Article(id=1307086156609384630, tenantId=1146029695717560320, journalId=1306274195778404443, issueId=1307086088166732376, articleNumber=null, orderNo=null, doi=10.12401/j.nwg.2025057, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1741622400000, receivedDateStr=2025-03-11, revisedDate=1749398400000, revisedDateStr=2025-06-09, acceptedDate=1749571200000, acceptedDateStr=2025-06-11, onlineDate=1789563224222, onlineDateStr=2026-09-16, pubDate=1787155200000, pubDateStr=2026-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789563224222, onlineIssueDateStr=2026-09-16, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789563224222, creator=13701087609, updateTime=1789563224222, updator=13701087609, issue=Issue{id=1307086088166732376, tenantId=1146029695717560320, journalId=1306274195778404443, year='2026', volume='59', issue='4', pageStart='1', pageEnd='386', issueExtLink='null', onlineDate='null', pubDate='1787155200000', pubDateStr='2026-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1789563207904, creator='13701087609', updateTime=1789616196824, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1307308339885531645, tenantId=1146029695717560320, journalId=1306274195778404443, issueId=1307086088166732376, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1307308339885531646, tenantId=1146029695717560320, journalId=1306274195778404443, issueId=1307086088166732376, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=322, endPage=338, ext={EN=ArticleExt(id=1307086156751990967, articleId=1307086156609384630, tenantId=1146029695717560320, journalId=1306274195778404443, language=EN, title=Geochemical Characteristics and Distribution of Associated Resources in Ordovician Oilfield Water of Tahe Oilfield, Tarim Basin, columnId=null, journalTitle=Northwestern Geology, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The water resources of the Ordovician oilfield in the Tarim Basin's Tahe Oilfield are characterized by a high concentration of potassium, lithium, and other trace elements with significant economic value. These resources represent an important strategic asset in the Tarim Basin, alongside oil and gas resources. In this paper, Ordovician oilfield water samples from the Tahe oilfield were collected and analyzed to study its geochemical characteristics and its associated resource distribution pattern. The results demonstrate that the primary cations present in the Ordovician oilfield water of the Tahe Oilfield are Na+, Ca2+, K+, and Mg2+, while the primary anions are Cl−, SO42−, HCO3−, and NO3−. The mineralization of the oilfield water ranges from 140 to 260 g/L, with an average value of 216.56 g/L, indicating a medium level of mineralization. The oilfield water can be classified as a CaCl2 type. The characteristic coefficients indicate that the oilfield water undergoes alternating cation adsorption and robust water-rock interactions. It is a solution-filtered oilfield water, exhibiting complete reduction, optimal reservoir confinement, and a notable degree of metamorphism. The ions present in the oilfield water are predominantly derived from rock salt, gypsum, and crumbly clay minerals. The useful components, including K+, Li+, Br−, and Sr2+, exist in oilfield water can meet the industrial indicators of comprehensive utilization: the K+ content ranging from 556 to 2740 mg/L with an average value of 1781.19 mg/L; the Li+ content varying from 2.9 to 18.5 mg/L with an average concentration of 11.16 mg/L; the concentration of Br− ranging from 45 to 323 mg/L with an average concentration of 230.77 mg/L; The concentration of Sr2+ ranging from 341 to 605 mg/L with an average of 473.31 mg/L. Conducting research on oilfield water that coexists with oil and gas resources, and comprehensively developing and utilizing the associated resources, is of significant importance for enhancing the resource value of oil and gas fields.

, authors=Lidan REN1, Feng GENG1, Qiang HAN1, Tongcheng SUN1, Jizhong SHI2, *, Ting JIANG2, Xiaoming SHAO1, Wei LI2, Yan FAN2, Zhongyu LI2, authorsList=Lidan REN, Feng GENG, Qiang HAN, Tongcheng SUN, Jizhong SHI, Ting JIANG, Xiaoming SHAO, Wei LI, Yan FAN, Zhongyu LI, authorCompany=null, correspAuthors=Jizhong SHI, authorNote=null, correspAuthorsNote=null, copyrightStatement=Copyright © 2026 Northwestern Geology. All rights reserved., copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1307086160614944979, articleId=1307086156609384630, tenantId=1146029695717560320, journalId=1306274195778404443, language=CN, title=塔里木盆地塔河油田奥陶系油田水地球化学特征及其伴生资源分布特征, columnId=1307047819974570720, journalTitle=西北地质, columnName=非主题, runingTitle=null, highlight=null, articleAbstract=

塔里木盆地塔河油田奥陶系赋存有丰富的油田水,因其富含较高经济价值的钾、锂等微量元素,是塔里木盆地除油气资源之外的又一种重要的战略资源。笔者通过采集和分析塔河油田奥陶系油田水样品,研究其地球化学特征及其伴生资源分布特征。结果表明:塔河油田奥陶系油田水主要阳离子为Na+、Ca2+、K+和Mg2+,主要阴离子为Cl−、SO42−、HCO3−和NO3−;矿化度介于140~260 g/L,平均值为216.56 g/L,属于中等矿化度;油田水类型为CaCl2型。特征系数显示油田水经历了阳离子交替吸附和强烈的水岩相互作用,为溶滤油田水,还原彻底、油藏封闭性好、变质程度较高,油田水中的离子主要来源于岩盐、石膏和碎屑黏土矿物等。油田水中富含的K+、Li+、Br−、Sr2+等有用组分能达到综合利用的工业指标,K+含量为556~2740 mg/L,平均值为1781.19 mg/L;Li+含量为2.9~18.5 mg/L,平均值为11.16 mg/L;Br−含量为45~323 mg/L,平均值为230.77 mg/L;Sr2+含量为341~605 mg/L,平均值为473.31 mg/L。开展与油气资源共生的油田水研究,对其中的伴生资源进行综合开发利用,对拓展油气田的资源价值具有重要意义。

, authors=任丽丹1, 耿锋1, 韩强1, 孙同成1, 史冀忠2, *, 姜亭2, 邵小明1, 李渭2, 范焱2, 李忠煜2, authorsList=任丽丹, 耿锋, 韩强, 孙同成, 史冀忠, 姜亭, 邵小明, 李渭, 范焱, 李忠煜, authorCompany=null, correspAuthors=史冀忠, authorNote=

任丽丹(1986−),女,副研究员,主要从事油气勘探规划、地震综合解释等方面的工作。E−mail:

, correspAuthorsNote=
史冀忠(1983−),男,正高级工程师,主要从事沉积学及油气基础地质调查研究。E−mail:。
, copyrightStatement=版权所有©《西北地质》编辑部 2026, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=qjy4KSEhC2G+yIgcv4GbxQ==, magXml=Y8VNeVZ2BkSdRkqu9b0mcg==, pdfUrl=null, pdf=BmkfJiUGYnVUVXyF5KTChQ==, pdfFileSize=2148506, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=myaLUI+BBET6eWhxtEtBZQ==, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=nr/IyNy+UdwTwNqmrLL1BA==, mapNumber=null, fund=null)}, authors=[Author(id=1307086161055346907, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=252225464@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1307086161135038685, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, authorId=1307086161055346907, language=EN, stringName=Lidan REN, firstName=Lidan, middleName=null, lastName=REN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1Research Institute of Petroleum Exploration and Production, Northwest Oilfield Company, SINOPEC, Urumqi 830011, Xinjiang, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1307086161214730462, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, authorId=1307086161055346907, language=CN, stringName=任丽丹, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1中国石油化工股份有限公司西北油田分公司勘探开发研究院,新疆 乌鲁木齐 830011, bio={"content":"

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任丽丹(1986−),女,副研究员,主要从事油气勘探规划、地震综合解释等方面的工作。E−mail:

