Article(id=1281608095591805790, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1281608054340829934, articleNumber=null, orderNo=null, doi=10.16265/j.cnki.issn1003-3033.2026.04.1002, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1761753600000, receivedDateStr=2025-10-30, revisedDate=1768060800000, revisedDateStr=2026-01-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1783488781116, onlineDateStr=2026-07-08, pubDate=1777305600000, pubDateStr=2026-04-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1783488781116, onlineIssueDateStr=2026-07-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1783488781116, creator=13701087609, updateTime=1783488781116, updator=13701087609, issue=Issue{id=1281608054340829934, tenantId=1146029695717560320, journalId=1146031787341344770, year='2026', volume='36', issue='4', pageStart='1', pageEnd='286', issueExtLink='null', onlineDate='null', pubDate='1777305600000', pubDateStr='2026-04-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1783488771281, creator='13701087609', updateTime=1783588648031, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1282026967885124001, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1281608054340829934, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1282026967885124002, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1281608054340829934, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=152, endPage=159, ext={EN=ArticleExt(id=1281608095797326687, articleId=1281608095591805790, tenantId=1146029695717560320, journalId=1146031787341344770, language=EN, title=Performance mechanism of supported cobalt-copper catalyst for CO elimination, columnId=1277328337617941059, journalTitle=China Safety Science Journal, columnName=Safety Technology and Engineering, runingTitle=null, highlight=null, articleAbstract=

In order to realize the effective elimination of CO in the tail gas of mine trackless rubber-tyred vehicle, the development of high-performance CO elimination reaction catalyst was focused on in this study. Co₃O₄/CuO/Ni Foam(NF) supported catalyst was prepared by one-step solvothermal synthesis method. Characterization analyses, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and specific surface area measurement (BET), were conducted to investigate the effects of synthesis conditions such as synthesis time, synthesis temperature, and growth substrate, as well as physicochemical properties such as catalyst composition and morphological characteristics, on catalytic performance of catalyst. The optimal synthesis conditions and CO elimination performance of catalyst were determined. Hydrogen temperature-programmed reduction (H₂-TPR), oxygen temperature-programmed desorption (O₂-TPD), and in-situ infrared spectroscopy were employed to explore the intermediate processes of CO elimination catalyzed by the catalyst, revealing the catalytic mechanism of CO elimination by the catalyst. The results show that the optimal synthesis condition of Co₃O₄/CuO/NF supported catalyst is 140 ℃ for 4 h. Under this condition, the catalyst can completely eliminate CO at the elimination temperature of 150 ℃, and the elimination process of CO by the catalyst follows the Mars-van-Krevelen(MvK) mechanism.

, authors=Yifei Teng^{1, 2}, Ziqi He^{1, 2}, Yu Fu^{1, 2}, Mingxu Quan^{1, 2}, Chang Liu^{1, 2}, Zheng Cui^{1, 2}, authorsList=Yifei Teng, Ziqi He, Yu Fu, Mingxu Quan, Chang Liu, Zheng Cui, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1281608096359363426, articleId=1281608095591805790, tenantId=1146029695717560320, journalId=1146031787341344770, language=CN, title=负载型钴铜催化剂催化CO消除性能机制, columnId=1277328337940902469, journalTitle=中国安全科学学报, columnName=安全技术与工程, runingTitle=null, highlight=null, articleAbstract=

为有效消除矿用无轨胶轮车尾气中CO，开发高性能CO消除反应催化剂，利用一步溶剂热合成法制备Co₃O₄/CuO/泡沫镍（NF）负载型催化剂，通过X-射线衍射（XRD）、X-射线光电子能谱（XPS）、扫描电子显微镜（SEM）、比表面积测试（BET）等表征分析，研究合成时间、合成温度、生长基底等合成条件以及催化剂的组成成分、形貌特征等物化特性对催化剂催化性能的影响，明确催化剂的最佳合成条件与CO消除性能；通过氢气程序升温还原（H₂-TPR）与氧气程序升温脱附（O₂-TPD）与原位红外光谱分析，探究催化剂催化CO消除的反应中间过程，揭示催化剂消除CO的催化机制。研究结果表明：Co₃O₄/CuO/NF负载型催化剂的最佳合成条件为140 ℃反应4 h，该条件下所得催化剂可在消除温度150 ℃时完全消除CO，而催化剂对CO的消除过程则遵循MvK机制。

, authors=滕弋非副教授^{1, 2}, 赫梓岐^{1, 2}, 付钰^{1, 2}, 全明旭^{1, 2}, 刘唱副教授^{1, 2}, 崔政讲师^{1, 2}, authorsList=滕弋非副教授, 赫梓岐, 付钰, 全明旭, 刘唱副教授, 崔政讲师, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=5x1d69RX4dG6AcJK34RcjA==, magXml=dAAADpAn4NVCGTAyi6V/8Q==, pdfUrl=null, pdf=cEWB1oYNNv09Wpf0OEKJxA==, pdfFileSize=9797835, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=Aqni9zonF6ekRa/OnrXmOw==, mapNumber=null, fund=null)}, authors=[Author(id=1281608096950760298, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281608095591805790, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=395420278@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1281608097055617901, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281608095591805790, authorId=1281608096950760298, language=EN, stringName=Yifei Teng, firstName=Yifei, middleName=null, lastName=Teng, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=^{1, 2}, address=¹College of Safety Science and Engineering, Liaoning Technical University, Huludao Liaoning 125105, China
²Key Laboratory of Mine Thermodynamic Disasters and Control of Ministry of Education, Liaoning Technical University, Huludao Liaoning 125105, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1281608097147892590, tenantId=1146029695717560320, journalId=1146031787341344770, articleId=1281608095591805790, authorId=1281608096950760298, language=CN, stringName=滕弋非副教授, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=^{1, 2}, address=¹辽宁工程技术大学 安全科学与工程学院，辽宁 葫芦岛 125105
²辽宁工程技术大学 矿山热动力灾害与防治教育部重点实验室，辽宁 葫芦岛 125105, bio={"content":"

滕弋非（1992—），男，辽宁沈阳人，博士，副教授，主要从事有害气体消除等方面的研究工作。E-mail:395420278@qq.com。

"}, bioImg=null, bioContent=

滕弋非（1992—），男，辽宁沈阳人，博士，副教授，主要从事有害气体消除等方面的研究工作。E-mail:395420278@qq.com。

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