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The complexity of cavities, randomness of pore distribution, and multi-scale of pore size in porous materials make it difficult to quantitatively characterize pore microstructure. In recent years, fractal theory attracts more attention because of its unique advantages in portraying the self-similarity and multi-scale of complex structures. This paper reviews the development roadmap of fractal theory and its applications on porous materials, analyzes the single and multi-fractal feature extraction and characterization methods for porous materials at different scales, summarizes some advanced engineering material applications based on multifractal optimization, and discusses the research progress in the applications of fractal theory to the characterization of mechanical, thermal and permeability properties of porous materials. During the optimization design and performance characterization process of porous materials based on fractal theory, the main issues and shortcomings including the ambiguity of correlation mechanism between micro structure and macro multi-functional characteristics, and low efficiency and accuracy for prediction models and/or optimization algorithm are pointed out. The development trend and potential engineering applications of fractal theory such as the consideration of cross-scale effect, multi-physics coupling analysis, and optimization strategy based on machine learning are prospected.
, authors=Xin XUE, Shaoxiang GE, Yuhan WEI, Juan LIAO, authorsList=Xin XUE, Shaoxiang GE, Yuhan WEI, Juan LIAO, authorCompany=null, correspAuthors=Juan LIAO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321967710955753727, articleId=1321967707570950385, tenantId=1146029695717560320, journalId=1220038251117760515, language=CN, title=基于分形理论的多孔材料设计及表征研究进展, columnId=1220689389663994406, journalTitle=材料工程, columnName=综述, runingTitle=null, highlight=null, articleAbstract=
多孔材料内部空腔的复杂性、孔隙分布的随机性以及孔径的多尺度性对孔隙细观结构的定量表征带来困难。分形理论因其在表征复杂结构自相似性和多尺度性方面的独特优势,近年受到广泛关注。本文综述了分形理论在多孔材料领域的研究发展历程,分析了不同尺度下多孔材料单一和多重分形特征的提取与表征方法,对基于多重分形优化的先进工程材料应用案例进行了归纳,重点讨论了分形理论在多孔材料力学性能、传热性能和渗透性能表征研究中的进展,指出基于分形理论指导多孔材料优化设计及性能表征过程中,主要存在细观结构-宏观多功能特性之间的关联物理机制不明确、预测/优化模型算法效率和精度低的问题,对分形理论在多孔材料未来的研究发展和潜在的工程应用前景,如考虑跨尺度效应、多物理场耦合分析、机器学习优化策略等进行了展望。
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廖娟(1984—),女,教授,博士,研究方向为轻量化材料成形及性能表征,联系地址:福建省福州地区大学城学园路2号福州大学机械学院北506B(350116),E-mail:
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Development history of fractal theory in field of porous materials, figureFileSmall=LZMJyhrRCOYf2pzh1UGPFA==, figureFileBig=DyA9AdOy00ke9KKl+/Rfhw==, tableContent=null), ArticleFig(id=1321967715930198306, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图1, caption=
分形理论在多孔材料领域的发展历程, figureFileSmall=LZMJyhrRCOYf2pzh1UGPFA==, figureFileBig=DyA9AdOy00ke9KKl+/Rfhw==, tableContent=null), ArticleFig(id=1321967716139913507, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Fig.2, caption=
Flow chart of calculating fractal dimension of metal fiber cross section by box-counting method(a)image of local pore cross sections obtained from CT skeleton;(b)extraction of pore edges after image grayscale and black and white binarization processing;(c)segmented mesh covering pore edges;(d)box-counting method to calculate fractal dimension, figureFileSmall=I2kY+Vap5sQlxM40ZwiL7Q==, figureFileBig=0Ci50k7EQR56NEZh7b+pOw==, tableContent=null), ArticleFig(id=1321967716223799588, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图2, caption=
盒维法计算金属纤维截面孔隙分形维数流程(a)从CT骨架中获取的局部孔隙截面图;(b)图像灰度和黑白二值化处理后提取孔隙轮廓;(c)分割网格覆盖孔隙轮廓;(d)盒维法计算分形维数, figureFileSmall=I2kY+Vap5sQlxM40ZwiL7Q==, figureFileBig=0Ci50k7EQR56NEZh7b+pOw==, tableContent=null), ArticleFig(id=1321967716303491365, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Fig.3, caption=
Applications of structural engineering materials based on regular multifractal theory(a)design of a snake-like bionic shape structure[47];(b)three-dimensional cross fractal multicell lattice structure for vibration reduction[48];(c)multi-dimensional fractal periodic structure with elastic function of three-dimensional expansion[49];(d)Koch curve wire mesh in titanium alloy for structural reinforcement elements[50];(e)periodic “textured” fractal metamaterials with superelasticity[51], figureFileSmall=5K9EeeRxVxaaxmFw5sfGKA==, figureFileBig=rmUgaa/KQxiMWQS6r3mGJw==, tableContent=null), ArticleFig(id=1321967716383183142, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图3, caption=
基于规则多重分形理论的先进结构工程材料应用(a)蛇形仿生形结构设计[47];(b)用于减振的三维交叉分形多胞点阵结构[48];(c)具有三维拉胀弹性功能的多维分形周期性结构[49];(d)用于结构增强元件的钛合金Koch曲线丝网[50];(e)具有超弹性特性的周期“刻纹”分形超材料[51], figureFileSmall=5K9EeeRxVxaaxmFw5sfGKA==, figureFileBig=rmUgaa/KQxiMWQS6r3mGJw==, tableContent=null), ArticleFig(id=1321967716483846439, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Fig.4, caption=