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figs=[ArticleFig(id=1307086165727801625, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.1, caption=Tectonic units of Tarim Basin and location of study area, figureFileSmall=D3soxVINSwk/a617rfEvDA==, figureFileBig=myaLUI+BBET6eWhxtEtBZQ==, tableContent=null), ArticleFig(id=1307086165790716186, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图1, caption=塔里木盆地构造单元划分及研究区位置, figureFileSmall=D3soxVINSwk/a617rfEvDA==, figureFileBig=myaLUI+BBET6eWhxtEtBZQ==, tableContent=null), ArticleFig(id=1307086165950099739, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.2, caption=Sampling well distribution map of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=GSpCibNa8N2yH6J9sBZUFg==, figureFileBig=OfPnxCo0ycVqzGJ97IGclg==, tableContent=null), ArticleFig(id=1307086166013014300, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图2, caption=塔河油田奥陶系油田水采样井分布图, figureFileSmall=GSpCibNa8N2yH6J9sBZUFg==, figureFileBig=OfPnxCo0ycVqzGJ97IGclg==, tableContent=null), ArticleFig(id=1307086166092706077, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.3, caption=TDS distribution frequency diagram of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=kMbT/Nfle7QP4sXe0FAZbg==, figureFileBig=n++NsJ0HPVurRWx8xRS8pQ==, tableContent=null), ArticleFig(id=1307086166155620638, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图3, caption=塔河油田奥陶系油田水矿化度分布频率图, figureFileSmall=kMbT/Nfle7QP4sXe0FAZbg==, figureFileBig=n++NsJ0HPVurRWx8xRS8pQ==, tableContent=null), ArticleFig(id=1307086166222729503, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.4, caption=Relationship between TDS and Cl−, Na++Ca2+ of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=QDq48xQbyf4SJ06vWA2jbg==, figureFileBig=xQP1EXSyI0Tflf4XsHIsyQ==, tableContent=null), ArticleFig(id=1307086166289838368, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图4, caption=塔河油田奥陶系油田水矿化度与Cl−和Na++Ca2+相关性, figureFileSmall=QDq48xQbyf4SJ06vWA2jbg==, figureFileBig=xQP1EXSyI0Tflf4XsHIsyQ==, tableContent=null), ArticleFig(id=1307086166352752929, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.5, caption=Relationship between TDS and depth of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=WghKRAcbJzOO0us4MIqhAA==, figureFileBig=A4IQ7TMbY/Br+RvAcSBH9A==, tableContent=null), ArticleFig(id=1307086166424056098, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图5, caption=塔河油田奥陶系油田水矿化度与深度关系, figureFileSmall=WghKRAcbJzOO0us4MIqhAA==, figureFileBig=A4IQ7TMbY/Br+RvAcSBH9A==, tableContent=null), ArticleFig(id=1307086166491164963, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.6, caption=Relationship between TDS and K+、Li+、B3+、Br−、Rb+、Sr2+ content of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=IPXk8ul+IGht2rkEPYt1sg==, figureFileBig=1K3uKqislZzUnIa2pu8SqA==, tableContent=null), ArticleFig(id=1307086166558273828, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图6, caption=塔河油田奥陶系油田水矿化度与K+、Li+、B3+、Br−、Rb+、Sr2+含量关系, figureFileSmall=IPXk8ul+IGht2rkEPYt1sg==, figureFileBig=1K3uKqislZzUnIa2pu8SqA==, tableContent=null), ArticleFig(id=1307086166637965605, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.7, caption=Characteristic coefficient of Ordovician oilfield water in Tahe Oilfield, figureFileSmall=1ugnLAoKXWIPwTo/60aSrA==, figureFileBig=CDpJwz4Crc70Tnw+GRLKnA==, tableContent=null), ArticleFig(id=1307086166709268774, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图7, caption=塔河油田奥陶系油田水特征系数判别图, figureFileSmall=1ugnLAoKXWIPwTo/60aSrA==, figureFileBig=CDpJwz4Crc70Tnw+GRLKnA==, tableContent=null), ArticleFig(id=1307086166780571943, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.8, caption=Distribution frequency of water-associated resources in Ordovician oilfield water of Tahe Oilfield, figureFileSmall=vIjiswwRmoofjcQ131YBfQ==, figureFileBig=/LfNjI7n2P4YaIgVaLZPjA==, tableContent=null), ArticleFig(id=1307086166868652328, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图8, caption=塔河油田奥陶系油田水伴生资源含量分布频率图, figureFileSmall=vIjiswwRmoofjcQ131YBfQ==, figureFileBig=/LfNjI7n2P4YaIgVaLZPjA==, tableContent=null), ArticleFig(id=1307086166944149801, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.9, caption=Contour diagram of potassium content(mg/L)in Ordovician oilfield water of Tahe Oilfield, figureFileSmall=DaQWWZ7Tjxdkzgr+7UdELQ==, figureFileBig=hge8wx+smat52bXFElXbsw==, tableContent=null), ArticleFig(id=1307086167019647274, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图9, caption=塔河油田奥陶系油田水钾含量(mg/L)等值线图, figureFileSmall=DaQWWZ7Tjxdkzgr+7UdELQ==, figureFileBig=hge8wx+smat52bXFElXbsw==, tableContent=null), ArticleFig(id=1307086167095144747, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.10, caption=Contour diagram of lithium content(mg/L)in Ordovician oilfield water of Tahe Oilfield, figureFileSmall=PzmJbplwkk8TAYc0tLLszQ==, figureFileBig=XO3s/4qedy96Y1xJpVGBXA==, tableContent=null), ArticleFig(id=1307086167179030828, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图10, caption=塔河油田奥陶系油田水锂含量(mg/L)等值线图, figureFileSmall=PzmJbplwkk8TAYc0tLLszQ==, figureFileBig=XO3s/4qedy96Y1xJpVGBXA==, tableContent=null), ArticleFig(id=1307086167254528301, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.11, caption=Contour diagram of bromine content (mg/L) in Ordovician oilfield water of Tahe Oilfield, figureFileSmall=lUuICpGt4JMhLzM+4G+4RQ==, figureFileBig=0WF+AqnwmOez83tJpxj0OA==, tableContent=null), ArticleFig(id=1307086167317442862, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图11, caption=塔河油田奥陶系油田水溴含量(mg/L)等值线图, figureFileSmall=lUuICpGt4JMhLzM+4G+4RQ==, figureFileBig=0WF+AqnwmOez83tJpxj0OA==, tableContent=null), ArticleFig(id=1307086168986775855, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Fig.12, caption=Contour diagram of strontium content (mg/L) in Ordovician oilfield water of Tahe Oilfield, figureFileSmall=/u7mKqrQypRYlCL/bh1lmw==, figureFileBig=hr6llPrincQK9t5f4IPouQ==, tableContent=null), ArticleFig(id=1307086169129382192, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=图12, caption=塔河油田奥陶系油田水锶含量(mg/L)等值线图, figureFileSmall=/u7mKqrQypRYlCL/bh1lmw==, figureFileBig=hr6llPrincQK9t5f4IPouQ==, tableContent=null), ArticleFig(id=1307086169204879665, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Tab.1, caption=

