Article(id=1282029981932957968, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282029960869167928, articleNumber=null, orderNo=null, doi=10.16265/j.cnki.issn1003-3033.2025.07.1677, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1741536000000, receivedDateStr=2025-03-10, revisedDate=1747843200000, revisedDateStr=2025-05-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1783589366657, onlineDateStr=2026-07-09, pubDate=1753632000000, pubDateStr=2025-07-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1783589366657, onlineIssueDateStr=2026-07-09, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1783589366657, creator=13701087609, updateTime=1783589366657, updator=13701087609, issue=Issue{id=1282029960869167928, tenantId=1146029695717560320, journalId=1146031787341344770, year='2025', volume='35', issue='7', pageStart='1', pageEnd='252', issueExtLink='null', onlineDate='null', pubDate='1753632000000', pubDateStr='2025-07-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1783589361636, creator='13701087609', updateTime=1783589710614, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1282031424651903975, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282029960869167928, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1282031424656098280, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282029960869167928, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=159, endPage=166, ext={EN=ArticleExt(id=1282029983208026385, articleId=1282029981932957968, tenantId=1146029695717560320, journalId=1146031787341344770, language=EN, title=Investigation of inhibitory influence of cinnamomum camphora leaf extract on hydrogen evolution from Al-Zn dust in wet dust removal, columnId=1149733269173878863, journalTitle=China Safety Science Journal, columnName=Safety engineering technology, runingTitle=null, highlight=null, articleAbstract=

In order to promote the safe and eco-friendly operation of wet dust collection systems by mitigating hydrogen fire and explosion risks caused by metal waste dust in contact with water, a custom-designed metal-water hydrogen evolution testing system and a water-based Cinnamomum camphor leaf extract (prepared via decoction) were utilized. Experiments assessed the hydrogen suppression efficiency of Cinnamomum camphor leaf extract at various mass concentrations. Surface analysis and theoretical calculations were conducted to study the adsorption behavior, chemical reaction kinetics, and inhibition mechanism of Cinnamomum camphor leaf extract on hydrogen evolution from aluminum-zinc (Al-Zn) dust. The hydrogen suppression stability at the optimal mass concentration was evaluated under varying environmental conditions. Experimental results demonstrated that higher mass concentrations of extract improved its ability to suppress hydrogen evolution from Al-Zn dust. At a mass concentration of 50 mg/L, the hydrogen suppression efficiency reached 97.86%, and the reaction rate constant was nearly zero, suggesting negligible hydrogen production. Cinnamomum camphor leaf extract spontaneously adsorbs onto the Al-Zn dust surface, following the monolayer Langmuir model and involving both physical and chemical adsorption. The surface analysis reveals that Cinnamomum camphor leaf extract forms a protective film on the Al-Zn dust via complexation, effectively preventing dust-water contact and suppressing hydrogen evolution. Tests under varying external conditions demonstrated that Cinnamomum camphor leaf extract consistently suppressed hydrogen evolution from Al-Zn dust, despite variations in temperature fluctuations, pressure changes, and water disturbances in the wet dust collection system.

, authors=Tengteng HAO, Kaili XU, Haojie WANG, Chenyang NI, Jihang SHI, authorsList=Tengteng HAO, Kaili XU, Haojie WANG, Chenyang NI, Jihang SHI, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1282029983463878930, articleId=1282029981932957968, tenantId=1146029695717560320, journalId=1146031787341344770, language=CN, title=香樟叶提取物对铝锌废尘湿式除尘产氢的抑制影响研究, columnId=1149733269727526997, journalTitle=中国安全科学学报, columnName=安全工程技术, runingTitle=null, highlight=null, articleAbstract=

为实现湿式除尘系统绿色本质化安全运行,降低铝锌废尘遇水产氢引发火灾、爆炸事故的风险,利用金属与水产氢测试系统和煎煮法制备的水基香樟叶提取物,开展质量浓度作用下的抑氢有效性试验,基于表面分析得出香樟叶提取物抑制铝锌(Al-Zn)粉产氢的吸附行为学特征、化学反应动力学参数和抑氢机制,评估最佳香樟叶提取物质量浓度在多变环境条件下的抑氢可靠性。结果表明:随着质量浓度升高,香樟叶提取物对Al-Zn粉遇水产氢的抑制效果逐渐增强,当质量浓度为50 mg/L时,抑氢效率为97.86%,化学反应速率常数接近于0,几乎无氢气产生。香樟叶提取物可自发吸附在Al-Zn粉表面,其吸附行为符合单层Langmuir模型,包括物理和化学双重吸附机制。香樟叶提取物通过络合作用在Al-Zn粉表面形成抑制膜,可有效阻隔颗粒与水接触,从而抑制金属产氢行为。在湿式除尘器内温度变化、压强波动和水体扰动的影响下,香樟叶提取物对Al-Zn粉产氢具有稳定的抑制效果。

, authors=郝腾腾, 许开立教授, 王浩杰, 倪辰阳, 史继航, authorsList=郝腾腾, 许开立教授, 王浩杰, 倪辰阳, 史继航, authorCompany=null, correspAuthors=null, authorNote=

郝腾腾(1998—),男,山东菏泽人,博士研究生,主要研究方向为轻金属加工火灾爆炸预防技术。E-mail:

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郝腾腾(1998—),男,山东菏泽人,博士研究生,主要研究方向为轻金属加工火灾爆炸预防技术。E-mail:

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郝腾腾(1998—),男,山东菏泽人,博士研究生,主要研究方向为轻金属加工火灾爆炸预防技术。E-mail:

