Article(id=1319263338945692109, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319263322806014330, articleNumber=null, orderNo=null, doi=10.13647/j.cnki.btgkj.2018.01.023, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1507737600000, receivedDateStr=2017-10-12, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1792466490732, onlineDateStr=2026-10-20, pubDate=1519488000000, pubDateStr=2018-02-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792466490732, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792466490732, creator=13701087609, updateTime=1792466490732, updator=13701087609, issue=Issue{id=1319263322806014330, tenantId=1146029695717560320, journalId=1185652524569653253, year='2018', volume='44', issue='1', pageStart='1', pageEnd='98', issueExtLink='null', onlineDate='null', pubDate='1519488000000', pubDateStr='2018-02-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792466486884, creator='13701087609', updateTime=1792467566463, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319267850951438726, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319263322806014330, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319267850955633031, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319263322806014330, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=72, endPage=74, ext={EN=ArticleExt(id=1319263339159601614, articleId=1319263338945692109, tenantId=1146029695717560320, journalId=1185652524569653253, language=EN, title=Thermodynamic Analysis of Yttrium Zinc Alloy Prepared by Liquid Cathode Molten Salt Electrolysis, columnId=1319263323493880187, journalTitle=Science & Technology of Baotou Steel, columnName=Product Development and Technology, runingTitle=null, highlight=null, articleAbstract=

In the paper, thermodynamic calculation of yttrium zinc alloy prepared by electrolytic oxide in fluoride molten salt system is carried out. The decomposition voltage of Y2O3 + 3C = 2Y + 3CO is 1.4 V at 1 027 ℃; through the phase diagram analysis of LiF-YF3 and Y-Zn two element system, it is known that electrolyte of (25%~100%) LiF-(75%~0%) YF3(mass fraction) is molten state at 1 027 ℃, yttrium zinc alloy with the 20%~30% (mass fraction) zinc content is molten state; The analysis of alloy density shows that the density of yttrium zinc alloy>4.469 g/cm3, which is larger than the density of electrolyte.

, authors=Ya-qiao YU1, Yu-bao LIU1, Guo-hua CHEN1, Xiao-ming YUAN2, Ri-zeng GAO1, Wen-can ZHANG1, authorsList=Ya-qiao YU, Yu-bao LIU, Guo-hua CHEN, Xiao-ming YUAN, Ri-zeng GAO, Wen-can ZHANG, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319263339386094031, articleId=1319263338945692109, tenantId=1146029695717560320, journalId=1185652524569653253, language=CN, title=液态阴极熔盐电解法制备钇锌合金热力学分析, columnId=1319263323665846653, journalTitle=包钢科技, columnName=产品研发与工艺技术, runingTitle=null, highlight=null, articleAbstract=

文章对氟化物熔盐体系电解氧化物制取钇锌合金进行了有关热力学计算,得到1 027 ℃下Y2O3 + 3C=2Y + 3CO分解电压为1.4 V;通过对LiF-YF3、Y-Zn二元体系相图分析,可知在1 027 ℃下(25%~100%)LiF-(75%~0%)YF3(质量分数)电解质为熔融状态,锌含量在20%~30%(质量分数)的钇锌合金为熔融状态;对合金密度分析结果表明:钇锌合金密度>4.469 g/cm3,大于电解质密度。

, authors=于雅樵1, 刘玉宝1, 陈国华1, 袁晓鸣2, 高日增1, 张文灿1, authorsList=于雅樵, 刘玉宝, 陈国华, 袁晓鸣, 高日增, 张文灿, authorCompany=null, correspAuthors=null, authorNote=

于雅樵(1958-),男,内蒙古包头市人,高级工程师,现从事稀土合金制备相关工作。

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于雅樵(1958-),男,内蒙古包头市人,高级工程师,现从事稀土合金制备相关工作。

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于雅樵(1958-),男,内蒙古包头市人,高级工程师,现从事稀土合金制备相关工作。

