Article(id=1321490259968373652, tenantId=1146029695717560320, journalId=1220038251117760515, issueId=1321490128967675980, articleNumber=null, orderNo=null, doi=10.11868/j.issn.1001-4381.2023.000775, pmid=null, cstr=32421.14.j.issn.1001-4381.2023.000775, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=1700496000000, receivedDateStr=2023-11-21, revisedDate=null, revisedDateStr=null, acceptedDate=1706112000000, acceptedDateStr=2024-01-25, onlineDate=1792997430077, onlineDateStr=2026-10-26, pubDate=1768838400000, pubDateStr=2026-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792997430077, onlineIssueDateStr=2026-10-26, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792997430077, creator=13701087609, updateTime=1792997430077, updator=13701087609, issue=Issue{id=1321490128967675980, tenantId=1146029695717560320, journalId=1220038251117760515, year='2026', volume='54', issue='1', pageStart='1', pageEnd='259', issueExtLink='null', onlineDate='null', pubDate='1768838400000', pubDateStr='2026-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792997398845, creator='13701087609', updateTime=1792997398845, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=250, endPage=259, ext={EN=ArticleExt(id=1321490260182283157, articleId=1321490259968373652, tenantId=1146029695717560320, journalId=1220038251117760515, language=EN, title=Interfacial regulation of cobalt-nickel/nitrogen-doped carbon nanospheres and its electrochemical sensing performance for detection of chloramphenicol, columnId=1220689384450478826, journalTitle=Journal of Materials Engineering, columnName=RESEARCH ARTICLE, runingTitle=null, highlight=null, articleAbstract=

Chloramphenicol （CAP）， as an antibiotic， is widely used as a veterinary medicine in the aquaculture industry. The misuse of CAP can lead to a range of environmental and human health issues， making it extremely important to establish a rapid and sensitive method for detecting CAP. Electrochemical sensors have been widely studied by researchers due to their advantages of simple operation， rapid response， high sensitivity， and ease of miniaturization， but their performance mainly depends on the sensing material. In this work， cobalt-nickel metal-organic framework （CoNi-MOF） is in situ synthesized on the surface of bacteria. CoNi nitrogen-doped carbon nanospheres （CoNi/CN-900） with abundant active sites and a large specific surface area is obtained after carbonization at 900 ℃ by interfacial regulation. The uniform distribution of Ni and Co on CoNi/CN-900 provides more catalytically active sites for the detection of CAP. The CoNi/CN-900-based CAP electrochemical sensor shows a good linear range of 20 nmol/L- 4 μmol/L and 4-38 μmol/L， a detection limit as low as 6.6 nmol/L， and a high sensitivity of 8.75 μA·μmol·L^-1·cm^-2. Compared with the reported same type sensors， it has higher sensitivity and a lower detection limit. In addition， the sensor has good selectivity and high stability， which can keep more than 99.1% of its initial current at room temperature for 35 days.

, authors=Zhuanzhuan SHI, Liang LIU, Zuqiang MA, Yunpeng LI, Wenting MIAO, Xiaokun FU, Xiaoshuai WU, authorsList=Zhuanzhuan SHI, Liang LIU, Zuqiang MA, Yunpeng LI, Wenting MIAO, Xiaokun FU, Xiaoshuai WU, authorCompany=null, correspAuthors=Zhuanzhuan SHI, Xiaoshuai WU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321490261407019938, articleId=1321490259968373652, tenantId=1146029695717560320, journalId=1220038251117760515, language=CN, title=钴镍/氮掺杂碳纳米球的界面调控及其对检测氯霉素的电化学传感性能, columnId=1220689384622445292, journalTitle=材料工程, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

氯霉素（CAP）作为一种抗生素，在水产养殖业中被广泛用作兽药。CAP的滥用会导致一系列环境和人类健康问题，因此建立一种快速高灵敏检测CAP的方法极为重要。电化学传感器由于具有操作简单、反应迅速、灵敏度高、易于小型化等优点而受到研究者的广泛关注，但其性能主要取决于传感材料。本工作以细菌为模板，在细菌表面原位合成了钴镍金属有机框架（CoNi-MOF），通过界面调控在900 ℃碳化后得到具有丰富活性位点和大比表面积的CoNi氮掺杂碳纳米球（CoNi/CN-900），且其表面分布均匀的Ni、Co为CAP提供了更多的催化活性位点。基于CoNi/CN-900构建的CAP电化学传感器在20 nmol/L~4 μmol/L和4~38 μmol/L范围内显示出良好的线性响应，检出限低至6.6 nmol/L，灵敏度高达8.75 μA·μmol·L^-1·cm^-2。相比于已报道的同类型传感器，该传感器具有较高的灵敏度和较低的检出限。此外，该传感器的选择性好、稳定性高，室温保存35天仍能保持初始电流的99.1%以上。

