Article(id=1322282126502900709, tenantId=1146029695717560320, journalId=1220038251117760515, issueId=1322281938308677669, articleNumber=null, orderNo=null, doi=10.11868/j.issn.1001-4381.2025.000346, pmid=null, cstr=32421.14.j.issn.1001-4381.2025.000346, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=1750176000000, receivedDateStr=2025-06-18, revisedDate=null, revisedDateStr=null, acceptedDate=1753027200000, acceptedDateStr=2025-07-21, onlineDate=1793186225771, onlineDateStr=2026-10-28, pubDate=1784476800000, pubDateStr=2026-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793186225771, onlineIssueDateStr=2026-10-28, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793186225771, creator=13701087609, updateTime=1793186225771, updator=13701087609, issue=Issue{id=1322281938308677669, tenantId=1146029695717560320, journalId=1220038251117760515, year='2026', volume='54', issue='7', pageStart='1', pageEnd='347', issueExtLink='null', onlineDate='null', pubDate='1784476800000', pubDateStr='2026-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1793186180903, creator='13701087609', updateTime=1793186267843, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322282303045349604, tenantId=1146029695717560320, journalId=1220038251117760515, issueId=1322281938308677669, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322282303045349605, tenantId=1146029695717560320, journalId=1220038251117760515, issueId=1322281938308677669, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=34, endPage=50, ext={EN=ArticleExt(id=1322282126716810214, articleId=1322282126502900709, tenantId=1146029695717560320, journalId=1220038251117760515, language=EN, title=Recent advances and prospects in wire arc additive manufacturing of shape memory alloys, columnId=1322282006344483370, journalTitle=Journal of Materials Engineering, columnName=HIGH-PERFORMANCE SHAPE MEMORY MATERIALS COLUMN, runingTitle=null, highlight=null, articleAbstract=
Shape memory alloys (SMAs), owing to their unique superelasticity and shape memory effect, have been widely utilized as intelligent materials in aerospace, marine engineering, biomedicine, automotive industries, and other fields. With the continuous advancement of national major scientific projects and engineering initiatives, traditional forming technologies have become inadequate to meet the stringent requirements for SMAs structural components in terms of lightweight design, intelligent functionality, multifunctional integration, and superior comprehensive performance. Wire arc additive manufacturing (WAAM) technology demonstrates distinct advantages in the efficient and cost-effective fabrication of medium to large-scale complex metal structures, attributed to its short production cycles, high material utilization rates, and excellent forming performance. This technology effectively addresses issues inherent in conventional forming methods, such as poor forming quality, low strength and toughness, and spatial constraints in forming, thereby greatly meeting the manufacturing requirements for SMAs. However, due to the complex thermal cycling effects in WAAM, the microstructure exhibits defects such as coarse grains, pores, inhomogeneous deformation, and cracks, severely affecting the performance of structural components. This paper comprehensively reviews recent domestic and international research progress on WAAM-processed SMAs, encompassing fundamental characteristics of SMAs, principles and classifications of WAAM, microstructure control, precipitation phases, phase transformation and hysteresis characteristics, defect suppression, superelasticity and shape memory effects, and performance enhancement. Finally, an outlook is provided from the perspective of synergistic control of material-process-microstructure-property, indicating that the deep integration of intelligent, composite, and cross-scale precision control technologies will be the future direction.
