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In order to address the safety and environmental risks associated with aqueous ammonia leakage accidents in the chemical industry, based on the rich pore structure and physicochemical properties of porous materials, AC and zeolite were selected as the basic raw materials for detergents. The powder detergents AC@AlCl₃ and Zeolite@AlCl₃ were prepared by impregnating with an AlCl₃ solution of varying mass fractions. Using aqueous ammonia as the target contaminant, systematic experiments were conducted involving both individual decontamination and combined powder-liquid decontamination, employing the aforementioned modified powdered decontaminants along with various surfactants. By evaluating indicators such as decontaminant dosage, volume fraction of volatile gas, and the morphology of decontamination products, the effectiveness of individual versus combined decontamination was compared, and the practical performance of the powder-liquid synergistic decontamination strategy was comprehensively assessed. The results demonstrate a significant enhancement in the decontamination capacity of the modified powders, with decontamination efficiencies for aqueous ammonia exceeding 70%. Among the samples, AC@20%AlCl₃, combined with a 3% NaHCO₃ powder solution, forms a more complete gel-like solid during the decontamination process, and the decontamination efficiency reaches 80%. This approach successfully realizes the goals of high efficiency, cost-effectiveness, and safety in aqueous ammonia decontamination.

, authors=Bihe YUAN, Guangyi ZHANG, Zhezhe TAN, Chunying LEI^**, authorsList=Bihe YUAN, Guangyi ZHANG, Zhezhe TAN, Chunying LEI, authorCompany=null, correspAuthors=Chunying LEI, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1281616670221382197, articleId=1281616669785174579, tenantId=1146029695717560320, journalId=1146031787341344770, language=CN, title=氨水泄漏的粉液共洗消试验研究, columnId=1277328337940902469, journalTitle=中国安全科学学报, columnName=安全技术与工程, runingTitle=null, highlight=null, articleAbstract=

为解决化工行业氨水泄漏事故引发的安全与环境风险，基于多孔材料丰富的孔隙结构和物化性质，选用活性炭（AC）和沸石作为洗消剂的基本原料，通过浸渍不同质量分数AlCl₃溶液，制备粉体洗消剂AC@AlCl₃和Zeolite@AlCl₃。以氨水为洗消对象，采用上述改性粉体洗消剂，并结合多种表面活性剂，系统开展单一洗消与粉液共洗消试验。通过考察洗消剂用量、挥发气体体积分数及洗消产物形态等指标，对比单一洗消与共洗消的效果，综合评价粉液协同洗消策略的实际表现。结果表明：改性后粉体的洗消能力得到显著提升，对氨水的洗消效率均超过70%。其中，AC@20%AlCl₃和3% NaHCO₃粉液组合在洗消过程中可形成较为完整的凝胶固化物，洗消效率达到80%，可实现高效、经济且安全的氨水洗消目标。

, authors=袁必和教授, 张广毅, 谈哲哲, 雷春英实验师^**, authorsList=袁必和教授, 张广毅, 谈哲哲, 雷春英实验师, authorCompany=null, correspAuthors=雷春英实验师, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=GM6gBLq/MoSv1NhmC2tRKg==, magXml=yKZ7A2TG1GosMKNd3mXt2A==, pdfUrl=null, pdf=pHUWvLeD+33oNeN8s/sbrA==, pdfFileSize=2067818, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=+moNLoJm0Btyd6OKxdamkA==, mapNumber=null, fund=null)}, authors=[Author(id=1281616670514983482, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281616669785174579, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=yuanbh@whut.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1281616670615646780, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281616669785174579, authorId=1281616670514983482, language=EN, stringName=Bihe YUAN, firstName=Bihe, middleName=null, lastName=YUAN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Safety Science and Emergency Management, Wuhan University of Technology, Wuhan Hubei 430070, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1281616670695338557, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281616669785174579, authorId=1281616670514983482, language=CN, stringName=袁必和教授, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=武汉理工大学 安全科学与应急管理学院，湖北 武汉 430070, bio={"content":"

袁必和（1988—），男，安徽合肥人，博士，教授，主要从事燃烧与阻燃机制、新能源热安全与风险防控、工业热安全与防火防爆技术、聚合物基复合材料、安全智能传感与监测预警技术等方面的研究。E-mail: yuanbh@whut.edu.cn。

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袁必和（1988—），男，安徽合肥人，博士，教授，主要从事燃烧与阻燃机制、新能源热安全与风险防控、工业热安全与防火防爆技术、聚合物基复合材料、安全智能传感与监测预警技术等方面的研究。E-mail: yuanbh@whut.edu.cn。

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