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液态阴极熔盐电解法制备钇锌合金热力学分析
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于雅樵 1 , 刘玉宝 1 , 陈国华 1 , 袁晓鸣 2 , 高日增 1 , 张文灿 1
包钢科技 | 产品研发与工艺技术 2018,44(1): 72-74
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包钢科技 |产品研发与工艺技术 2018 , 44 (1) : 72 -74
液态阴极熔盐电解法制备钇锌合金热力学分析
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于雅樵1, 刘玉宝1, 陈国华1, 袁晓鸣2, 高日增1, 张文灿1
作者信息
  • 1.包钢稀土研究院,内蒙古 包头 014010
  • 2.内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010
作者简介:

于雅樵(1958-),男,内蒙古包头市人,高级工程师,现从事稀土合金制备相关工作。

Thermodynamic Analysis of Yttrium Zinc Alloy Prepared by Liquid Cathode Molten Salt Electrolysis
Ya-qiao YU1, Yu-bao LIU1, Guo-hua CHEN1, Xiao-ming YUAN2, Ri-zeng GAO1, Wen-can ZHANG1
Affiliations
  • 1.Rare Earth Institute of Baotou Steel (Group) Corp., Baotou 014010, Nei Monggol, China
  • 2.Technical Center of Inner Mongolia Steel Union Co. Ltd. of Baotou Steel (Group) Corp., Baotou 014010, Nei Monggol, China
出版时间: 2018-02-25 doi: 10.13647/j.cnki.btgkj.2018.01.023
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文章对氟化物熔盐体系电解氧化物制取钇锌合金进行了有关热力学计算,得到1 027 ℃下Y2O3 + 3C=2Y + 3CO分解电压为1.4 V;通过对LiF-YF3、Y-Zn二元体系相图分析,可知在1 027 ℃下(25%~100%)LiF-(75%~0%)YF3(质量分数)电解质为熔融状态,锌含量在20%~30%(质量分数)的钇锌合金为熔融状态;对合金密度分析结果表明:钇锌合金密度>4.469 g/cm3,大于电解质密度。

钇锌合金  /  氟化物  /  熔盐电解  /  热力学

In the paper, thermodynamic calculation of yttrium zinc alloy prepared by electrolytic oxide in fluoride molten salt system is carried out. The decomposition voltage of Y2O3 + 3C = 2Y + 3CO is 1.4 V at 1 027 ℃; through the phase diagram analysis of LiF-YF3 and Y-Zn two element system, it is known that electrolyte of (25%~100%) LiF-(75%~0%) YF3(mass fraction) is molten state at 1 027 ℃, yttrium zinc alloy with the 20%~30% (mass fraction) zinc content is molten state; The analysis of alloy density shows that the density of yttrium zinc alloy>4.469 g/cm3, which is larger than the density of electrolyte.

yttrium zinc alloy  /  fluoride  /  molten salt electrolysis  /  thermodynamic
于雅樵, 刘玉宝, 陈国华, 袁晓鸣, 高日增, 张文灿. 液态阴极熔盐电解法制备钇锌合金热力学分析. 包钢科技, 2018 , 44 (1) : 72 -74 . DOI: 10.13647/j.cnki.btgkj.2018.01.023
Ya-qiao YU, Yu-bao LIU, Guo-hua CHEN, Xiao-ming YUAN, Ri-zeng GAO, Wen-can ZHANG. Thermodynamic Analysis of Yttrium Zinc Alloy Prepared by Liquid Cathode Molten Salt Electrolysis[J]. Science & Technology of Baotou Steel, 2018 , 44 (1) : 72 -74 . DOI: 10.13647/j.cnki.btgkj.2018.01.023

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doi: 10.13647/j.cnki.btgkj.2018.01.023
  • 接收时间:2017-10-12
  • 首发时间:2026-10-20
  • 出版时间:2018-02-25
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  • 收稿日期:2017-10-12
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    1.包钢稀土研究院,内蒙古 包头 014010
    2.内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010
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2种不同金属材料的力学参数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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