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structure of nanocomposites（a）schematic illustration of fabrication of nanocomposites；（b）SEM image of CoNi/CN-700；（c）SEM image of CoNi/CN-800；（d）SEM image of CoNi/CN-900；（e）SEM image of CoNi/CN-1000；（f）nitrogen adsorption-desorption isotherms；（g）pore size distributions of CoNi/CN-900 and CoNi/CN-1000, figureFileSmall=SGOTypiB+TCa9xNExognCw==, figureFileBig=ZYjkSAbubGA7nUUzHhQIWQ==, tableContent=null), ArticleFig(id=1321927166003102516, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图1, caption=复合材料的制备流程、形貌及孔径结构图（a）复合材料的制备流程图；（b）CoNi/CN-700的SEM图；（c）CoNi/CN-800的SEM图；（d）CoNi/CN-900的SEM图；（e）CoNi/CN-1000的SEM图；（f）CoNi/CN-900和CoNi/CN-1000的氮吸附-解吸等温线；（g）CoNi/CN-900和CoNi/CN-1000的孔径分布, figureFileSmall=SGOTypiB+TCa9xNExognCw==, figureFileBig=ZYjkSAbubGA7nUUzHhQIWQ==, tableContent=null), ArticleFig(id=1321927166170874677, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Fig.2, caption=XRD and XPS of different materials（a）XRD patterns of different CoNi/CN materials；（b）XPS total spectra of CN，CoNi/CN and CoNi/CN-900；（c）Co 2p of CoNi/CN and CoNi/CN-900；（d）Ni 2p of CoNi/CN and CoNi/CN-900；（e）N 1s of CN and CoNi/CN-900, figureFileSmall=zivS8WSECHoePe+LkffZEQ==, figureFileBig=WsWcJImznbDc2mareLTb+g==, tableContent=null), ArticleFig(id=1321927166242177846, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图2, caption=不同材料的XRD和XPS图（a）不同CoNi/CN材料的XRD图；（b）CN、CoNi/CN和CoNi/CN-900的XPS 总谱图；（c）CoNi/CN和CoNi/CN-900的Co 2p谱图；（d）CoNi/CN和CoNi/CN-900的Ni 2p谱图；（e）CN和CoNi/CN-900的N 1s谱图, figureFileSmall=zivS8WSECHoePe+LkffZEQ==, figureFileBig=WsWcJImznbDc2mareLTb+g==, tableContent=null), ArticleFig(id=1321927166309286711, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Fig.3, caption=CV curves and capacitive current corresponds to function diagram of different scanning rates（a）CoNi/CN-700；（b）CoNi/CN-800；（c）CoNi/CN-900；（d）CoNi/CN-100；（e）CoNi/CN；（f）capacitive current corresponds to function diagram of different scanning rates （20-100 mV·s^-1）, figureFileSmall=hYaErBur/msKeGTVPoGIPA==, figureFileBig=o84kVEGq6dGWdvNP733KYg==, tableContent=null), ArticleFig(id=1321927166519001912, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图3, caption=不同扫描速率下的CV曲线和电容电流对应不同扫描速率的函数图（a）CoNi/CN-700；（b）CoNi/CN-800；（c）CoNi/CN-900；（d）CoNi/CN-100；（e）CoNi/CN；（f）电容电流对应不同扫描速率（20~100 mV·s^-1）的函数图, figureFileSmall=hYaErBur/msKeGTVPoGIPA==, figureFileBig=o84kVEGq6dGWdvNP733KYg==, tableContent=null), ArticleFig(id=1321927166590305081, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Fig.4, caption=Electrochemical response of different materials to CAP and pH optimization of PBS（a）CV curves of different materials modified GCEs in 0.1 mol/L PBS containing 15 μmol/L CAP （scan rate：50 mV·s^-1）； （b）histogram corresponding to reduction peak current value of Fig.（a）；（c）CV curves at different pH values；（d）line plots corresponding to Fig.（c）, figureFileSmall=nezjKTLtQB751kJG+pdqzg==, figureFileBig=+hdzva1WnFG8Hd0XJwAxzw==, tableContent=null), ArticleFig(id=1321927166678385466, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图4, caption=不同材料对CAP的电化学响应和PBS溶液pH优化（a）不同材料修饰的电极在含15 μmol/L CAP的0.1 mol/L PBS中的CV图（扫描速率：50 mV·s^-1）；（b）对应（a）图中还原峰电流值的柱状图；（c）不同pH下的CV图；（d）对应图（c）的电流响应折线图, figureFileSmall=nezjKTLtQB751kJG+pdqzg==, figureFileBig=+hdzva1WnFG8Hd0XJwAxzw==, tableContent=null), ArticleFig(id=1321927166934238011, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Fig.5, caption=Electrochemical behavior and reaction mechanism of CoNi/CN-900/GCE at different scan rates and different concentrations of CAP（a）CV curves of CoNi/CN-900/GCE to 5 μmol/L CAP in 0.1 mol/L PBS under different scan rates；（b）linear relationship between peak current and scan rate；（c）DPV curves of CoNi/CN-900/GCE to different concentrations of CAP；（d）linear relationship between CAP concentration and current response；（e）reaction mechanism of CAP on CoNi/CN-900/GCE, figureFileSmall=G38TOUDouOmWJDwcbyfsPw==, figureFileBig=E9UBptdRgCVF94npT7wImg==, tableContent=null), ArticleFig(id=1321927167013929788, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图5, caption=CoNi/CN-900/GCE在不同扫速和不同浓度CAP中的电化学行为及反应机理解析（a）不同扫描速率下0.1 mol/L PBS中CoNi/CN-900/GCE对5 μmol/L CAP的响应CV图；（b）还原峰值电流与扫描速率的线性关系；（c）CoNi/CN-900/GCE对不同浓度CAP的DPV响应曲线；（d）CAP浓度与电流响应的线性关系图；（e）CAP反应机理图, figureFileSmall=G38TOUDouOmWJDwcbyfsPw==, figureFileBig=E9UBptdRgCVF94npT7wImg==, tableContent=null), ArticleFig(id=1321927167089427261, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Fig.6, caption=Selectivity， repeatability，and stability of CoNi/CN-900 towards CAP（a）selectivity of CoNi/CN-900 towards CAP；（b）bar chart corresponding to current response in Fig.（a）；（c）repeatability of CoNi/CN-900/GCE；（d）stability of CoNi/CN-900/GCE, figureFileSmall=dNPlqOeamRZKJASdGuag7g==, figureFileBig=RqBy+535zIKp1sxFONZgvQ==, tableContent=null), ArticleFig(id=1321927167357862718, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=图6, caption=CoNi/CN-900/GCE对CAP的选择性、稳定性和重复性（a）CoNi/CN-900对CAP的选择性测试；（b）对应图（a）中电流响应的柱状图；（c）CoNi/CN-900/GCE的重复实验；（d）CoNi/CN-900/GCE的稳定性实验, figureFileSmall=dNPlqOeamRZKJASdGuag7g==, figureFileBig=RqBy+535zIKp1sxFONZgvQ==, tableContent=null), ArticleFig(id=1321927167445943103, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=EN, label=Table 1, caption=

