Article(id=1282037451099193886, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282037390130790473, articleNumber=null, orderNo=null, doi=10.16265/j.cnki.issn1003-3033.2025.12.0064, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1751212800000, receivedDateStr=2025-06-30, revisedDate=1758384000000, revisedDateStr=2025-09-21, acceptedDate=null, acceptedDateStr=null, onlineDate=1783591147445, onlineDateStr=2026-07-09, pubDate=1766851200000, pubDateStr=2025-12-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1783591147445, onlineIssueDateStr=2026-07-09, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1783591147445, creator=13701087609, updateTime=1783591147445, updator=13701087609, issue=Issue{id=1282037390130790473, tenantId=1146029695717560320, journalId=1146031787341344770, year='2025', volume='35', issue='12', pageStart='1', pageEnd='259', issueExtLink='null', onlineDate='null', pubDate='1766851200000', pubDateStr='2025-12-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1783591132910, creator='13701087609', updateTime=1783593783109, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1282048505929777979, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282037390130790473, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1282048505929777980, tenantId=1146029695717560320, journalId=1146031787341344770, issueId=1282037390130790473, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=164, endPage=171, ext={EN=ArticleExt(id=1282037451346657823, articleId=1282037451099193886, tenantId=1146029695717560320, journalId=1146031787341344770, language=EN, title=Study on thermal and flame retardant properties of hydrated phase change materials for preventing coal spontaneous combustion, columnId=1149733269173878863, journalTitle=China Safety Science Journal, columnName=Safety engineering technology, runingTitle=null, highlight=null, articleAbstract=
To effectively suppress the transition of coal spontaneous combustion oxidation in goaf areas into the accelerated stage, a stable and high-heat-storage PCM was prepared using ammonium aluminum sulfate dodecahydrate and magnesium sulfate heptahydrate as raw materials. Through differential scanning calorimetry tests, solid-liquid transition tests, programmed heating tests, infrared spectroscopy, thermal insulation tests, and microscopic analysis, PCM thermal properties, the driving mechanism of solid-liquid transition, heat storage capacity, and coal oxidation inhibitory performance were studied. The test results show that the developed material has a phase transition temperature of 66.8℃, a latent heat of phase transition of 300.708 J/g, and a relatively low specific heat capacity during the heating process. The melting time exhibits an exponential decrease with increasing temperature, and a dense covering film forms after melting. When the material is added at a mass fraction of 15%, the inhibitory rate reaches 41%. Under a 500℃ heat source, with a material thickness of 30 mm, the effective thermal insulation time reaches 65 minutes.
, authors=Jingjing LI
1, Yi LU
**, 1, 2, 3, Shuzhen SHAO
1, Shiliang SHI
1, Zhengjing SHI
4, Bo YU
5, authorsList=Jingjing LI, Yi LU, Shuzhen SHAO, Shiliang SHI, Zhengjing SHI, Bo YU, authorCompany=null, correspAuthors=Yi LU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1282037452906938914, articleId=1282037451099193886, tenantId=1146029695717560320, journalId=1146031787341344770, language=CN, title=防治煤自燃的水合相变材料热学及阻燃特性研究, columnId=1149733269727526997, journalTitle=中国安全科学学报, columnName=安全工程技术, runingTitle=null, highlight=null, articleAbstract=
为有效抑制采空区煤自燃氧化进入加速阶段,以十二水硫酸铝铵和七水硫酸镁为原料,制备性能稳定、储热量大的水合相变材料(PCM);通过差示扫描量热试验、固流转换试验、程序升温试验、红外光谱试验、隔热试验及微观分析等手段,分析材料的热学性能、固流转换的驱动机理、储热性及阻化性能。结果表明:所研发材料的相变温度为66.8 ℃,相变潜热为300.708 J/g,升温过程中具有较低的比热容;其融化时间随温度升高呈指数型下降,融化后可形成较为致密的覆盖膜;当材料添加量为15%时,阻化率达到41%;在500 ℃热源条件下,材料厚度为30 mm时,有效隔热时间可达65 min。
, authors=李竟境
1, 鲁义
教授**, 1, 2, 3, 邵淑珍
1, 施式亮
教授1, 史正景
4, 余波
5, authorsList=李竟境, 鲁义
教授, 邵淑珍, 施式亮
教授, 史正景, 余波, authorCompany=null, correspAuthors=鲁义
教授, authorNote=
, correspAuthorsNote=
** 鲁义(1986—),男,江西新干人, 博士,教授,主要从事煤自燃与瓦斯灾害防治方面的研究。E-mail:
luyijx@163.com。
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李竟境(2002—),女,陕西西安人,硕士研究生,主要研究方向为火灾科学与技术。E-mail: 1759668601@qq.com。
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李竟境(2002—),女,陕西西安人,硕士研究生,主要研究方向为火灾科学与技术。E-mail: 1759668601@qq.com。
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