, authors=Fubao WU, Shiquan ZHANG, Bo QIAO, Shiying GAO, Lijun WU, Xiaoting WANG, Hongwei ZHENG, authorsList=Fubao WU, Shiquan ZHANG, Bo QIAO, Shiying GAO, Lijun WU, Xiaoting WANG, Hongwei ZHENG, authorCompany=null, correspAuthors=Fubao WU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322282128528749559, articleId=1322282126502900709, tenantId=1146029695717560320, journalId=1220038251117760515, language=CN, title=形状记忆合金电弧增材制造研究进展与展望, columnId=1322282006491284012, journalTitle=材料工程, columnName=高性能形状记忆材料专栏, runingTitle=null, highlight=null, articleAbstract=
形状记忆合金(SMAs)因具有独特的超弹性和形状记忆效应,作为智能材料已广泛地应用于航空航天、海洋工程、生物医学、汽车等领域。随着国家重大科技项目与工程化的不断推进,传统成形技术已无法满足对形状记忆合金结构件在轻量化、智能化、功能化及兼具优异综合性能方面的严苛要求。电弧增材制造(WAAM)技术,因生产周期短、材料利用率高、成形性能好等优点,在大中型复杂金属结构件的高效低成本制造上具有明显优势,可避免传统制造技术存在的成形质量差、强韧性低、成形空间受限等问题,极大地满足了形状记忆合金构件的制造需求。然而,WAAM由于其复杂的热循环效应,组织存在晶粒粗大、气孔、不均匀变形和裂纹等缺陷,严重影响结构件的性能。本文从形状记忆合金的基础特性、WAAM原理与分类、WAAM成形组织调控、析出相、相变与滞后特性、缺陷抑制、超弹性与形状记忆效应、性能提升等方面对近年来国内外WAAM形状记忆合金的研究进展进行了综述,最后从材料-工艺-组织-性能协同调控方面进行了展望,指出智能化、复合化及跨尺度精准调控技术的深度融合将是未来发展方向。
, authors=邬富宝, 张世全, 乔波, 高世鹰, 吴利军, 王晓亭, 郑宏伟, authorsList=邬富宝, 张世全, 乔波, 高世鹰, 吴利军, 王晓亭, 郑宏伟, authorCompany=null, correspAuthors=邬富宝, authorNote=null, correspAuthorsNote=
邬富宝(1984—),男,助理研究员,硕士,研究方向为铝合金加工与成形技术、电弧增材制造,联系地址:内蒙古包头市青山区呼得木林大街5号五二研究所北区(014034),E-mail:
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27:1593-1610., articleTitle=Revealing microstructural evolutions,mechanical properties and wear performance of wire arc additive manufacturing homogeneous and heterogeneous NiTi alloy, refAbstract=null)], funds=[Fund(id=1322282136128827449, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, awardId=2025LHMS05046, language=CN, fundingSource=内蒙古自治区自然科学基金(2025LHMS05046), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1322282128788796408, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, xref=null, ext=[AuthorCompanyExt(id=1322282128881071097, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, companyId=1322282128788796408, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Inner Mongolia Institute of Metal Materials,Baotou 014034,Inner Mongolia,China), AuthorCompanyExt(id=1322282128889459706, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, companyId=1322282128788796408, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=内蒙古金属材料研究所,内蒙古 包头 014034)])], figs=[ArticleFig(id=1322282132962127911, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.1, caption=
Classification of shape memory alloys, figureFileSmall=w2WY1BvhxoLSsEX55qGwgA==, figureFileBig=Nec4ZeC+qDxTB0O7nymCvg==, tableContent=null), ArticleFig(id=1322282133029236776, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图1, caption=
形状记忆合金分类, figureFileSmall=w2WY1BvhxoLSsEX55qGwgA==, figureFileBig=Nec4ZeC+qDxTB0O7nymCvg==, tableContent=null), ArticleFig(id=1322282133251534889, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.2, caption=
Schematic diagram of WAAM[64] (a)GMAW;(b)CMT;(c)GTAW;(d)PAW, figureFileSmall=84ZWe5U/C7sAsd4BTgNh7w==, figureFileBig=fBhfn4Rp2NvhL+C9Y/I2oQ==, tableContent=null), ArticleFig(id=1322282133322838058, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图2, caption=