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香樟叶提取物对铝锌废尘湿式除尘产氢的抑制影响研究
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郝腾腾 , 许开立教授 , 王浩杰 , 倪辰阳 , 史继航
中国安全科学学报 | 安全工程技术 2025,35(7): 159-166
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中国安全科学学报 |安全工程技术 2025 , 35 (7) : 159 -166
香樟叶提取物对铝锌废尘湿式除尘产氢的抑制影响研究
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郝腾腾 , 许开立教授, 王浩杰, 倪辰阳, 史继航
作者信息
  • 东北大学 资源与土木工程学院,辽宁 沈阳 110819
作者简介:

郝腾腾(1998—),男,山东菏泽人,博士研究生,主要研究方向为轻金属加工火灾爆炸预防技术。E-mail:

Investigation of inhibitory influence of cinnamomum camphora leaf extract on hydrogen evolution from Al-Zn dust in wet dust removal
Tengteng HAO , Kaili XU, Haojie WANG, Chenyang NI, Jihang SHI
Affiliations
  • School of Resources and Civil Engineering, Northeastern University, Shenyang Liaoning 110819, China
出版时间: 2025-07-28 doi: 10.16265/j.cnki.issn1003-3033.2025.07.1677
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为实现湿式除尘系统绿色本质化安全运行,降低铝锌废尘遇水产氢引发火灾、爆炸事故的风险,利用金属与水产氢测试系统和煎煮法制备的水基香樟叶提取物,开展质量浓度作用下的抑氢有效性试验,基于表面分析得出香樟叶提取物抑制铝锌(Al-Zn)粉产氢的吸附行为学特征、化学反应动力学参数和抑氢机制,评估最佳香樟叶提取物质量浓度在多变环境条件下的抑氢可靠性。结果表明:随着质量浓度升高,香樟叶提取物对Al-Zn粉遇水产氢的抑制效果逐渐增强,当质量浓度为50 mg/L时,抑氢效率为97.86%,化学反应速率常数接近于0,几乎无氢气产生。香樟叶提取物可自发吸附在Al-Zn粉表面,其吸附行为符合单层Langmuir模型,包括物理和化学双重吸附机制。香樟叶提取物通过络合作用在Al-Zn粉表面形成抑制膜,可有效阻隔颗粒与水接触,从而抑制金属产氢行为。在湿式除尘器内温度变化、压强波动和水体扰动的影响下,香樟叶提取物对Al-Zn粉产氢具有稳定的抑制效果。

香樟叶提取物  /  湿式除尘  /  铝锌(Al-Zn)粉  /  抑氢剂  /  抑氢效率  /  吸附行为

In order to promote the safe and eco-friendly operation of wet dust collection systems by mitigating hydrogen fire and explosion risks caused by metal waste dust in contact with water, a custom-designed metal-water hydrogen evolution testing system and a water-based Cinnamomum camphor leaf extract (prepared via decoction) were utilized. Experiments assessed the hydrogen suppression efficiency of Cinnamomum camphor leaf extract at various mass concentrations. Surface analysis and theoretical calculations were conducted to study the adsorption behavior, chemical reaction kinetics, and inhibition mechanism of Cinnamomum camphor leaf extract on hydrogen evolution from aluminum-zinc (Al-Zn) dust. The hydrogen suppression stability at the optimal mass concentration was evaluated under varying environmental conditions. Experimental results demonstrated that higher mass concentrations of extract improved its ability to suppress hydrogen evolution from Al-Zn dust. At a mass concentration of 50 mg/L, the hydrogen suppression efficiency reached 97.86%, and the reaction rate constant was nearly zero, suggesting negligible hydrogen production. Cinnamomum camphor leaf extract spontaneously adsorbs onto the Al-Zn dust surface, following the monolayer Langmuir model and involving both physical and chemical adsorption. The surface analysis reveals that Cinnamomum camphor leaf extract forms a protective film on the Al-Zn dust via complexation, effectively preventing dust-water contact and suppressing hydrogen evolution. Tests under varying external conditions demonstrated that Cinnamomum camphor leaf extract consistently suppressed hydrogen evolution from Al-Zn dust, despite variations in temperature fluctuations, pressure changes, and water disturbances in the wet dust collection system.

Cinnamomum camphor leaf extract  /  wet dust collection  /  aluminum-zinc (Al-Zn) dust  /  hydrogen inhibitor  /  hydrogen suppression efficiency  /  adsorption behavior
郝腾腾, 许开立教授, 王浩杰, 倪辰阳, 史继航. 香樟叶提取物对铝锌废尘湿式除尘产氢的抑制影响研究. 中国安全科学学报, 2025 , 35 (7) : 159 -166 . DOI: 10.16265/j.cnki.issn1003-3033.2025.07.1677
Tengteng HAO, Kaili XU, Haojie WANG, Chenyang NI, Jihang SHI. Investigation of inhibitory influence of cinnamomum camphora leaf extract on hydrogen evolution from Al-Zn dust in wet dust removal[J]. China Safety Science Journal, 2025 , 35 (7) : 159 -166 . DOI: 10.16265/j.cnki.issn1003-3033.2025.07.1677
  • 国家自然科学基金资助(52074066)
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doi: 10.16265/j.cnki.issn1003-3033.2025.07.1677
  • 接收时间:2025-03-10
  • 首发时间:2026-07-09
  • 出版时间:2025-07-28
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  • 收稿日期:2025-03-10
  • 修回日期:2025-05-22
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国家自然科学基金资助(52074066)
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    东北大学 资源与土木工程学院,辽宁 沈阳 110819
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2种不同金属材料的力学参数

Family
属数
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genus
种数
Number of
species
占总种数比例
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total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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