Chemical composition of Ordovician oilfield water in Tahe Oilfield

, figureFileSmall=null, figureFileBig=null, tableContent=
样品
编号
生产井段
(m)
产水量矿化度Na+Ca2+K+Mg2+Cl−SO42−HCO3−NO3−Li+B3+Br−Sr2+Rb+I−pH值
t/dg/Lg/Lg/Lmg/Lmg/Lg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L
TH015494.0~5913.8/21065.110.81400806133431145<0.025.652.32124102.10<0.026.0
TH025600.2~5694.041.723069.213.91550753144259159<0.025.545.62214372.05<0.026.0
TH035815.2~5890.068.721066.69.61640587134371151<0.026.251.12183712.29<0.026.0
TH045609.0~5685.037.123068.412.31 960959143223188<0.026.549.22414292.09<0.026.0
TH055488.5~5560.032.022065.712.21290862138358145<0.025.454.62074441.86<0.025.5
TH065390.0~5949.1/22066.111.21170892136304174<0.025.148.31964191.78<0.026.0
TH075435.7~5520.4282.722066.211.61420953142242159<0.026.253.32274491.91<0.026.0
TH085491.0~5510.663.522067.211.41400927139234172<0.026.261.62214491.98<0.025.5
TH095468.6~5667.381.322066.311.01660982136371188<0.0211.379.32954522.02<0.025.5
TH105481.0~5704.049.121065.710.91540981138189126<0.027.089.12454362.12<0.026.0
TH115372.0~5451.044.821060.711.01320921131485232<0.024.950.81944121.62<0.026.0
TH125444.0~5506.0/21064.611.417001010137216197<0.027.487.92594492.077.215.5
TH135337.0~5430.0/21064.411.41440103013623220311.37.288.12534831.52<0.026.0
TH145420.0~5472.024.421065.311.514701040137202159<0.026.476.12244561.97<0.026.0
TH155464.0~5614.015.921061.811.71680104013231223821.87.249.52174771.84<0.026.0
TH165479.0~5498.312.722065.111.21720105013328620922.411.244.02234811.89<0.026.0
TH175526.4~5534.129.523065.011.31 870106013928217422.112.653.22395582.11<0.026.0
TH185550.0~5588.321.922066.811.21760106013631917219.47.145.22284921.66<0.026.0
TH195452.9~5491.112.722063.09.7165073713233119721.710.853.32184722.00<0.025.5
TH205476.2~5595.118.322066.511.21610110013828617419.17.361.42234891.99<0.025.5
TH215512.0~5720.021.422063.810.81940106013525723825.712.749.62365442.09<0.026.0
TH225494.8~5546.823.623066.311.81830111013731415120.512.853.42365162.13<0.025.5
TH235469.5~5577.158.323065.511.21870105013926518620.012.957.82405352.06<0.026.0
TH245529.0~5600.0/24065.811.21970110014727817715.012.262.72605452.06<0.026.0
TH255506.0~5580.018.523067.911.21930114013925518018.013.044.12345342.18<0.026.0
TH265527.0~5587.034.322063.511.31480107013327820321.911.924.62235151.81<0.026.0
TH275533.0~5627.5110.923066.011.618201100141317162220.013.057.82395622.24<0.026.0
TH285710.7~5998.915.022061.411.31470105013328413915.610.947.72155012.04<0.025.5
TH295173.0~6161.054.122062.99.41790101013114422624.911.233.31974762.31<0.025.5
TH305811.9~5891.026.923063.710.8184099813935021439.612.246.92394962.16<0.025.5
TH315862.4~5883.9194.123069.710.91780115014330913923.811.146.72154882.15<0.025.5
TH326047.9~6073.555.124069.411.22020105014832020931.412.792.52616052.52<0.025.5
TH335619.9~5693.053.119053.69.31450102011820824418.110.638.41924481.82<0.025.5
TH346104.2~6207.096.520058.29.5159010401219820326.313.741.52105042.32<0.025.5
TH355522.0~5545.235.422062.810.418208031323055820.412.247.62155052.44<0.026.0
TH365520.0~5554.8162.824069.511.11970108014629417414.513.147.82555842.44<0.025.5
TH375563.0~5859.658.815045.87.425807859428246<0.0216.2347.02603413.1916.605.5
TH385585.0~6051.6/22063.910.2198092013427820920.411.546.92304611.95<0.026.0
TH395560.0~5645.032.322064.311.12030113013825122026.113.243.92435462.26<0.026.0
TH405601.5~5879.4/23064.711.81880120014120828420.813.522.42634962.02<0.026.0
TH416173.0~6481.141.122066.410.62240937144219209<0.0214.425.52904882.91<0.026.0
TH426098.0~6174.076.520059.28.6161085612121625521.813.352.42014042.31<0.025.7
TH436132.0~6240.027.720059.78.9171096412410020913.113.240.92314542.417.485.5
TH445878.0~6066.0189.524071.412.0263010701541489912.314.273.93235933.387.795.5
TH455823.5~5978.0111.824071.410.4177099214817217413.412.450.32345372.58<0.025.5
TH466529.0~6538.0/22057.116.81180113013729273<0.026.410.31455292.32<0.025.5
TH476475.0~6570.0375.322067.210.4246080714413158<0.0214.721.32964363.16<0.026.0
TH486516.0~6600.08.420059.511.4556154012966317<0.022.925.0454801.1516.606.0
TH496702.3~6807.145.421060.910.6132086813486290<0.0216.020.92374362.26<0.026.0
TH506519.5~6602.031.020059.610.4138087312413530413.515.122.72174332.25<0.026.0
TH516427.9~6915.011.822067.910.42460819136163226<0.0215.228.12484613.17<0.026.0
TH526102.0~6164.031.422069.810.6193093313915213018.614.222.32524432.43<0.026.0
TH536205.0~6780.457.121064.110.1111098713012323211.913.319.22303911.70<0.026.0
TH546862.0~7323.051.215044.07.8171069894429130<0.0215.058.62154212.2633.906.0
TH556903.4~7328.655.614043.85.9190057088392246<0.0218.583.31934482.7744.606.0
TH566847.2~7023.047.718054.98.4254073611337217412.118.476.02145703.5525.306.0
TH576753.0~6840.0179.425071.012.4274095815517911612.812.234.92664194.98<0.025.5
TH586400.4~6681.731.021059.810.6171010501312638611.914.045.32204752.34<0.025.5
TH596172.0~6249.8/25070.911.4219096115218413915.710.620.32634062.86<0.025.5
TH606238.0~6687.073.220059.89.5208088212821117417.813.646.42494922.5112.306.0
TH616544.6~6642.076.125072.911.7228099515318615115.212.426.12664823.31<0.025.5
TH626214.0~6249.054.423067.411.1211097114520714518.811.635.42394153.08<0.025.5
TH636195.4~6333.042.518053.48.2171078811215020323.412.936.52023712.25<0.025.5
TH646265.0~6395.7/26073.012.42380964156193110398.012.343.82694413.48<0.025.5
), ArticleFig(id=1307086169372651826, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=表1, caption=

