Article(id=1322942644963385775, tenantId=1146029695717560320, journalId=1255847867265597444, issueId=1322941937514316514, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1182700800000, receivedDateStr=2007-06-25, revisedDate=1188835200000, revisedDateStr=2007-09-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343705644, onlineDateStr=2026-10-30, pubDate=1228406400000, pubDateStr=2008-12-05, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343705644, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343705644, creator=13701087609, updateTime=1793343705644, updator=13701087609, issue=Issue{id=1322941937514316514, tenantId=1146029695717560320, journalId=1255847867265597444, year='2008', volume='22', issue='4', pageStart='337', pageEnd='448', issueExtLink='null', onlineDate='null', pubDate='1228406400000', pubDateStr='2008-12-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343536975, creator='13701087609', updateTime=1793343536975, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=397, endPage=401, ext={EN=ArticleExt(id=1322942645668028848, articleId=1322942644963385775, tenantId=1146029695717560320, journalId=1255847867265597444, language=EN, title=Property Comparison of Porous Graphite Nanopowders Prepared by Detonation Splitting Technique with Different Acid Content, columnId=null, journalTitle=Chinese Journal of High Pressure Physics, columnName=, runingTitle=null, highlight=null, articleAbstract=

N2 adsorption/desorption isotherms and pore diameter distribution of the porous graphite nanopowders, prepared by detonation splitting technique with different acid content in raw materials, were analyzed using Brunauer-Emmet-Teller (BET) equation and Barrett-Joyner-Halenda (BJH) method. The results indicate that there exists hysteresis phenomenon in the product isotherms and the corresponding BET surface area is 5.3~9.2 times of the natural flake graphite which is increasing with the acid content in raw materials. The difference of the BET surface area among the detonation soot is mainly caused by the pore of which diameter distributes between 3 nm and 7 nm. Moreover, the amount of the pore size at about 4 nm arrived at the maximum after detonation. In addition, the research provides sorption capacity information for application and at the same time it also proves that acid has perfect impact on preparing graphite nanopowders.

, authors=Gui-Lei SUN1, 2, Xiao-Jie LI2, Hong-Hao YAN2, Xiao-Hong WANG2, De-An JIANG2, authorsList=Gui-Lei SUN, Xiao-Jie LI, Hong-Hao YAN, Xiao-Hong WANG, De-An JIANG, authorCompany=null, correspAuthors=Xiao-Jie LI, authorNote=

SUN Gui-Lei (1980—), male, engaged in nanocarbon materials researching. E-mail:

, correspAuthorsNote=
LI Xiao-Jie (1963—), male, PH.D., professor, engaged in explosion mechanics, reaching on material synthesis. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=Moq5nk5V02fjWAG/u3Tpcw==, magXml=DudimALlRR15+wrCeRjYQw==, pdfUrl=null, pdf=d1fGAoZqiMZ3b3LlGZEXbg==, pdfFileSize=370637, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=egNDpgk+NynNcnWoohdUHA==, mapNumber=null, fund=null), CN=ArticleExt(id=1322942645823218097, articleId=1322942644963385775, tenantId=1146029695717560320, journalId=1255847867265597444, language=CN, title=爆轰裂解法制备纳米石墨粉的吸附性能研究, columnId=null, journalTitle=高压物理学报, columnName=null, runingTitle=null, highlight=null, articleAbstract=

在酸含量不同的原材料中,通过爆轰的方法制备纳米石墨粉,并利用BET方程以及BJH方法对所得纳米石墨粉进行比表面积和孔径分布分析。分析结果表明,所得爆轰产物中有的比表面积大致为天然鳞片石墨的5.3~9.2倍,而且随酸含量的增大逐渐增大,产物的等温线中存在吸附滞后现象。其中,增大的比表面积主要由分布在3 nm至7 nm之间的孔引起的,而且在爆轰后,孔径4 nm左右的孔,其数量达到最大值。通过对纳米石墨粉的研究,分析了酸在爆轰过程中的积极作用,并为纳米石墨粉的进一步应用提供了结构信息。

