Article(id=1319265701186093161, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319265642189009808, articleNumber=null, orderNo=null, doi=10.13647/j.cnki.btgkj.2017.06.022, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1482854400000, receivedDateStr=2016-12-28, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1792467053934, onlineDateStr=2026-10-20, pubDate=1514131200000, pubDateStr=2017-12-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792467053934, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792467053934, creator=13701087609, updateTime=1792467053934, updator=13701087609, issue=Issue{id=1319265642189009808, tenantId=1146029695717560320, journalId=1185652524569653253, year='2017', volume='43', issue='6', pageStart='1', pageEnd='98', issueExtLink='null', onlineDate='null', pubDate='1514131200000', pubDateStr='2017-12-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792467039868, creator='13701087609', updateTime=1792467450245, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319267363489427783, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319265642189009808, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319267363489427784, tenantId=1146029695717560320, journalId=1185652524569653253, issueId=1319265642189009808, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=64, endPage=68, ext={EN=ArticleExt(id=1319265702800900202, articleId=1319265701186093161, tenantId=1146029695717560320, journalId=1185652524569653253, language=EN, title=Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method, columnId=1187340471245357385, journalTitle=Science & Technology of Baotou Steel, columnName=Quality of Variety and Experiment and Research, runingTitle=null, highlight=null, articleAbstract=

The total amount of rare earth in mixed rare earth chloride solution [RECl3(L)] is determined by EDTA titration and the effects of glass metering instruments, analytical reagents, sample homogeneity and non-rare earth metal ions on the measurement results are studied. The results show that: Glass metering instruments have the greater impact on the measurement results, especially the error accumulation effect of metering instruments, and errors of total rare earth correction (within the maximum allowable calibration error) can reach 3.66 g/L; the effect of aluminum and iron ions on the measurement results can be eliminated by adding masking agents; the zinc ion concentration is small and the effect on the results can be negligible. In the daily analysis process, pay attention to analyze the quality and correct use of reagents, ensuring the homogeneity of samples, reducing the analysis error, and improve the accuracy of analysis results.

, authors=Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU, authorsList=Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319265704558313579, articleId=1319265701186093161, tenantId=1146029695717560320, journalId=1185652524569653253, language=CN, title=EDTA法测定RECl3(L)稀土总量影响因素分析, columnId=1185887584472417142, journalTitle=包钢科技, columnName=品种质量与试验研究, runingTitle=null, highlight=null, articleAbstract=

采用EDTA滴定法测定混合氯化稀土溶液[RECl3(L)]稀土总量,研究了玻璃计量器具、分析试剂、样品的均匀性以及非稀土金属离子等对测定结果的影响。研究结果表明:玻璃计量器具对测定结果影响较大,特别是计量器具的误差累积效应,稀土总量修正(最大允许校准误差内)误差达3.66 g/L;铝、铁离子对测定结果的影响可通过加入掩蔽剂消除,锌离子浓度小,对结果的影响可忽略,在日常分析过程中,注意分析试剂的质量和正确使用,保证样品的均一性,减少分析误差,提高分析结果的准确度。

, authors=都业俭, 张桂梅, 薛建萍, 陈强, 王鸿宇, 郭建鹏, 孙二凤, 吴粉连, authorsList=都业俭, 张桂梅, 薛建萍, 陈强, 王鸿宇, 郭建鹏, 孙二凤, 吴粉连, authorCompany=null, correspAuthors=null, authorNote=

都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

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都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

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都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

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EDTA法测定RECl3(L)稀土总量影响因素分析
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都业俭 , 张桂梅 , 薛建萍 , 陈强 , 王鸿宇 , 郭建鹏 , 孙二凤 , 吴粉连
包钢科技 | 品种质量与试验研究 2017,43(6): 64-68
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包钢科技 |品种质量与试验研究 2017 , 43 (6) : 64 -68
EDTA法测定RECl3(L)稀土总量影响因素分析
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都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

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都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

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都业俭, 张桂梅, 薛建萍, 陈强, 王鸿宇, 郭建鹏, 孙二凤, 吴粉连
作者信息
  • 中国北方稀土(集团)高科技股份有限公司冶炼分公司(华美公司),内蒙古 包头 014010
作者简介:

都业俭(1977-),男,蒙古族,辽宁省庄河市人,硕士,工程师,现从事选矿、稀土分析研究工作。

Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method
Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU
Affiliations
  • Smelting Branch Co. of Hi-tech Co. Ltd. of China Northern Rare Earth (Group) Corp. (Huamei Co.), Baotou 014010, Nei Monggol, China
出版时间: 2017-12-25 doi: 10.13647/j.cnki.btgkj.2017.06.022
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采用EDTA滴定法测定混合氯化稀土溶液[RECl3(L)]稀土总量,研究了玻璃计量器具、分析试剂、样品的均匀性以及非稀土金属离子等对测定结果的影响。研究结果表明:玻璃计量器具对测定结果影响较大,特别是计量器具的误差累积效应,稀土总量修正(最大允许校准误差内)误差达3.66 g/L;铝、铁离子对测定结果的影响可通过加入掩蔽剂消除,锌离子浓度小,对结果的影响可忽略,在日常分析过程中,注意分析试剂的质量和正确使用,保证样品的均一性,减少分析误差,提高分析结果的准确度。

混合氯化稀土溶液  /  EDTA滴定法  /  计量器具  /  非稀土金属离子  /  误差累积效应

The total amount of rare earth in mixed rare earth chloride solution [RECl3(L)] is determined by EDTA titration and the effects of glass metering instruments, analytical reagents, sample homogeneity and non-rare earth metal ions on the measurement results are studied. The results show that: Glass metering instruments have the greater impact on the measurement results, especially the error accumulation effect of metering instruments, and errors of total rare earth correction (within the maximum allowable calibration error) can reach 3.66 g/L; the effect of aluminum and iron ions on the measurement results can be eliminated by adding masking agents; the zinc ion concentration is small and the effect on the results can be negligible. In the daily analysis process, pay attention to analyze the quality and correct use of reagents, ensuring the homogeneity of samples, reducing the analysis error, and improve the accuracy of analysis results.

mixed rare earth chloride solution  /  EDTA titration  /  metering instruments  /  non-rare earth metal ions  /  error accumulation effect
都业俭, 张桂梅, 薛建萍, 陈强, 王鸿宇, 郭建鹏, 孙二凤, 吴粉连. EDTA法测定RECl3(L)稀土总量影响因素分析. 包钢科技, 2017 , 43 (6) : 64 -68 . DOI: 10.13647/j.cnki.btgkj.2017.06.022
Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU. Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method[J]. Science & Technology of Baotou Steel, 2017 , 43 (6) : 64 -68 . DOI: 10.13647/j.cnki.btgkj.2017.06.022

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doi: 10.13647/j.cnki.btgkj.2017.06.022
  • 接收时间:2016-12-28
  • 首发时间:2026-10-20
  • 出版时间:2017-12-25
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  • 收稿日期:2016-12-28
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    中国北方稀土(集团)高科技股份有限公司冶炼分公司(华美公司),内蒙古 包头 014010
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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