姜一平(1978—),女,博士研究生,主要从事热电材料的高压合成研究.

High Pressure Synthesis and Electric Transport Properties of La-Filled CoSb3 Skutterudite Thermoelectric Materials
Yi-Ping JIANG1, 2, Xiao-Peng JIA1, Hong-An MA1 , Tai-Chao SU1, Nan DONG1, Le DENG1
Affiliations
  • 1.National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
  • 2.Department of physics, Beihua University, Jilin 132013, China
出版时间: 2009-04-15
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采用高温高压手段,在压力3.5 GPa、温度900 K的条件下,成功合成出La填充型方钴矿热电材料LaxCo4Sb12(0<x≤1.0),系统地研究了样品的晶体结构和电输运性能随填充分数x的变化关系。研究结果表明:在最大填充分数x为0~1.0的范围内,随着La填充分数的增加,样品的晶胞常数稍有增大,晶体结构仍为典型的方钴矿结构,没有La杂质相出现。室温下样品的电输运性能测试结果表明:La填充型方钴矿为p型半导体;样品的电阻率和Seebeck系数随La含量的增加均呈现出先增加后逐渐降低的趋势;当填充分数x为0.3时,样品的Seebeck系数和电阻率均达到了最大值;功率因子在x=0.5时达到了最大值。

La  /  方钴矿  /  高温高压  /  热电材料

La-filled skutterudite compounds LaxCo4Sb12 (0<x≤1.0) were successfully synthesized at 3.5 GPa and 900 K. The X-ray diffraction results indicate that all synthesized samples exist as a single phase with a crystal structure of CoSb3. The composition-dependent electric transport properties of La-filled CoSb3 have been studied at room temperature. The lattice parameters of the samples increase gradually with the increasing of La content. No La phase is found in the range of x from 0.1 to 1.0. The La-filled skutterudite is p type semiconductor. The electrical resistivity and Seebeck coefficient increase firstly with the increasing of La content and then decrease. When the La content x is 0.3, the electrical resistivity and Seebeck coefficient both reach the maximum value. The maximum power factor is obtained when the La content x is 0.5.

La  /  skutterudite  /  high temperature and high pressure  /  thermoelectric material
姜一平, 贾晓鹏, 马红安, 宿太超, 董楠, 邓乐. 高压合成La填充型CoSb3方钴矿热电材料及其电输运性能. 高压物理学报, 2009 , 23 (2) : 87 -90 .
Yi-Ping JIANG, Xiao-Peng JIA, Hong-An MA, Tai-Chao SU, Nan DONG, Le DENG. High Pressure Synthesis and Electric Transport Properties of La-Filled CoSb3 Skutterudite Thermoelectric Materials[J]. Chinese Journal of High Pressure Physics, 2009 , 23 (2) : 87 -90 .
  • 国家自然科学基金(50731006; 50801030)
  • 吉林大学985工程研究生创新基金(20080219)
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2009年第23卷第2期
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  • 接收时间:2008-07-14
  • 首发时间:2026-10-30
  • 出版时间:2009-04-15
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  • 收稿日期:2008-07-14
  • 修回日期:2008-10-15
基金
国家自然科学基金(50731006; 50801030)
吉林大学985工程研究生创新基金(20080219)
作者信息
    1.吉林大学超硬材料国家重点实验室,吉林 长春 130012
    2.北华大学物理学院,吉林 吉林 132013

通讯作者:

马红安(1974—),男,博士,教授,主要从事超硬和功能材料的高压合成研究. E-mail:
参考文献
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小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
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