WAAM原理示意图[64] (a)GMAW;(b)CMT;(c)GTAW;(d)PAW, figureFileSmall=84ZWe5U/C7sAsd4BTgNh7w==, figureFileBig=fBhfn4Rp2NvhL+C9Y/I2oQ==, tableContent=null), ArticleFig(id=1322282133377364011, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.3, caption=
Classification of WAAM technologies, figureFileSmall=HSGKjF4M+yV8+Wr8wv9LqA==, figureFileBig=ewDXLiEUY7vFW2GLz4Vxlw==, tableContent=null), ArticleFig(id=1322282133431889964, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图3, caption=
WAAM技术分类, figureFileSmall=HSGKjF4M+yV8+Wr8wv9LqA==, figureFileBig=ewDXLiEUY7vFW2GLz4Vxlw==, tableContent=null), ArticleFig(id=1322282135088640045, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=null, caption=null, figureFileSmall=gyl01jPkve45fC3DauuQ3g==, figureFileBig=11bV6SwgjBK1kW1DwXoEnQ==, tableContent=null), ArticleFig(id=1322282135164137518, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图4, caption=
WAAMed形状记忆合金显微组织(a)NiTi试样不同区域金相组织[73];(b)NiTiTa试样不同区域金相组织[73];(c)不同状态NiTiCu合金EBSD分析图[74]Fig.4 Microstructure of WAAMed shape memory alloys(a)microstructure of NiTi samples in different regions[73];(b)microstructure of NiTiTa samples in different regions[73];(c)EBSD map of NiTiCu alloys in different states[74]
, figureFileSmall=gyl01jPkve45fC3DauuQ3g==, figureFileBig=11bV6SwgjBK1kW1DwXoEnQ==, tableContent=null), ArticleFig(id=1322282135239634991, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.5, caption=
(TiTa)2Ni precipitates in WAAMed NiTiTa shape memory alloys[78], figureFileSmall=pVUDbn2ClMI9727n2oY3eQ==, figureFileBig=Qo+er4x6Cz5ozY1SyJX3ZQ==, tableContent=null), ArticleFig(id=1322282135302549552, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图5, caption=
WAAMed NiTiTa形状记忆合金的(TiTa)2Ni析出相[78](a)低放大倍率下等轴晶区的透射电镜像;(b)图(a)中区域b的放大像;(c)~(f)局部析出相及元素分布映射;(g)析出相的放大形态及其元素组成和SAED;(h)图(g)中区域h的高分辨透射电镜像(a)TEM image of the equiaxed grains region at low magnification;(b)magnified image of region b in Fig.(a);(c)-(f)images of local precipitates and the corresponding elemental mapping;(g)enlarged morphology of precipitates with element composition and SAED;(h)high-resolution TEM image of region h in Fig.(g)
, figureFileSmall=pVUDbn2ClMI9727n2oY3eQ==, figureFileBig=Qo+er4x6Cz5ozY1SyJX3ZQ==, tableContent=null), ArticleFig(id=1322282135369658417, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.6, caption=
Phase transformation behaviour of WAAMed NiTiCu alloys in different states[74](a)DSC curves;(b)variation curves of phase transformation temperature and hysteresis, figureFileSmall=+YXOgmK76Ketz4sO5J4j8A==, figureFileBig=jEanoUzBWHvGcNRix+E7sw==, tableContent=null), ArticleFig(id=1322282135449350194, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图6, caption=
WAAMed NiTiCu形状记忆合金不同状态下相变行为[74](a)DSC曲线;(b)相变温度与滞后变化曲线, figureFileSmall=+YXOgmK76Ketz4sO5J4j8A==, figureFileBig=jEanoUzBWHvGcNRix+E7sw==, tableContent=null), ArticleFig(id=1322282135541624883, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.7, caption=