Comparison of different CAP sensing platforms constructed with cobalt-based nanomaterials^{［10，18-20］}

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Sensing material	Liner range/（μmol·L-1）	Detection limit/（nmol·L-1）	Sensitivity/（μA·μmol·L-1·cm-2）	Reference
NiCo2O4@C	0.5-320	35		［10］
Sr2Co2O5 NPs	0.01-931.1	2.3		［18］
CoMoO4	0.06-1190.14	14	0.293	［19］
Co3O4@rGO	1-2000	550	1.32	［20］
CoNi/CN-900	0.02-4	6.6	8.75	This work
	4-38		0.92

), ArticleFig(id=1321927169253688130, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321490259968373652, language=CN, label=表1, caption=

基于Ni或Co的纳米材料构建的不同CAP传感平台性能比较^{［10，18-20］}

, figureFileSmall=null, figureFileBig=null, tableContent=

Sensing material	Liner range/（μmol·L-1）	Detection limit/（nmol·L-1）	Sensitivity/（μA·μmol·L-1·cm-2）	Reference
NiCo2O4@C	0.5-320	35		［10］
Sr2Co2O5 NPs	0.01-931.1	2.3		［18］
CoMoO4	0.06-1190.14	14	0.293	［19］
Co3O4@rGO	1-2000	550	1.32	［20］
CoNi/CN-900	0.02-4	6.6	8.75	This work
	4-38		0.92

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