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爆轰裂解法制备纳米石墨粉的吸附性能研究
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孙贵磊 1, 2 , 李晓杰 2 , 闫鸿浩 2 , 王小红 2 , 江德安 2
高压物理学报 | 2008,22(4): 397-401
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高压物理学报 2008 , 22 (4) : 397 -401
爆轰裂解法制备纳米石墨粉的吸附性能研究
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孙贵磊1, 2 , 李晓杰2 , 闫鸿浩2, 王小红2, 江德安2
作者信息
  • 1.中国劳动关系学院,北京 100037
  • 2.大连理工大学工业装备结构分析国家重点实验室,辽宁 大连 116023
通讯作者:
李晓杰
Property Comparison of Porous Graphite Nanopowders Prepared by Detonation Splitting Technique with Different Acid Content
Gui-Lei SUN1, 2 , Xiao-Jie LI2 , Hong-Hao YAN2, Xiao-Hong WANG2, De-An JIANG2
Affiliations
  • 1.China Institute of Industrial Relations, Beijing 100037, China
  • 2.State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023, China
  • Corresponding Author:
    LI Xiao-Jie (1963—), male, PH.D., professor, engaged in explosion mechanics, reaching on material synthesis. E-mail:

    SUN Gui-Lei (1980—), male, engaged in nanocarbon materials researching. E-mail:

出版时间: 2008-12-05
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在酸含量不同的原材料中,通过爆轰的方法制备纳米石墨粉,并利用BET方程以及BJH方法对所得纳米石墨粉进行比表面积和孔径分布分析。分析结果表明,所得爆轰产物中有的比表面积大致为天然鳞片石墨的5.3~9.2倍,而且随酸含量的增大逐渐增大,产物的等温线中存在吸附滞后现象。其中,增大的比表面积主要由分布在3 nm至7 nm之间的孔引起的,而且在爆轰后,孔径4 nm左右的孔,其数量达到最大值。通过对纳米石墨粉的研究,分析了酸在爆轰过程中的积极作用,并为纳米石墨粉的进一步应用提供了结构信息。

纳米石墨粉  /  吸附/脱附等温线  /  孔径分布  /  爆轰技术

N2 adsorption/desorption isotherms and pore diameter distribution of the porous graphite nanopowders, prepared by detonation splitting technique with different acid content in raw materials, were analyzed using Brunauer-Emmet-Teller (BET) equation and Barrett-Joyner-Halenda (BJH) method. The results indicate that there exists hysteresis phenomenon in the product isotherms and the corresponding BET surface area is 5.3~9.2 times of the natural flake graphite which is increasing with the acid content in raw materials. The difference of the BET surface area among the detonation soot is mainly caused by the pore of which diameter distributes between 3 nm and 7 nm. Moreover, the amount of the pore size at about 4 nm arrived at the maximum after detonation. In addition, the research provides sorption capacity information for application and at the same time it also proves that acid has perfect impact on preparing graphite nanopowders.

graphite nanopowders  /  adsorption/desorption isotherms  /  pore size distribution  /  detonation technique
孙贵磊, 李晓杰, 闫鸿浩, 王小红, 江德安. 爆轰裂解法制备纳米石墨粉的吸附性能研究. 高压物理学报, 2008 , 22 (4) : 397 -401 .
Gui-Lei SUN, Xiao-Jie LI, Hong-Hao YAN, Xiao-Hong WANG, De-An JIANG. Property Comparison of Porous Graphite Nanopowders Prepared by Detonation Splitting Technique with Different Acid Content[J]. Chinese Journal of High Pressure Physics, 2008 , 22 (4) : 397 -401 .
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2008年第22卷第4期
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  • 接收时间:2007-06-25
  • 首发时间:2026-10-30
  • 出版时间:2008-12-05
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  • 收稿日期:2007-06-25
  • 修回日期:2007-09-04
基金
National Natural Science Foundation(10572034; 10602013)
作者信息
    1.中国劳动关系学院,北京 100037
    2.大连理工大学工业装备结构分析国家重点实验室,辽宁 大连 116023

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2种不同金属材料的力学参数
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genus
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species
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Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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