Article(id=1311360781577450051, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360779169919555, articleNumber=null, orderNo=null, doi=10.13426/j.cnki.yky.2025.09.06, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1757174400000, receivedDateStr=2025-09-07, revisedDate=1761235200000, revisedDateStr=2025-10-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1790582374233, onlineDateStr=2026-09-28, pubDate=1779206400000, pubDateStr=2026-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790582374233, onlineIssueDateStr=2026-09-28, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790582374233, creator=13701087609, updateTime=1790582374233, updator=13701087609, issue=Issue{id=1311360779169919555, tenantId=1146029695717560320, journalId=1146123346816638986, year='2026', volume='45', issue='2', pageStart='1', pageEnd='156', issueExtLink='null', onlineDate='null', pubDate='1779206400000', pubDateStr='2026-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1790582373659, creator='13701087609', updateTime=1790583908456, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1311367216646418706, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360779169919555, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1311367216646418707, tenantId=1146029695717560320, journalId=1146123346816638986, issueId=1311360779169919555, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1, endPage=11, ext={EN=ArticleExt(id=1311360781787165252, articleId=1311360781577450051, tenantId=1146029695717560320, journalId=1146123346816638986, language=EN, title=Research Progress on the Blockage of In-situ Leaching Uranium Induced by Clay Minerals and Pyrite, columnId=1179340519550370065, journalTitle=Uranium Mining and Metallurgy, columnName=Cover Article, runingTitle=null, highlight=null, articleAbstract=

In-situ leaching (ISL) of uranium, a core technology in China's uranium mining, faces significant challenges due to pore blockage caused by clay minerals and pyrite, which severely restricts leaching efficiency and production capacity. This paper systematically reviews the causes and mechanisms of blocking phenomena in acid leaching, alkaline leaching, and "CO2 + O2" neutral leaching processes. It reveals that clay minerals induce pore blockage through physicochemical interactions such as swelling, ion exchange, and argillization of non-clay minerals, while pyrite oxidation generates sulfate and iron ions, leading to permeability reduction via mineral precipitation and colloidal adsorption. Current unblocking technologies primarily employ inhibitors to suppress pyrite oxidation, chelating agents to immobilize iron-containing precipitates, and swelling suppressants to mitigate clay mineral expansion. However, challenges remain, including lack of specificity, limited environmental compatibility, and insufficient long-term stability. Future research should focus on elucidating the synergistic mechanisms of clay-pyrite interactions, developing intelligent unblocking materials with targeted functionality, and establishing ecological risk assessment frameworks. These advancements aim to drive innovation in green and efficient unblocking technologies, providing theoretical and technical support for China's large-scale uranium base construction and sustainable nuclear energy development.

, authors=Xuerui ZHAO1, 2, Zhenzhong LIU1, Chunguang LI1, 2, Ying XU3, Xianzhe DUAN1, Weimin QUE3, Zhenping TANG1, authorsList=Xuerui ZHAO, Zhenzhong LIU, Chunguang LI, Ying XU, Xianzhe DUAN, Weimin QUE, Zhenping TANG, authorCompany=null, correspAuthors=Zhenzhong LIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1311360782198207045, articleId=1311360781577450051, tenantId=1146029695717560320, journalId=1146123346816638986, language=CN, title=黏土矿和黄铁矿诱发地浸采铀堵塞的研究进展, columnId=1171165155376275591, journalTitle=铀矿冶, columnName=封面文章, runingTitle=null, highlight=null, articleAbstract=

在地浸采铀生产过程中,由黏土矿与黄铁矿引发的堵塞问题严重制约了浸出效率与产能提升。笔者系统综述了酸法、碱法及“CO2 +O2”中性浸出工艺中堵塞现象的成因与影响机制,揭示了黏土矿物通过膨胀、离子置换以及非黏土矿物黏土化等物理化学作用导致孔隙堵塞的关键过程,阐明了黄铁矿氧化产生的硫酸根与铁离子通过矿物沉淀、胶体吸附等途径引发的渗透性下降问题。针对上述堵塞机制,现有解堵技术主要采用加入抑制剂阻断黄铁矿氧化、加入螯合剂生成铁系沉淀物及采用抑膨剂调控黏土矿物膨胀等策略,但仍存在靶向性与环境兼容性不足等问题。未来研究需聚焦黏土-黄铁矿协同作用机理解析、智能解堵材料开发及生态风险评估体系构建,以推动绿色高效解堵技术的创新,为中国铀矿大基地建设与核能可持续发展提供理论支撑与技术保障。