塔河油田奥陶系油田水化学组分

, figureFileSmall=null, figureFileBig=null, tableContent=
样品
编号
生产井段
(m)
产水量矿化度Na+Ca2+K+Mg2+Cl−SO42−HCO3−NO3−Li+B3+Br−Sr2+Rb+I−pH值
t/dg/Lg/Lg/Lmg/Lmg/Lg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L
TH015494.0~5913.8/21065.110.81400806133431145<0.025.652.32124102.10<0.026.0
TH025600.2~5694.041.723069.213.91550753144259159<0.025.545.62214372.05<0.026.0
TH035815.2~5890.068.721066.69.61640587134371151<0.026.251.12183712.29<0.026.0
TH045609.0~5685.037.123068.412.31 960959143223188<0.026.549.22414292.09<0.026.0
TH055488.5~5560.032.022065.712.21290862138358145<0.025.454.62074441.86<0.025.5
TH065390.0~5949.1/22066.111.21170892136304174<0.025.148.31964191.78<0.026.0
TH075435.7~5520.4282.722066.211.61420953142242159<0.026.253.32274491.91<0.026.0
TH085491.0~5510.663.522067.211.41400927139234172<0.026.261.62214491.98<0.025.5
TH095468.6~5667.381.322066.311.01660982136371188<0.0211.379.32954522.02<0.025.5
TH105481.0~5704.049.121065.710.91540981138189126<0.027.089.12454362.12<0.026.0
TH115372.0~5451.044.821060.711.01320921131485232<0.024.950.81944121.62<0.026.0
TH125444.0~5506.0/21064.611.417001010137216197<0.027.487.92594492.077.215.5
TH135337.0~5430.0/21064.411.41440103013623220311.37.288.12534831.52<0.026.0
TH145420.0~5472.024.421065.311.514701040137202159<0.026.476.12244561.97<0.026.0
TH155464.0~5614.015.921061.811.71680104013231223821.87.249.52174771.84<0.026.0
TH165479.0~5498.312.722065.111.21720105013328620922.411.244.02234811.89<0.026.0
TH175526.4~5534.129.523065.011.31 870106013928217422.112.653.22395582.11<0.026.0
TH185550.0~5588.321.922066.811.21760106013631917219.47.145.22284921.66<0.026.0
TH195452.9~5491.112.722063.09.7165073713233119721.710.853.32184722.00<0.025.5
TH205476.2~5595.118.322066.511.21610110013828617419.17.361.42234891.99<0.025.5
TH215512.0~5720.021.422063.810.81940106013525723825.712.749.62365442.09<0.026.0
TH225494.8~5546.823.623066.311.81830111013731415120.512.853.42365162.13<0.025.5
TH235469.5~5577.158.323065.511.21870105013926518620.012.957.82405352.06<0.026.0
TH245529.0~5600.0/24065.811.21970110014727817715.012.262.72605452.06<0.026.0
TH255506.0~5580.018.523067.911.21930114013925518018.013.044.12345342.18<0.026.0
TH265527.0~5587.034.322063.511.31480107013327820321.911.924.62235151.81<0.026.0
TH275533.0~5627.5110.923066.011.618201100141317162220.013.057.82395622.24<0.026.0
TH285710.7~5998.915.022061.411.31470105013328413915.610.947.72155012.04<0.025.5
TH295173.0~6161.054.122062.99.41790101013114422624.911.233.31974762.31<0.025.5
TH305811.9~5891.026.923063.710.8184099813935021439.612.246.92394962.16<0.025.5
TH315862.4~5883.9194.123069.710.91780115014330913923.811.146.72154882.15<0.025.5
TH326047.9~6073.555.124069.411.22020105014832020931.412.792.52616052.52<0.025.5
TH335619.9~5693.053.119053.69.31450102011820824418.110.638.41924481.82<0.025.5
TH346104.2~6207.096.520058.29.5159010401219820326.313.741.52105042.32<0.025.5
TH355522.0~5545.235.422062.810.418208031323055820.412.247.62155052.44<0.026.0
TH365520.0~5554.8162.824069.511.11970108014629417414.513.147.82555842.44<0.025.5
TH375563.0~5859.658.815045.87.425807859428246<0.0216.2347.02603413.1916.605.5
TH385585.0~6051.6/22063.910.2198092013427820920.411.546.92304611.95<0.026.0
TH395560.0~5645.032.322064.311.12030113013825122026.113.243.92435462.26<0.026.0
TH405601.5~5879.4/23064.711.81880120014120828420.813.522.42634962.02<0.026.0
TH416173.0~6481.141.122066.410.62240937144219209<0.0214.425.52904882.91<0.026.0
TH426098.0~6174.076.520059.28.6161085612121625521.813.352.42014042.31<0.025.7
TH436132.0~6240.027.720059.78.9171096412410020913.113.240.92314542.417.485.5
TH445878.0~6066.0189.524071.412.0263010701541489912.314.273.93235933.387.795.5
TH455823.5~5978.0111.824071.410.4177099214817217413.412.450.32345372.58<0.025.5
TH466529.0~6538.0/22057.116.81180113013729273<0.026.410.31455292.32<0.025.5
TH476475.0~6570.0375.322067.210.4246080714413158<0.0214.721.32964363.16<0.026.0
TH486516.0~6600.08.420059.511.4556154012966317<0.022.925.0454801.1516.606.0
TH496702.3~6807.145.421060.910.6132086813486290<0.0216.020.92374362.26<0.026.0
TH506519.5~6602.031.020059.610.4138087312413530413.515.122.72174332.25<0.026.0
TH516427.9~6915.011.822067.910.42460819136163226<0.0215.228.12484613.17<0.026.0
TH526102.0~6164.031.422069.810.6193093313915213018.614.222.32524432.43<0.026.0
TH536205.0~6780.457.121064.110.1111098713012323211.913.319.22303911.70<0.026.0
TH546862.0~7323.051.215044.07.8171069894429130<0.0215.058.62154212.2633.906.0
TH556903.4~7328.655.614043.85.9190057088392246<0.0218.583.31934482.7744.606.0
TH566847.2~7023.047.718054.98.4254073611337217412.118.476.02145703.5525.306.0
TH576753.0~6840.0179.425071.012.4274095815517911612.812.234.92664194.98<0.025.5
TH586400.4~6681.731.021059.810.6171010501312638611.914.045.32204752.34<0.025.5
TH596172.0~6249.8/25070.911.4219096115218413915.710.620.32634062.86<0.025.5
TH606238.0~6687.073.220059.89.5208088212821117417.813.646.42494922.5112.306.0
TH616544.6~6642.076.125072.911.7228099515318615115.212.426.12664823.31<0.025.5
TH626214.0~6249.054.423067.411.1211097114520714518.811.635.42394153.08<0.025.5
TH636195.4~6333.042.518053.48.2171078811215020323.412.936.52023712.25<0.025.5
TH646265.0~6395.7/26073.012.42380964156193110398.012.343.82694413.48<0.025.5
), ArticleFig(id=1307086169691418931, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Tab.2, caption=

A classification method of oilfield water by Sulin

, figureFileSmall=null, figureFileBig=null, tableContent=
水类型成因系数(质量浓度比)
Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+
大陆水Na2SO4>1<1<0
NaHCO3>1>1<0
海水MgCl2<1<0<1
深层水CaCl2<1<0>1
), ArticleFig(id=1307086170039546164, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=表2, caption=

油田水的苏林分类法

, figureFileSmall=null, figureFileBig=null, tableContent=
水类型成因系数(质量浓度比)
Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+
大陆水Na2SO4>1<1<0
NaHCO3>1>1<0
海水MgCl2<1<0<1
深层水CaCl2<1<0>1
), ArticleFig(id=1307086170119237941, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Tab.3, caption=

Genetic coefficient of Ordovician oilfield water in Tahe Oilfield

, figureFileSmall=null, figureFileBig=null, tableContent=
样品编号Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+样品编号Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+
TH010.49−157.5484.24TH330.45−309.6263.14
TH020.48−288.8099.34TH340.48−644.1060.38
TH030.50−181.67114.82TH350.48−226.8986.18
TH040.48−334.5377.79TH360.48−260.2070.83
TH050.48−201.9683.87TH370.49−1707.1460.89
TH060.49−229.9378.36TH380.48−252.1676.20
TH070.47−313.2279.54TH390.47−293.6365.22
TH080.48−306.8477.45TH400.46−366.8363.58
TH090.49−187.8770.98TH410.46−354.3482.82
TH100.48−382.5473.70TH420.49−286.1172.20
TH110.46−144.9576.33TH430.48−643.0066.70
TH120.47−335.1971.68TH440.46−558.1177.20
TH130.47−308.6269.51TH450.48−445.3577.22
TH140.48−354.9568.94TH460.42−273.6370.71
TH150.47−225.0067.50TH470.47−586.2695.17
TH160.49−237.4164.67TH480.46−104.8345.13
TH170.47−262.4169.81TH490.45−848.0384.22
TH180.49−216.9365.28TH500.48−477.0473.77
TH190.48−208.4693.62TH510.50−417.7983.15
TH200.48−250.0065.00TH520.50−455.2674.17
TH210.47−277.0467.17TH530.49−535.7766.77
TH220.48−225.1663.69TH540.47−115.8571.20
TH230.47−277.3670.00TH550.50−111.9977.02
TH240.45−292.0973.82TH560.49−156.1878.94
TH250.49−278.8262.37TH570.46−469.2787.68
TH260.48−250.0064.95TH580.46−270.7267.81
TH270.47−236.5968.18TH590.47−440.7684.39
TH280.46−252.1168.19TH600.47−323.2277.32
TH290.48−472.9267.43TH610.48−430.6580.50
TH300.46−215.1475.45TH620.46−374.8879.92
TH310.49−237.2263.74TH630.48−390.6774.37
TH320.47−245.6374.86TH640.47−430.0586.10
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塔河油田奥陶系油田水成因系数