Shape memory effect of WAAMed shape memory alloys(a)memory recovery process of Cu-12.5Al-3.0Mn alloy (pre-strain is 8.0%)[96];(b)memory recovery process of Cu-12.5Al-3.0Mn-1.0Ni alloy(pre-strain is 8.0%)[96];(c)comparison of specific strength and maximum recoverable strain between WAAMed Ti-14.7V-9.8Al shape memory alloy and other typical high-temperature shape memory alloys (Note:the ordinate of the red dotted box point is the maximum fully recoverable strain of the alloy)[87], figureFileSmall=uZHCWeMbZyNyOkvIMXC27w==, figureFileBig=jekfEgYymyReCHPo9QaJKw==, tableContent=null), ArticleFig(id=1322282135671648308, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图7, caption=
WAAMed形状记忆合金的形状记忆效应(a)Cu-12.5Al-3.0Mn合金的形状恢复过程(预应变8.0%)[96];(b)Cu-12.5Al-3.0Mn-1.0Ni合金的形状恢复过程(预应变8.0%)[96];(c)Ti-14.7V-9.8Al合金与其他典型高温形状记忆合金的比强度和最大可恢复应变的比较(注:红色虚线框的点的纵坐标为合金的最大完全可恢复应变)[87]
, figureFileSmall=uZHCWeMbZyNyOkvIMXC27w==, figureFileBig=jekfEgYymyReCHPo9QaJKw==, tableContent=null), ArticleFig(id=1322282135768117301, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Fig.8, caption=
Future research directions of WAAMed shape memory alloys, figureFileSmall=jeKY13fHqMTI1J31nt45ug==, figureFileBig=cgdPsDvCd85fgMfvkI8BiQ==, tableContent=null), ArticleFig(id=1322282135839420470, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=图8, caption=
WAAMed形状记忆合金未来研究方向, figureFileSmall=jeKY13fHqMTI1J31nt45ug==, figureFileBig=cgdPsDvCd85fgMfvkI8BiQ==, tableContent=null), ArticleFig(id=1322282135906529335, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=EN, label=Table 1, caption=
Mechanical properties of WAAMed shape memory alloys
, figureFileSmall=null, figureFileBig=null, tableContent=
| SMAs | Process | Heat treatment | UTS/MPa | CS/MPa | YS/MPa | EL/% | HV | Ref. |
|---|
| Ti-based | Ti14.4V9.7Al2Zr Ti14.4V9.7Al4Zr Ti14.4V9.7Al6Zr | GTAW | Annealing:900 ℃/6 h; ice-water quenching | 814.0 | | 352.0 | 10.1 | | [40] |
| 775.0 | | 501.0 | 13.0 | |
| 646.0 | | <200.0 | 12.8 | |
| Ti-12.2V-10.1Al | GTAW | Annealing:900 ℃/6 h; ice-water quenching | 905.0 | | 550.0 | 7.9 | 326.0 | [87] |
| Ti-14.7V-9.8Al | 852.0 | | | 9.0 | 317.0 |
| Ti-17.0V-9.5Al | 534.0 | | 260.0 | 6.1 | 303.0 |
| Fe-based* | Fe-17.0Mn-5.0Si-10.0Cr-4.0Ni-1.0(V,C) | GMAW | | 821.0±64.0 | | 472.0±18.0 | 26.0±1.5 | 250.0-300.0 | [95] |
| Fe28.0Mn5.0Si | | Annealing:1050 ℃/8 h; Solution: 900 ℃/2 h | | | | | 220.0-260.0 | [100] |
| Fe28.0Mn5.0Si+50.0% nano-Si doping | | | | | 278.4 |
| NiTi-based | Ni50.8Ti49.2 | W-DED | | 511.6 | | | 8.5 | | [73] |
| Ni49.1Ti48.6Ta2.3 | | 558.1 | | | 7.9 | |
| NiTiCu(20.0%Cu) | CMT | | 232.0±11.0 | | | 3.7±0.7 | 369.5 | [74,88] |
T6: 900 ℃/1 h+ 450 ℃/1 h | 539.0 | | | 6.9 | 317.0 |
| Ti-Ni-Al-V | CMT | | | 2100.0±15.0 | | 8.7±0.6 | 685.4(bottom area) 553.0(top area) | [77] |
| Ni52.0Ti48.0 | CMT | | | 1766.0(H) 1981.0(L) | | 28.1(H) 35.3(L) | 500.0-750.0(bottom area) 400.0(middle area) 500.0(top area) | [89,101] |
| Solution: 800 ℃/1 h | | 2406.0(H) 2537.0(L) | | 16.9(H) 18.4(L) | |
