Article(id=1311360837168755657, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360814477575028, articleNumber=null, orderNo=null, doi=10.13426/j.cnki.yky.2025.12.12, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1766073600000, receivedDateStr=2025-12-19, revisedDate=1769788800000, revisedDateStr=2026-01-31, acceptedDate=null, acceptedDateStr=null, onlineDate=1790582387487, onlineDateStr=2026-09-28, pubDate=1787155200000, pubDateStr=2026-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790582387487, onlineIssueDateStr=2026-09-28, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790582387487, creator=13701087609, updateTime=1790582387487, updator=13701087609, issue=Issue{id=1311360814477575028, tenantId=1146029695717560320, journalId=1146123346816638986, year='2026', volume='45', issue='3', pageStart='1', pageEnd='172', issueExtLink='null', onlineDate='null', pubDate='1787155200000', pubDateStr='2026-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1790582382077, creator='13701087609', updateTime=1790583873531, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1311367070160355561, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360814477575028, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1311367070160355562, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360814477575028, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=75, endPage=87, ext={EN=ArticleExt(id=1311360837399442378, articleId=1311360837168755657, tenantId=1146029695717560320, journalId=1146123346816638986, language=EN, title=Dissolution Effect of Small Molecule Organic Acids on Biotite, columnId=1175805041752556213, journalTitle=Uranium Mining and Metallurgy, columnName=Mining and Hydrometallurgy, runingTitle=null, highlight=null, articleAbstract=

To enhance the leachability of low-permeability uranium-bearing strata during in-situ leaching of uranium, biotite—a mineral commonly enriched in the Nalinggou sandstone type uranium deposit, which often leads to localized densification and impeded fluid flow—was systematically investigated for its dissolution behavior in the presence of three low-molecular-weight organic acids: citric acid, tartaric acid, and succinic acid. A comparative study was conducted through dissolution experiments and PHREEQC simulations, combined with analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) surface area analysis. The research focused on the mechanisms of structural alteration, cation release characteristics, and pore parameter evolution of biotite under varying organic acid concentrations. The results demonstrate that organic acids significantly enhance biotite dissolution, leading to increased cation release, aggravated crystal structure degradation, and expanded specific surface area and pore volume. These effects intensify with higher acid concentrations. Among the tested acids, tartaric acid exhibited the most pronounced dissolution effect, increasing the specific surface area from 4.071 8 m2/g to 9.184 5 m2/g. PHREEQC simulations revealed that organic acids effectively inhibit the precipitation of Al (OH)3 and iron oxides by complexing with Al3+ and Fe3+, thereby prolonging the mineral dissolution process. The study indicates that low-molecular-weight organic acids can improve the permeability of uranium-bearing layers by enhancing mineral dissolution and optimizing pore structure. These findings provide a theoretical foundation and technical support for improving uranium leachability.

, authors=Can WANG1, 2, Yang LING1, 2, Hui ZHANG1, 2, Feng LI1, 2, Dexin DING1, 2, authorsList=Can WANG, Yang LING, Hui ZHANG, Feng LI, Dexin DING, authorCompany=null, correspAuthors=Hui ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1311360837676266443, articleId=1311360837168755657, tenantId=1146029695717560320, journalId=1146123346816638986, language=CN, title=小分子有机酸对黑云母溶蚀作用的试验研究, columnId=1175805041991631542, journalTitle=铀矿冶, columnName=开采·选冶, runingTitle=null, highlight=null, articleAbstract=

为提升地浸采铀低渗透性矿层的可浸出性,以纳岭沟砂岩型铀矿床中富集且常导致砂岩局部物性致密、阻碍渗流的黑云母为研究对象,系统开展了柠檬酸、酒石酸和琥珀酸3种小分子有机酸对其溶蚀作用的对比研究。通过溶蚀试验、PHREEQC模拟,并结合X射线衍射(XRD)、扫描电镜(SEM)和比表面积测试(BET)等分析手段,探讨了在不同有机酸浓度下黑云母的结构破坏机制、阳离子释放特征及孔隙参数变化。结果表明,有机酸对黑云母具有显著溶蚀能力,表现为阳离子溶出增强、晶体结构破坏加剧、比表面积和孔体积增加,且作用效果随酸浓度升高而增强。其中,酒石酸对黑云母的溶蚀效果最为显著,可使其比表面积从4.071 8 m2/g提高至9.184 5 m2/g。PHREEQC模拟结果显示,有机酸通过配合Al3+和Fe3+,可有效抑制Al(OH)3的生成和铁氧化物的沉淀,延长矿物溶解过程。研究表明,小分子有机酸可通过增强矿物溶解和优化孔隙结构而改善铀矿层渗透性,研究结果为提升铀的可浸出性提供了理论依据和技术支撑。