, figureFileSmall=null, figureFileBig=null, tableContent=
样品编号Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+样品编号Na+/Cl−(Na+-Cl−)/SO42−(Cl−-Na+)/ Mg2+
TH010.49−157.5484.24TH330.45−309.6263.14
TH020.48−288.8099.34TH340.48−644.1060.38
TH030.50−181.67114.82TH350.48−226.8986.18
TH040.48−334.5377.79TH360.48−260.2070.83
TH050.48−201.9683.87TH370.49−1707.1460.89
TH060.49−229.9378.36TH380.48−252.1676.20
TH070.47−313.2279.54TH390.47−293.6365.22
TH080.48−306.8477.45TH400.46−366.8363.58
TH090.49−187.8770.98TH410.46−354.3482.82
TH100.48−382.5473.70TH420.49−286.1172.20
TH110.46−144.9576.33TH430.48−643.0066.70
TH120.47−335.1971.68TH440.46−558.1177.20
TH130.47−308.6269.51TH450.48−445.3577.22
TH140.48−354.9568.94TH460.42−273.6370.71
TH150.47−225.0067.50TH470.47−586.2695.17
TH160.49−237.4164.67TH480.46−104.8345.13
TH170.47−262.4169.81TH490.45−848.0384.22
TH180.49−216.9365.28TH500.48−477.0473.77
TH190.48−208.4693.62TH510.50−417.7983.15
TH200.48−250.0065.00TH520.50−455.2674.17
TH210.47−277.0467.17TH530.49−535.7766.77
TH220.48−225.1663.69TH540.47−115.8571.20
TH230.47−277.3670.00TH550.50−111.9977.02
TH240.45−292.0973.82TH560.49−156.1878.94
TH250.49−278.8262.37TH570.46−469.2787.68
TH260.48−250.0064.95TH580.46−270.7267.81
TH270.47−236.5968.18TH590.47−440.7684.39
TH280.46−252.1168.19TH600.47−323.2277.32
TH290.48−472.9267.43TH610.48−430.6580.50
TH300.46−215.1475.45TH620.46−374.8879.92
TH310.49−237.2263.74TH630.48−390.6774.37
TH320.47−245.6374.86TH640.47−430.0586.10
), ArticleFig(id=1307086170517696823, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=EN, label=Tab.4, caption=

Characteristic coefficient of Ordovician oilfield water in Tahe Oilfield

, figureFileSmall=null, figureFileBig=null, tableContent=
样品编号钠氯系数溴氯系数脱硫系数钙镁系数钾氯系数硼氯系数
TH010.751.590.068.1310.531.29
TH020.741.530.0311.1910.761.04
TH030.771.630.059.9312.241.25
TH040.741.690.037.7813.711.13
TH050.731.500.058.589.351.30
TH060.751.440.047.618.601.16
TH070.721.600.037.3810.001.23
TH080.751.590.037.4610.071.45
TH090.752.170.056.7912.211.91
TH100.731.780.036.7411.162.12
TH110.711.480.077.2410.081.27
TH120.731.890.036.8412.412.10
TH130.731.860.036.7110.592.12
TH140.741.640.036.7110.731.82
TH150.721.640.046.8212.731.23
TH160.751.680.046.4712.931.08
TH170.721.720.046.4613.451.26
TH180.761.680.046.4112.941.09
TH190.741.650.058.0112.501.32
TH200.741.620.046.1711.671.46
TH210.731.750.046.1814.371.20
TH220.751.720.046.4513.361.28
TH230.731.730.046.4713.451.36
TH240.691.770.036.1713.401.40
TH250.751.680.035.9613.881.04
TH260.741.680.046.4011.130.61
TH270.721.700.046.4012.911.34
TH280.711.620.046.5311.051.18
TH290.741.500.025.6213.660.83
TH300.711.720.056.5613.241.11
TH310.751.500.045.7512.451.07
TH320.721.760.046.4713.652.05
TH330.701.630.035.5412.291.07
TH340.741.740.015.5413.141.12
TH350.731.630.047.8513.791.18
TH360.731.750.046.2313.491.07
TH370.752.780.015.7027.5612.16
TH380.741.720.046.7214.781.15
TH390.721.760.035.9614.711.04
TH400.711.870.035.9613.330.52
TH410.712.010.036.8615.560.58
TH420.751.660.036.1013.311.42
TH430.741.860.015.5713.791.08
TH440.712.100.026.8017.081.57
TH450.741.580.026.3611.961.11
TH460.641.060.049.028.610.25
TH470.722.060.027.8217.080.49
TH480.710.350.094.494.310.64
TH490.701.770.017.419.850.51
TH500.741.750.027.2211.130.60
TH510.771.820.027.7018.090.68
TH520.771.810.026.8913.880.53
TH530.761.770.026.218.540.48
TH540.722.290.086.8018.252.05
TH550.772.200.086.3221.663.11
TH560.751.890.066.9322.482.21
TH570.711.720.027.8517.680.74
TH580.701.680.046.1213.051.13
TH590.721.730.027.1914.410.44
TH600.721.950.036.5116.251.19
TH610.731.740.027.1314.900.56
TH620.721.650.036.9314.550.80
TH630.741.800.026.3315.271.07
TH640.721.720.027.8015.260.92
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塔河油田奥陶系油田水特征系数

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样品编号钠氯系数溴氯系数脱硫系数钙镁系数钾氯系数硼氯系数
TH010.751.590.068.1310.531.29
TH020.741.530.0311.1910.761.04
TH030.771.630.059.9312.241.25
TH040.741.690.037.7813.711.13
TH050.731.500.058.589.351.30
TH060.751.440.047.618.601.16
TH070.721.600.037.3810.001.23
TH080.751.590.037.4610.071.45
TH090.752.170.056.7912.211.91
TH100.731.780.036.7411.162.12
TH110.711.480.077.2410.081.27
TH120.731.890.036.8412.412.10
TH130.731.860.036.7110.592.12
TH140.741.640.036.7110.731.82
TH150.721.640.046.8212.731.23
TH160.751.680.046.4712.931.08
TH170.721.720.046.4613.451.26
TH180.761.680.046.4112.941.09
TH190.741.650.058.0112.501.32
TH200.741.620.046.1711.671.46
TH210.731.750.046.1814.371.20
TH220.751.720.046.4513.361.28
TH230.731.730.046.4713.451.36
TH240.691.770.036.1713.401.40
TH250.751.680.035.9613.881.04
TH260.741.680.046.4011.130.61
TH270.721.700.046.4012.911.34
TH280.711.620.046.5311.051.18
TH290.741.500.025.6213.660.83
TH300.711.720.056.5613.241.11
TH310.751.500.045.7512.451.07
TH320.721.760.046.4713.652.05
TH330.701.630.035.5412.291.07
TH340.741.740.015.5413.141.12
TH350.731.630.047.8513.791.18
TH360.731.750.046.2313.491.07
TH370.752.780.015.7027.5612.16
TH380.741.720.046.7214.781.15
TH390.721.760.035.9614.711.04
TH400.711.870.035.9613.330.52
TH410.712.010.036.8615.560.58
TH420.751.660.036.1013.311.42
TH430.741.860.015.5713.791.08
TH440.712.100.026.8017.081.57
TH450.741.580.026.3611.961.11
TH460.641.060.049.028.610.25
TH470.722.060.027.8217.080.49
TH480.710.350.094.494.310.64
TH490.701.770.017.419.850.51
TH500.741.750.027.2211.130.60
TH510.771.820.027.7018.090.68
TH520.771.810.026.8913.880.53
TH530.761.770.026.218.540.48
TH540.722.290.086.8018.252.05
TH550.772.200.086.3221.663.11
TH560.751.890.066.9322.482.21
TH570.711.720.027.8517.680.74
TH580.701.680.046.1213.051.13
TH590.721.730.027.1914.410.44
TH600.721.950.036.5116.251.19
TH610.731.740.027.1314.900.56
TH620.721.650.036.9314.550.80
TH630.741.800.026.3315.271.07
TH640.721.720.027.8015.260.92
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Index of individual exploitation and comprehensive utilization of oilfield water (mg/L)