T6: 800 ℃/1 h+ 450 ℃/3 h | | 1927.0(H) 2271.0(L) | | 27.5(H) 35.2(L) | |
| Ni49.0Ti47.0Nb4.0 | | | 1874.0(H) 2268.0(L) | | 31.7(H) 36.2(L) | 300.0-600.0(bottom area) 300.0-450.0(near top) |
| Ni47.0Ti44.0Nb9.0 | | | 2042.0(H) 2214.0(L) | | 32.6(H) 38.3(L) | 300.0-400.0(bottom area) 280.0-350.0(near top) |
| Solution: 800 ℃/1 h | | 2216.0(H) 2143.0(L) | | 32.4(H) 40.2(L) | |
T6: 800 ℃/1 h+ 450 ℃/3 h | | 2072.0(H) 2243.0(L) | | 33.4(H) 40.2(L) | |
| Ni45.0Ti42.0Nb13.0 | | | 2483.0(H) 2206.0(L) | | 37.2(H) 35.6(L) | 250.0-300.0 |
| Ni51.1Ti48.9 | UHFP-GTA | Annealing: 950 ℃/5 h | 611.3±12.4 | | | 19.5 | 288.6±10.5 | [102] |
| Ni-Ti-Cr-Mo-Nb | CMT | | | 1970.0 | | 8.0 | 570.0(bottom area) 580.0-650.0(middle area) 603.0-714.0(top area) | [79] |
), ArticleFig(id=1322282135994609720, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1322282126502900709, language=CN, label=表1, caption=
WAAMed形状记忆合金力学性能
, figureFileSmall=null, figureFileBig=null, tableContent=
| SMAs | Process | Heat treatment | UTS/MPa | CS/MPa | YS/MPa | EL/% | HV | Ref. |
|---|
| Ti-based | Ti14.4V9.7Al2Zr Ti14.4V9.7Al4Zr Ti14.4V9.7Al6Zr | GTAW | Annealing:900 ℃/6 h; ice-water quenching | 814.0 | | 352.0 | 10.1 | | [40] |
| 775.0 | | 501.0 | 13.0 | |
| 646.0 | | <200.0 | 12.8 | |
| Ti-12.2V-10.1Al | GTAW | Annealing:900 ℃/6 h; ice-water quenching | 905.0 | | 550.0 | 7.9 | 326.0 | [87] |
| Ti-14.7V-9.8Al | 852.0 | | | 9.0 | 317.0 |
| Ti-17.0V-9.5Al | 534.0 | | 260.0 | 6.1 | 303.0 |
| Fe-based* | Fe-17.0Mn-5.0Si-10.0Cr-4.0Ni-1.0(V,C) | GMAW | | 821.0±64.0 | | 472.0±18.0 | 26.0±1.5 | 250.0-300.0 | [95] |
| Fe28.0Mn5.0Si | | Annealing:1050 ℃/8 h; Solution: 900 ℃/2 h | | | | | 220.0-260.0 | [100] |
| Fe28.0Mn5.0Si+50.0% nano-Si doping | | | | | 278.4 |
| NiTi-based | Ni50.8Ti49.2 | W-DED | | 511.6 | | | 8.5 | | [73] |
| Ni49.1Ti48.6Ta2.3 | | 558.1 | | | 7.9 | |
| NiTiCu(20.0%Cu) | CMT | | 232.0±11.0 | | | 3.7±0.7 | 369.5 | [74,88] |
T6: 900 ℃/1 h+ 450 ℃/1 h | 539.0 | | | 6.9 | 317.0 |
| Ti-Ni-Al-V | CMT | | | 2100.0±15.0 | | 8.7±0.6 | 685.4(bottom area) 553.0(top area) | [77] |
| Ni52.0Ti48.0 | CMT | | | 1766.0(H) 1981.0(L) | | 28.1(H) 35.3(L) | 500.0-750.0(bottom area) 400.0(middle area) 500.0(top area) | [89,101] |
| Solution: 800 ℃/1 h | | 2406.0(H) 2537.0(L) | | 16.9(H) 18.4(L) | |
T6: 800 ℃/1 h+ 450 ℃/3 h | | 1927.0(H) 2271.0(L) | | 27.5(H) 35.2(L) | |
| Ni49.0Ti47.0Nb4.0 | | | 1874.0(H) 2268.0(L) | | 31.7(H) 36.2(L) | 300.0-600.0(bottom area) 300.0-450.0(near top) |
| Ni47.0Ti44.0Nb9.0 | | | 2042.0(H) 2214.0(L) | | 32.6(H) 38.3(L) | 300.0-400.0(bottom area) 280.0-350.0(near top) |
| Solution: 800 ℃/1 h | | 2216.0(H) 2143.0(L) | | 32.4(H) 40.2(L) | |
T6: 800 ℃/1 h+ 450 ℃/3 h | | 2072.0(H) 2243.0(L) | | 33.4(H) 40.2(L) | |
| Ni45.0Ti42.0Nb13.0 | | | 2483.0(H) 2206.0(L) | | 37.2(H) 35.6(L) | 250.0-300.0 |
| Ni51.1Ti48.9 | UHFP-GTA | Annealing: 950 ℃/5 h | 611.3±12.4 | | | 19.5 | 288.6±10.5 | [102] |
| Ni-Ti-Cr-Mo-Nb | CMT | | | 1970.0 | | 8.0 | 570.0(bottom area) 580.0-650.0(middle area) 603.0-714.0(top area) | [79] |
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