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张辉
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小分子有机酸对黑云母溶蚀作用的试验研究
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王灿 1, 2 , 凌阳 1, 2 , 张辉 1, 2 , 李峰 1, 2 , 丁德馨 1, 2
铀矿冶 | 开采·选冶 2026,45(3): 75-87
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铀矿冶 |开采·选冶 2026 , 45 (3) : 75 -87
小分子有机酸对黑云母溶蚀作用的试验研究
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王灿1, 2, 凌阳1, 2, 张辉1, 2, 李峰1, 2, 丁德馨1, 2
作者信息
  • 1.南华大学铀矿冶生物技术国防重点学科实验室,湖南 衡阳 421001
  • 2.南华大学资源环境与安全工程学院,湖南 衡阳 421001
通讯作者:
张辉
Dissolution Effect of Small Molecule Organic Acids on Biotite
Can WANG1, 2, Yang LING1, 2, Hui ZHANG1, 2, Feng LI1, 2, Dexin DING1, 2
Affiliations
  • 1.National Defense Key Discipline Laboratory of Uranium Mining and Metallurgy Biotechnology, University of South China, Hengyang 421000, China
  • 2.College of Resources Environment and Safety Engineering, University of South China, Hengyang 421000, China
出版时间: 2026-08-20 doi: 10.13426/j.cnki.yky.2025.12.12
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为提升地浸采铀低渗透性矿层的可浸出性,以纳岭沟砂岩型铀矿床中富集且常导致砂岩局部物性致密、阻碍渗流的黑云母为研究对象,系统开展了柠檬酸、酒石酸和琥珀酸3种小分子有机酸对其溶蚀作用的对比研究。通过溶蚀试验、PHREEQC模拟,并结合X射线衍射(XRD)、扫描电镜(SEM)和比表面积测试(BET)等分析手段,探讨了在不同有机酸浓度下黑云母的结构破坏机制、阳离子释放特征及孔隙参数变化。结果表明,有机酸对黑云母具有显著溶蚀能力,表现为阳离子溶出增强、晶体结构破坏加剧、比表面积和孔体积增加,且作用效果随酸浓度升高而增强。其中,酒石酸对黑云母的溶蚀效果最为显著,可使其比表面积从4.071 8 m2/g提高至9.184 5 m2/g。PHREEQC模拟结果显示,有机酸通过配合Al3+和Fe3+,可有效抑制Al(OH)3的生成和铁氧化物的沉淀,延长矿物溶解过程。研究表明,小分子有机酸可通过增强矿物溶解和优化孔隙结构而改善铀矿层渗透性,研究结果为提升铀的可浸出性提供了理论依据和技术支撑。

黑云母  /  有机酸  /  溶蚀  /  孔隙  /  渗透性  /  地浸采铀  /  砂岩型铀矿

To enhance the leachability of low-permeability uranium-bearing strata during in-situ leaching of uranium, biotite—a mineral commonly enriched in the Nalinggou sandstone type uranium deposit, which often leads to localized densification and impeded fluid flow—was systematically investigated for its dissolution behavior in the presence of three low-molecular-weight organic acids: citric acid, tartaric acid, and succinic acid. A comparative study was conducted through dissolution experiments and PHREEQC simulations, combined with analytical techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) surface area analysis. The research focused on the mechanisms of structural alteration, cation release characteristics, and pore parameter evolution of biotite under varying organic acid concentrations. The results demonstrate that organic acids significantly enhance biotite dissolution, leading to increased cation release, aggravated crystal structure degradation, and expanded specific surface area and pore volume. These effects intensify with higher acid concentrations. Among the tested acids, tartaric acid exhibited the most pronounced dissolution effect, increasing the specific surface area from 4.071 8 m2/g to 9.184 5 m2/g. PHREEQC simulations revealed that organic acids effectively inhibit the precipitation of Al (OH)3 and iron oxides by complexing with Al3+ and Fe3+, thereby prolonging the mineral dissolution process. The study indicates that low-molecular-weight organic acids can improve the permeability of uranium-bearing layers by enhancing mineral dissolution and optimizing pore structure. These findings provide a theoretical foundation and technical support for improving uranium leachability.

biotite  /  organic acids  /  dissolution  /  porosity  /  permeability  /  in-situ leaching of uranium  /  sandstone type uranium deposit
王灿, 凌阳, 张辉, 李峰, 丁德馨. 小分子有机酸对黑云母溶蚀作用的试验研究. 铀矿冶, 2026 , 45 (3) : 75 -87 . DOI: 10.13426/j.cnki.yky.2025.12.12
Can WANG, Yang LING, Hui ZHANG, Feng LI, Dexin DING. Dissolution Effect of Small Molecule Organic Acids on Biotite[J]. Uranium Mining and Metallurgy, 2026 , 45 (3) : 75 -87 . DOI: 10.13426/j.cnki.yky.2025.12.12
  • 国家自然科学基金面上项目(42277264)
  • 核技术研发科研项目[HNKF202311(48)
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doi: 10.13426/j.cnki.yky.2025.12.12
  • 接收时间:2025-12-19
  • 首发时间:2026-09-28
  • 出版时间:2026-08-20
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  • 收稿日期:2025-12-19
  • 修回日期:2026-01-31
基金
国家自然科学基金面上项目(42277264)
核技术研发科研项目[HNKF202311(48)
作者信息
    1.南华大学铀矿冶生物技术国防重点学科实验室,湖南 衡阳 421001
    2.南华大学资源环境与安全工程学院,湖南 衡阳 421001

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张辉
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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