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组分K+Li+B3+Br−I−Rb+Sr2+
单独开采310016.4300300302044.2
综合利用10548.26050-60101022.1
塔河油田奥陶系1781.1911.1652.29230.762.702.32473.31
), ArticleFig(id=1307086170983264570, tenantId=1146029695717560320, journalId=1306274195778404443, articleId=1307086156609384630, language=CN, label=表5, caption=

油田水单独开采及综合利用指标(mg/L)

, figureFileSmall=null, figureFileBig=null, tableContent=
组分K+Li+B3+Br−I−Rb+Sr2+
单独开采310016.4300300302044.2
综合利用10548.26050-60101022.1
塔河油田奥陶系1781.1911.1652.29230.762.702.32473.31
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塔里木盆地塔河油田奥陶系油田水地球化学特征及其伴生资源分布特征
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任丽丹 1 , 耿锋 1 , 韩强 1 , 孙同成 1 , 史冀忠 2, * , 姜亭 2 , 邵小明 1 , 李渭 2 , 范焱 2 , 李忠煜 2
西北地质 | 非主题 2026,59(4): 322-338
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西北地质 |非主题 2026 , 59 (4) : 322 -338
塔里木盆地塔河油田奥陶系油田水地球化学特征及其伴生资源分布特征
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任丽丹1 , 耿锋1, 韩强1, 孙同成1, 史冀忠2, * , 姜亭2, 邵小明1, 李渭2, 范焱2, 李忠煜2
作者信息
  • 1中国石油化工股份有限公司西北油田分公司勘探开发研究院,新疆 乌鲁木齐 830011
  • 2中国地质调查局西安地质调查中心(西北地质科技创新中心),陕西 西安 710119
通讯作者:
史冀忠(1983−),男,正高级工程师,主要从事沉积学及油气基础地质调查研究。E−mail:。
作者简介:

任丽丹(1986−),女,副研究员,主要从事油气勘探规划、地震综合解释等方面的工作。E−mail:

Geochemical Characteristics and Distribution of Associated Resources in Ordovician Oilfield Water of Tahe Oilfield, Tarim Basin
Lidan REN1 , Feng GENG1, Qiang HAN1, Tongcheng SUN1, Jizhong SHI2, * , Ting JIANG2, Xiaoming SHAO1, Wei LI2, Yan FAN2, Zhongyu LI2
Affiliations
  • 1Research Institute of Petroleum Exploration and Production, Northwest Oilfield Company, SINOPEC, Urumqi 830011, Xinjiang, China
  • 2Xi’an Center of China Geological Survey(Northwest China Center for Geoscience Innovation), Xi’an 710119, Shaanxi, China
出版时间: 2026-08-20 doi: 10.12401/j.nwg.2025057
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塔里木盆地塔河油田奥陶系赋存有丰富的油田水,因其富含较高经济价值的钾、锂等微量元素,是塔里木盆地除油气资源之外的又一种重要的战略资源。笔者通过采集和分析塔河油田奥陶系油田水样品,研究其地球化学特征及其伴生资源分布特征。结果表明:塔河油田奥陶系油田水主要阳离子为Na+、Ca2+、K+和Mg2+,主要阴离子为Cl−、SO42−、HCO3−和NO3−;矿化度介于140~260 g/L,平均值为216.56 g/L,属于中等矿化度;油田水类型为CaCl2型。特征系数显示油田水经历了阳离子交替吸附和强烈的水岩相互作用,为溶滤油田水,还原彻底、油藏封闭性好、变质程度较高,油田水中的离子主要来源于岩盐、石膏和碎屑黏土矿物等。油田水中富含的K+、Li+、Br−、Sr2+等有用组分能达到综合利用的工业指标,K+含量为556~2740 mg/L,平均值为1781.19 mg/L;Li+含量为2.9~18.5 mg/L,平均值为11.16 mg/L;Br−含量为45~323 mg/L,平均值为230.77 mg/L;Sr2+含量为341~605 mg/L,平均值为473.31 mg/L。开展与油气资源共生的油田水研究,对其中的伴生资源进行综合开发利用,对拓展油气田的资源价值具有重要意义。

塔里木盆地  /  油田水  /  地球化学  /  微量元素  /  锂  /  钾

The water resources of the Ordovician oilfield in the Tarim Basin's Tahe Oilfield are characterized by a high concentration of potassium, lithium, and other trace elements with significant economic value. These resources represent an important strategic asset in the Tarim Basin, alongside oil and gas resources. In this paper, Ordovician oilfield water samples from the Tahe oilfield were collected and analyzed to study its geochemical characteristics and its associated resource distribution pattern. The results demonstrate that the primary cations present in the Ordovician oilfield water of the Tahe Oilfield are Na+, Ca2+, K+, and Mg2+, while the primary anions are Cl−, SO42−, HCO3−, and NO3−. The mineralization of the oilfield water ranges from 140 to 260 g/L, with an average value of 216.56 g/L, indicating a medium level of mineralization. The oilfield water can be classified as a CaCl2 type. The characteristic coefficients indicate that the oilfield water undergoes alternating cation adsorption and robust water-rock interactions. It is a solution-filtered oilfield water, exhibiting complete reduction, optimal reservoir confinement, and a notable degree of metamorphism. The ions present in the oilfield water are predominantly derived from rock salt, gypsum, and crumbly clay minerals. The useful components, including K+, Li+, Br−, and Sr2+, exist in oilfield water can meet the industrial indicators of comprehensive utilization: the K+ content ranging from 556 to 2740 mg/L with an average value of 1781.19 mg/L; the Li+ content varying from 2.9 to 18.5 mg/L with an average concentration of 11.16 mg/L; the concentration of Br− ranging from 45 to 323 mg/L with an average concentration of 230.77 mg/L; The concentration of Sr2+ ranging from 341 to 605 mg/L with an average of 473.31 mg/L. Conducting research on oilfield water that coexists with oil and gas resources, and comprehensively developing and utilizing the associated resources, is of significant importance for enhancing the resource value of oil and gas fields.