Application of fractal theory in characterization of porous material mechanical properties(a)Menger Sponge fractal model,multifractal features and compressive strength fractal model of concrete[60];(b),(c)pore cumulative curves and calculation error of Young’s modulus in porous ceramics based on IFU program[61], figureFileSmall=akju+pWJ6Ym2WfqNnD9xwA==, figureFileBig=oFDURoY17Z4B2OJZoeTfug==, tableContent=null), ArticleFig(id=1321967716571926824, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图4, caption=
分形理论在多孔材料力学性能表征中的应用(a)Menger Sponge分形模型、混凝土的多重分形特征以及抗压强度分形模型[60];(b),(c)基于IFU程序的多孔陶瓷孔隙积累曲线和杨氏模量计算误差[61], figureFileSmall=akju+pWJ6Ym2WfqNnD9xwA==, figureFileBig=oFDURoY17Z4B2OJZoeTfug==, tableContent=null), ArticleFig(id=1321967716660007209, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Fig.5, caption=
Effect of fractal pore design on heat-conducting property of metal foam(a)two-phase distribution of phase change materials in four Sierpinski fractal pore structures[71];(b)comparison of calculated fluid-solid heat-conduction coefficients ratio by using fractal model and other models when porosity φ is 0.17[72];(c),(d)effects of fractal dimension on evolution of liquid fraction,temperature distribution and solidification performance of metal foam[73], figureFileSmall=AOXIgnPABkk0aUnh2hZQsQ==, figureFileBig=gBD9B7VKmapF9gv3/nTrOg==, tableContent=null), ArticleFig(id=1321967716760670506, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图5, caption=
分形孔隙设计对金属泡沫导热性能的影响(a)四种 Sierpinski 分形孔隙结构下相变材料两相分布[71];(b)孔隙度φ = 0.17时分形模型与其他模型对固流导热系数比的计算结果对比[72];(c),(d)分形维数对液体分数演变、瞬态温度分布以及材料凝固性能的影响[73], figureFileSmall=AOXIgnPABkk0aUnh2hZQsQ==, figureFileBig=gBD9B7VKmapF9gv3/nTrOg==, tableContent=null), ArticleFig(id=1321967716831973675, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Fig.6, caption=
Application of fractal theory in characterization of porous material permeability properties(a)REA fractal permeability model[79];(b)schematic diagram of streamlines of smooth-foam and rough-foam elements[80], figureFileSmall=6aU+G7nc9t4BJmCq9KR5zg==, figureFileBig=rr2t8pHpSzmSR6pIfYx/tA==, tableContent=null), ArticleFig(id=1321967716928442668, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=图6, caption=
分形理论在多孔材料渗透性能表征中的应用(a)REA分形渗透模型[79];(b)光滑和粗糙开孔泡沫单元流线示意图[80], figureFileSmall=6aU+G7nc9t4BJmCq9KR5zg==, figureFileBig=rr2t8pHpSzmSR6pIfYx/tA==, tableContent=null), ArticleFig(id=1321967717003940141, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=EN, label=Table 1, caption=
Comparison of main characterization techniques of multi-scale pore structure[23]
, figureFileSmall=null, figureFileBig=null, tableContent=
| Pore type | Characterization type | Measurement technique | Accuracy |
|---|
| Nanopore(1-1000 nm) | 2D image observation | Atomic force microscope(AFM) | >0.1 nm |
| 2D image observation | Environmental scanning electron microscope(ESEM) | >1 nm |
| 2D image observation | Field emission scanning electron microscope(FESEM) | >1 nm |
| 2D image observation | Scanning electron microscope(SEM) | >6 nm |
| 3D reconstruction | Nano-CT | >50 nm |
| Micropore(1-1000 μm) | 2D image observation | Optical microscope | >0.3 μm |
| 3D reconstruction | Micro-CT | >1 μm |
| Macropore(>1 mm) | 3D reconstruction | Macro-CT | >0.6 mm |
| Quantitative characterization | Nuclear magnetic resonance(NMR) | >8 nm |
| Quantitative characterization | Gas adsorption | >1 nm |
| Quantitative characterization | Mercury intrusion porosimetry(MIP) | >0.01 μm |
), ArticleFig(id=1321967717180100910, tenantId=1146029695717560320, journalId=1220038251117760515, articleId=1321967707570950385, language=CN, label=表1, caption=
多尺度孔隙结构的主要表征技术对比[23]
, figureFileSmall=null, figureFileBig=null, tableContent=
| Pore type | Characterization type | Measurement technique | Accuracy |
|---|
| Nanopore(1-1000 nm) | 2D image observation | Atomic force microscope(AFM) | >0.1 nm |
| 2D image observation | Environmental scanning electron microscope(ESEM) | >1 nm |
| 2D image observation | Field emission scanning electron microscope(FESEM) | >1 nm |
| 2D image observation | Scanning electron microscope(SEM) | >6 nm |
| 3D reconstruction | Nano-CT | >50 nm |
| Micropore(1-1000 μm) | 2D image observation | Optical microscope | >0.3 μm |
| 3D reconstruction | Micro-CT | >1 μm |
| Macropore(>1 mm) | 3D reconstruction | Macro-CT | >0.6 mm |
| Quantitative characterization | Nuclear magnetic resonance(NMR) | >8 nm |
| Quantitative characterization | Gas adsorption | >1 nm |
| Quantitative characterization | Mercury intrusion porosimetry(MIP) | >0.01 μm |
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