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黏土矿和黄铁矿诱发地浸采铀堵塞的研究进展
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赵学瑞 1, 2 , 刘振中 1 , 李春光 1, 2 , 许影 3 , 段先哲 1 , 阙为民 3 , 唐振平 1
铀矿冶 | 封面文章 2026,45(2): 1-11
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铀矿冶 |封面文章 2026 , 45 (2) : 1 -11
黏土矿和黄铁矿诱发地浸采铀堵塞的研究进展
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赵学瑞1, 2, 刘振中1, 李春光1, 2, 许影3, 段先哲1, 阙为民3, 唐振平1
作者信息
  • 1.南华大学 资源环境与安全工程学院,湖南 衡阳 421001
  • 2.南华大学 放射性废物处理处置与数学模型研发中心,湖南 衡阳 421001
  • 3.核工业北京化工冶金研究院,北京 101149
通讯作者:
刘振中
Research Progress on the Blockage of In-situ Leaching Uranium Induced by Clay Minerals and Pyrite
Xuerui ZHAO1, 2, Zhenzhong LIU1, Chunguang LI1, 2, Ying XU3, Xianzhe DUAN1, Weimin QUE3, Zhenping TANG1
Affiliations
  • 1.School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, China
  • 2.R&D Center of Radioactive Waste Treatment, Disposal and Modeling, University of South China, Hengyang 421001, China
  • 3.Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing 101149, China
出版时间: 2026-05-20 doi: 10.13426/j.cnki.yky.2025.09.06
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在地浸采铀生产过程中,由黏土矿与黄铁矿引发的堵塞问题严重制约了浸出效率与产能提升。笔者系统综述了酸法、碱法及“CO2 +O2”中性浸出工艺中堵塞现象的成因与影响机制,揭示了黏土矿物通过膨胀、离子置换以及非黏土矿物黏土化等物理化学作用导致孔隙堵塞的关键过程,阐明了黄铁矿氧化产生的硫酸根与铁离子通过矿物沉淀、胶体吸附等途径引发的渗透性下降问题。针对上述堵塞机制,现有解堵技术主要采用加入抑制剂阻断黄铁矿氧化、加入螯合剂生成铁系沉淀物及采用抑膨剂调控黏土矿物膨胀等策略,但仍存在靶向性与环境兼容性不足等问题。未来研究需聚焦黏土-黄铁矿协同作用机理解析、智能解堵材料开发及生态风险评估体系构建,以推动绿色高效解堵技术的创新,为中国铀矿大基地建设与核能可持续发展提供理论支撑与技术保障。

地浸采铀  /  堵塞机制  /  黏土矿物  /  黄铁矿  /  解堵

In-situ leaching (ISL) of uranium, a core technology in China's uranium mining, faces significant challenges due to pore blockage caused by clay minerals and pyrite, which severely restricts leaching efficiency and production capacity. This paper systematically reviews the causes and mechanisms of blocking phenomena in acid leaching, alkaline leaching, and "CO2 + O2" neutral leaching processes. It reveals that clay minerals induce pore blockage through physicochemical interactions such as swelling, ion exchange, and argillization of non-clay minerals, while pyrite oxidation generates sulfate and iron ions, leading to permeability reduction via mineral precipitation and colloidal adsorption. Current unblocking technologies primarily employ inhibitors to suppress pyrite oxidation, chelating agents to immobilize iron-containing precipitates, and swelling suppressants to mitigate clay mineral expansion. However, challenges remain, including lack of specificity, limited environmental compatibility, and insufficient long-term stability. Future research should focus on elucidating the synergistic mechanisms of clay-pyrite interactions, developing intelligent unblocking materials with targeted functionality, and establishing ecological risk assessment frameworks. These advancements aim to drive innovation in green and efficient unblocking technologies, providing theoretical and technical support for China's large-scale uranium base construction and sustainable nuclear energy development.

in-situ leaching of uranium (ISL)  /  blocking mechanism  /  clay minerals  /  pyrite  /  clogging mitigation
赵学瑞, 刘振中, 李春光, 许影, 段先哲, 阙为民, 唐振平. 黏土矿和黄铁矿诱发地浸采铀堵塞的研究进展. 铀矿冶, 2026 , 45 (2) : 1 -11 . DOI: 10.13426/j.cnki.yky.2025.09.06
Xuerui ZHAO, Zhenzhong LIU, Chunguang LI, Ying XU, Xianzhe DUAN, Weimin QUE, Zhenping TANG. Research Progress on the Blockage of In-situ Leaching Uranium Induced by Clay Minerals and Pyrite[J]. Uranium Mining and Metallurgy, 2026 , 45 (2) : 1 -11 . DOI: 10.13426/j.cnki.yky.2025.09.06
  • 国家自然科学基金(U2341265)
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doi: 10.13426/j.cnki.yky.2025.09.06
  • 接收时间:2025-09-07
  • 首发时间:2026-09-28
  • 出版时间:2026-05-20
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出版历史
  • 收稿日期:2025-09-07
  • 修回日期:2025-10-24
基金
国家自然科学基金(U2341265)
作者信息
    1.南华大学 资源环境与安全工程学院,湖南 衡阳 421001
    2.南华大学 放射性废物处理处置与数学模型研发中心,湖南 衡阳 421001
    3.核工业北京化工冶金研究院,北京 101149

通讯作者:

刘振中
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https://castjournals.cast.org.cn/joweb/yky/CN/10.13426/j.cnki.yky.2025.09.06
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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