Tarim basin  /  oilfield water  /  geochemistry  /  trace element  /  lithium  /  potassium
任丽丹, 耿锋, 韩强, 孙同成, 史冀忠, 姜亭, 邵小明, 李渭, 范焱, 李忠煜. 塔里木盆地塔河油田奥陶系油田水地球化学特征及其伴生资源分布特征. 西北地质, 2026 , 59 (4) : 322 -338 . DOI: 10.12401/j.nwg.2025057
Lidan REN, Feng GENG, Qiang HAN, Tongcheng SUN, Jizhong SHI, Ting JIANG, Xiaoming SHAO, Wei LI, Yan FAN, Zhongyu LI. Geochemical Characteristics and Distribution of Associated Resources in Ordovician Oilfield Water of Tahe Oilfield, Tarim Basin[J]. Northwestern Geology, 2026 , 59 (4) : 322 -338 . DOI: 10.12401/j.nwg.2025057
油田水是指与油、气毗邻伴生,同时具有特殊物理、化学性质的地下水,是油、气藏流体系统的重要组成部分(高锡兴,1994;高娟琴等,2019)。与普通地下水相比,油田水的化学成分相对复杂,具有更高的微量组分含量,尤其油田水中富含的锂、钾等资源,是中国紧缺的矿产资源,对国家能源产业和新兴产业的发展具有重大意义(高娟琴等,2019;牛新生等,2021;王东晖等,2024;李进步等,2024)。
中国油田水资源分布广,主要分布在柴达木盆地、四川盆地、江汉盆地、塔里木盆地等沉积盆地(林耀庭等,1997;付建龙等,2006;穆延宗等,2016;刘雪等,2024)。柴达木盆地西部古近系和新近系油田水中富集K+、Li+、Br−、Rb+、Sr2+等多种有用组分,且普遍达到工业开采品位,其中南翼山油田水中Li+含量均高于200 mg/L(谭红兵等,2007)。四川盆地发现气田水的气藏占开发气藏的84%,主要层位为嘉陵江组和雷口坡组,其中黄金口背斜群中气田水Li+含量最高者达323 mg/L(林耀庭等,2008),伴生有用组分多,尤其是Na+、K+远超工业品位(高娟琴等,2019)。江汉盆地江陵凹陷产出于沙市组及新沟嘴组的油田水 Li+含量可达52~65 mg/L,高于油田水的工业品位,同时含有丰富的Na+、K+等伴生资源(黄华等,2014)。
前人对塔里木盆地油田水的研究主要集中在元素组成(蔡春芳等,1996;张敏等,1998;周晓芬,2000;钱一雄等,2003;刘建伟等,2005)、同位素特征(贾存善等,2007)、平面分布(钱一雄等,2005;张金川等,2007)、成因与演化(蔡春芳等,1997;蔡春芳,2000;蔡立国等,2002;李鹏春等,2007)等方面。塔河油田不同地质时代的油田水成分差异较大,矿化度总体较高,塔河油田奥陶系油田水的可溶物质主要成分与海水一致(刘建伟等,2005)。关于奥陶系油田水的成因,钱一雄等(2003,2005)认为主要受原始海水控制,早期存在大气水淋滤–淋溶作用;贾存善等(2007)认为是古大气降水和原生沉积水的混合水,并以古大气水为主。关于油田水中达到综合利用工业品位的伴生资源未进行综合评价。
笔者通过探讨塔里木盆地塔河油田奥陶系油田水的地球化学特征,进而研究油田水中富含的伴生资源(钾、锂、硼、溴、碘、锶等)的分布特征,开展与油气资源共生的富钾、锂油田水研究,加强油田水中伴生资源的综合开发利用,不仅可以弥补中国钾盐、锂矿的资源短缺,获取显著的社会效益和经济效益,而且对拓展油气田的资源价值具有重要意义。
塔河油田是中国第一大古生界海相油田,位于塔里木盆地北部,沙雅隆起中段(图1),北接库车坳陷,南部与顺托果勒低隆起相邻。塔河油田古生界各层系均有油气分布,以中—下奥陶统碳酸盐岩缝洞型油气藏为主(高玉飞等,2013)。
塔河油田奥陶纪整体为碳酸盐岩台地背景,中下奥陶统发育蓬莱坝组、鹰山组和一间房组;上奥陶统发育吐木休克组、良里塔格组和桑塔木组(陈轩等,2023;张长建等,2024)。蓬莱坝组主要为灰褐、灰色灰岩、云质灰岩夹灰质云岩、白云岩;鹰山组以浅褐、褐灰、灰色灰岩为主夹灰色灰质云岩、云质灰岩;一间房组主要为灰色灰岩、泥晶灰岩、生屑灰岩等;吐木休克组以棕灰色泥晶灰岩、紫红色瘤状灰岩为主;良里塔格组主要为灰褐、褐灰色灰岩、泥质灰岩,夹生屑灰岩、砂屑灰岩;桑塔木组主要以灰、深灰色泥岩为主,夹泥质粉砂岩及泥灰岩(刘文等,2002;史江涛等,2022;郭春涛等,2024)。
本次研究共采集塔河油田奥陶系油田水样品64件,采样点为塔河油田奥陶系生产油井的井口(图2),各井的生产井段及产水量见表1。将含有原油的油田水样品初步分离后装入干净的聚乙烯采样瓶,每个样品采集1500 mL,在实验室用滤纸将原油过滤除去,在自然资源部岩浆作用成矿与找矿重点实验室进行水质常规分析和伴生资源分析。
检测依据为DZ/T 0064.49-2021、DZ/T 0064.51-2021、GB/T 5750.6-2023和HJ700-2014等地下水分析行业标准,质量控制执行DZ/T 0130-2006地质矿产实验室测试质量管理规范要求。矿化度采用重量法;K+、Na+、Ca2+、Mg2+采用电感耦合等离子体发射光谱法;B3+、Li+、Sr2+、Rb+采用电感耦合等离子体质谱法;SO42−、C1−、Br−、NO3−采用离子色谱法;CO32−、HCO3−采用滴定法;I−采用硫酸铈催化分光光度法分别进行测试分析。
塔河油田奥陶系油田水主要阳离子浓度高低为:Na+>Ca2+>K+>Mg2+,Na+平均值为63.81 g/L,Ca2+平均值为10.79 g/L,K+平均值为1 781.19 mg/L,Mg2+平均值为968.20 mg/L;主要阴离子浓度高低为:Cl−>SO42−>HCO3−>NO3−,Cl−平均值为134.58 g/L,SO42−平均值为255.31 mg /L,HCO3−平均值为177.70 mg /L,NO3−平均值为33.12 mg /L。未检测出CO32−,这是因为油田水样品pH值介于5.5~6.0之间,呈弱酸性,因此未检测出CO32−是合理的(表1)。由于封闭环境下普遍存在的细菌还原作用,油田水中SO42−含量不高可能和细菌还原作用有关。
油田水的总矿化度(TDS)是指水中各种离子、分子、化合物的总含量,一般用在110 ℃下把水分蒸干所剩残渣的量来计量(钱一雄等,2005)。测试结果表明,塔河油田奥陶系油田水普遍拥有较高的矿化度含量,介于140~260 g/L,平均值为216.56 g/L,根据《矿产地质勘查规范 盐类》(DZ/T 0212—2020),属于中等矿化度;达到正常海水(35 g/L)矿化度的6.19倍,主体分布于210~240 g/L(表1,图3)。
油田水矿化度的大小主要受油田水中Cl−、Na+、Ca2+等主要离子的影响,与Cl−的相关系数为0.936(图4a),与Na++Ca2+的相关系数为0.894(图4b),说明塔河油田奥陶系油田水的矿化度主要受这两类离子浓度控制。
纵向上,随着深度的增加,塔河油田奥陶系油田水矿化度总体先有增大趋势,后又略降(图5)。油田水中伴生资源含量与矿化度的相关性均不强,K+、Li+、B3+、Br−、Rb+、Sr2+与矿化度的相关系数分别为0.037、0.047、0.173、0.134、0.021和0.142(图6)。
各国学者对于油田水分类方法不同,其中使用最多的是苏林分类(张金来,1979;汪蕴璞,1983)。苏林分类法是根据油田水中的盐类离子组成及含量差异,依据Na+/Cl−、(Na+-Cl−)/SO42−和(Cl−-Na+)/ Mg2+成因系数将油田水划分为Na2SO4型、NaHCO3型、MgCl2型和CaCl2型4种(表2)。
根据塔河油田油田水测试结果计算其成因系数(表3),Na+/Cl−值介于0.42~0.50,平均值为0.47,全部小于1;(Na+-Cl−)/SO42−值介于−1707.14~−104.83,平均值为−342.96,全部小于0;(Cl−-Na+)/ Mg2+值介于45.13~114.82,平均值为74.27,全部大于1。依据苏林分类法塔河油田奥陶系油田水均为氯化钙型,说明塔河油田奥陶系油田水埋藏较深、不受大气降水补给。
除了常用到的矿化度、水型外,特征系数常用来反映油田水的成因、赋存状态以及演化规律。常用的特征系数有钠氯系数(Na+/Cl−)c、溴氯系数(1 000×Br−/Cl−)ρ、脱硫系数(100×SO42 −/2×Cl−)c、钙镁系数(Ca2+/Mg2+)c、钾氯系数(1 000×K+/Cl−)ρ和硼氯系数(1 000×B3+/Cl−)c等(Davis et al.,1998,林晓英等,2012;韩佳君等,2013;李建森等,2014;杨丽杰等,2018;牛新生等,2021;赵雪松等,2024),其中c代表相关组分的物质量浓度,ρ代表相关组分的质量浓度。
(1)钠氯系数(Na+/Cl−)c可以判断油田水的来源、浓缩变质程度及水动力条件等。通常正常海水钠氯系数为0.85~0.87;岩盐层溶滤形成的地下水接近1;受大气降水淋滤作用影响的地下水一般大于1;受阳离子交替吸附和强烈的水岩相互作用的地下水一般小于0.85(李雯霞等,2016;石国成等,2016)。研究区油田水的钠氯系数为0.64~0.77,平均值为0.73(表4,图7),说明塔河油田奥陶系油田水经历了阳离子交替吸附和强烈的水岩相互作用。塔河油田奥陶系油田水在长时间的埋藏过程中与各种矿物及岩石发生反应或进行交换作用,特别表现在碳酸盐岩的溶解和再成岩中钙离子进入到油田水溶液中,这也是塔河油田奥陶系油田水Ca2+含量较高的原因。
(2)溴氯系数(1 000×Br−/Cl−)ρ可以判断油田水的成因。自然界中溴主要赋存在海洋中,在海水中的浓度为65 mg/L,海水具有稳定的Cl和Br含量(Fontes et al.,1986;Alcalá et al.,2008)。正常海水溴氯系数约为3.44,而溶滤油田水的溴氯系数通常较低(赵雪松等,2024)。研究区油田水的溴氯系数为0.35~2.78,平均值为1.72(表4,图7),远远低于3.44,说明塔河油田奥陶系油田水为溶滤油田水。
(3)脱硫系数(100×SO42 −/2×Cl−)c反映油田水所处的封闭程度,封闭性越好还原性越强,其值越小。通常用1 作为脱硫作用彻底与否的界限值,脱硫系数小于1,表明地层水还原彻底,油藏封闭性好;其值大于1,则表明还原不彻底,可能受浅表层氧化作用的影响(李雯霞等,2016)。研究区油田水的脱硫系数为0.01~0.09,平均值为0.04(表4,图7),说明塔河油田奥陶系油田水还原彻底、油藏封闭性好。
(4)钙镁系数(Ca2+/Mg2+)c反映油田水的变质程度和封闭性,封闭性越好,则变质程度越高,其值越高。判断标准值为3,深层油田水此系数一般大于3(李廷伟等,2006;韩佳君等,2013)。研究区油田水的钙镁系数为4.49~11.19,平均值为6.85(表4,图7),均大于3,说明塔河油田奥陶系油田水的封闭性好,且变质程度较高。
(5)钾氯系数(1 000×K+/Cl−)ρ反映钾的富集和油田水的浓缩程度。通常钾氯系数在10~20时为异常,大于20时为异常显著,大于75时达到钾盐沉积阶段(李建森等,2014)。研究区油田水的钾氯系数为4.31~27.56,平均值为13.36(表4,图7)。钾氯系数除TH48-TH46-TH49、TH53和TH05-TH06等3个井区外,其余井的钾氯系数均大于10,达到异常;TH37和TH55-TH56两个井区的钾氯系数达到20以上,为异常显著。
(6)硼氯系数(1 000×B3+/Cl−)c可以判断油田水所溶解的固体盐类物质来源(韩继龙,2018;赵雪松等,2024),海相地层水硼氯系数值为0.79(吴双等,2024)。研究区油田水的硼氯系数为0.25~12.16,平均值为1.35(表4,图7),远高于海相该系数特征值,说明油田水中的离子并非来源于海相物质,而是来源于岩盐、石膏和碎屑黏土矿物等。一般认为富氯油田水主要是由盐岩矿物溶解造成的(蔡立国等,2002),这与前述塔河油田奥陶系油田水矿化度主要受Na++Ca2+、Cl−的控制一致。
根据《矿产地质勘查规范 盐类》(DZ/T 0212—2020)、矿产资源工业要求参考手册及前人研究成果(宋鹤彬,1997;樊启顺等,2007),总结油田水中伴生资源单独开采及综合利用指标(表5)。塔河油田奥陶系油田水中K+含量大多为1 400~2 000 mg/L(图8a),平均值为1 781.19 mg/L;Li+含量主大多为10~16 mg/L(图8b),平均值为11.16 mg/L;Br−含量大多为200~260 mg/L(图8c),平均值为230.77 mg/L;Sr2+含量大多为430~510 mg/L(图8d),平均值为473.31 mg/L,均能达到综合利用的工业指标。B3+含量大多为40~60 mg/L(图8e),平均值为52.59 mg/L,TH13、TH24等13口井能达到综合利用指标;I−含量大部分井小于0.02 mg/L,只有TH37、TH48、TH54、TH55、TH56、TH60井能达到综合利用的指标(图8f),平均值为2.70 mg/L;Rb+含量普遍较低,介于1.15~4.98 mg/L,平均值为2.32 mg/L,未达到综合利用的指标。
塔河油田奥陶系油田水K+含量为556~2740 mg/L,平均值为1781.19 mg/L(表1,图8a),除TH48井外,其余井K+含量均大于综合利用的工业指标。平面上K+含量低值区位于TH48-TH46、TH53、TH33和TH05-TH06井区;高值区位于TH57、TH44、TH37、TH56和TH47-TH51井区(图9)。
塔河油田奥陶系油田水Li+含量为2.9~18.5 mg/L,平均值为11.16 mg/L(表1,图8b)。平面上Li+含量与K+含量分布具有相似的特征,高值区与低值区基本一致。低值区位于TH48-TH46、TH18、TH15、TH03-TH06-TH11井区;高值位于TH37、TH56、TH47-TH51和TH41-TH52井区(图10)。
塔河油田奥陶系油田水Br−含量为45~323 mg/L,平均值为230.77 mg/L(表1,图8c),除TH48井外,其余井Br−含量均大于综合利用的工业指标。平面上Br−含量与K+、Li+含量分布具有相似的特征,高值区与低值区基本一致。低值区位于TH48-TH46、TH33-TH29-TH06-TH11井区;高值位于TH44、TH61、TH57、TH09、TH41和TH47井区(图11)。
塔河油田奥陶系油田水Sr2+含量为341~605 mg/L,平均值为473.31 mg/L(表1,图8d),Sr2+在平面上总体呈现北东低,向南西增高的趋势,低值区位于TH37、TH03和TH53-TH42-TH63井区,高值区位于TH32-TH27-TH23、TH46、TH44和TH56井区(图12)。
(1)塔河油田奥陶系油田水主要阳离子浓度高低为:Na+>Ca2+>K+>Mg2+,主要阴离子浓度高低为:Cl−>SO42−>HCO3−>NO3−,矿化度为140~260 g/L,平均值为216.56 g/L,属于中等矿化度,达到正常海水矿化度的6.19倍。
(2)塔河油田奥陶系油田水均为氯化钙型,经历了阳离子交替吸附和强烈的水岩相互作用,为溶滤油田水,还原彻底、油藏封闭性好、变质程度较高,油田水中的离子主要来源于岩盐、石膏和碎屑黏土矿物等。
(3)塔河油田奥陶系油田水中富含的K+、Li+、Br−、Sr2+等伴生资源达到综合利用的工业指标,且K+、Li+和Br−在平面上具有相似的分布规律。

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2026年第59卷第4期
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doi: 10.12401/j.nwg.2025057
  • 接收时间:2025-03-11
  • 首发时间:2026-09-16
  • 出版时间:2026-08-20
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  • 收稿日期:2025-03-11
  • 修回日期:2025-06-09
  • 录用日期:2025-06-11
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    1中国石油化工股份有限公司西北油田分公司勘探开发研究院,新疆 乌鲁木齐 830011
    2中国地质调查局西安地质调查中心(西北地质科技创新中心),陕西 西安 710119

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史冀忠(1983−),男,正高级工程师,主要从事沉积学及油气基础地质调查研究。E−mail:。
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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