Article(id=1304141603099136241, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141595331293792, articleNumber=null, orderNo=null, doi=10.3969/j.issn.1009-3842.2026.04.003, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1779206400000, receivedDateStr=2026-05-20, revisedDate=1781625600000, revisedDateStr=2026-06-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1788861187957, onlineDateStr=2026-09-08, pubDate=1787846400000, pubDateStr=2026-08-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1788861187957, onlineIssueDateStr=2026-09-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1788861187957, creator=13701087609, updateTime=1788861187957, updator=13701087609, issue=Issue{id=1304141595331293792, tenantId=1146029695717560320, journalId=1303687303576780880, year='2026', volume='', issue='4', pageStart='1', pageEnd='132', issueExtLink='null', onlineDate='null', pubDate='1787846400000', pubDateStr='2026-08-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1788861186106, creator='13701087609', updateTime=1788924908244, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1304408865437672371, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141595331293792, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1304408865437672372, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141595331293792, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=24, endPage=33, ext={EN=ArticleExt(id=1304141603489206515, articleId=1304141603099136241, tenantId=1146029695717560320, journalId=1303687303576780880, language=EN, title=Structural Properties and Performance of Multi-Phase Refractory Materials Prepared from Copper Smelting Slag, columnId=1304141596639916642, journalTitle=Copper Engineering, columnName=Special Topic: Utilization of Mining and Metallurgical Solid Waste and Pollution Control, runingTitle=null, highlight=null, articleAbstract=

Multi-phase refractory materials were prepared using copper slag tailings and waste high-alumina bricks. Thermodynamic behavior of copper slag tailings during sintering was studied by XRD and TG-MS. Influence of copper slag tailing and waste high-alumina brick content on mechanical properties and high temperature properties of refractory materials were studied. Microstructure and phase transition process of multi-phase refractory materials were studied by SEM-EDS and XRD. Results showed that decomposition product of iron olivine in copper slag tailings reacted in-situ with alumina in waste high-alumina brick, and finally formed a mullite-corundum composite crystal phase combined with Fe-Al intercrystalline phase. When mass fraction of waste high-alumina brick and copper slag tailing was 40% and 10%, respectively, comprehensive performance of refractory material was the best. Compressive strength was 110.4 MPa, refractoriness under load reached 1 399 ℃, and strength retention rate after thermal shock was more than 80%. Research results provided a new prospective for high-value utilization of copper slag tailings and waste high-alumina bricks which are the main solid waste in copper smelting industry.

, authors=Yang Gao1, Bingrong Li1, Quanyong Wang1, Yongqiang Zhu2, Jin Yu1, Yu Tu1, Wei Zhang1, Yunlong Sun1, authorsList=Yang Gao, Bingrong Li, Quanyong Wang, Yongqiang Zhu, Jin Yu, Yu Tu, Wei Zhang, Yunlong Sun, authorCompany=null, correspAuthors=Bingrong Li, Yunlong Sun, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304141603988328693, articleId=1304141603099136241, tenantId=1146029695717560320, journalId=1303687303576780880, language=CN, title=铜渣尾矿制备复相耐火材料的结构与性能研究, columnId=1304878720477590059, journalTitle=铜业工程, columnName=矿冶固废资源综合利用与污染防治专题, runingTitle=null, highlight=null, articleAbstract=

本研究以铜冶炼渣选尾矿与废高铝砖为主要原料,制备了复相耐火材料。采用X射线衍射(XRD)和热重-质谱联用(TG-MS)方法分析了铜渣尾矿在烧结过程中的热化学行为;利用扫描电镜(SEM)、能谱分析(EDS)与XRD表征了复相耐火材料的微观结构及相转变过程。系统探讨了铜渣尾矿与废高铝砖添加量对材料力学性能和高温性能的影响机理。结果表明,铜渣尾矿中铁橄榄石的分解产物与废高铝砖中的氧化铝发生原位反应,最终形成铁铝晶间相-莫来石-刚玉复合晶相。当废高铝砖质量分数为40%、铜渣尾矿质量分数为10%时,所制备复相耐火材料的综合性能最优,抗压强度达110.4 MPa,0.2 MPa荷重软化温度为1 399 ℃,热震后强度保持率超过80%。该研究可为铜冶炼行业大宗固废——铜冶炼渣选尾矿与废高铝砖的高值化利用提供新的技术路径。

, authors=高杨1, 李炳蓉1, 王全勇1, 朱勇强2, 俞锦1, 涂宇1, 张威1, 孙云龙1, authorsList=高杨, 李炳蓉, 王全勇, 朱勇强, 俞锦, 涂宇, 张威, 孙云龙, authorCompany=null, correspAuthors=李炳蓉, 孙云龙, authorNote=

高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

, correspAuthorsNote=
孙云龙,高级工程师,E-mail:
李炳蓉,工程师,E-mail:
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高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

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高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

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铜渣尾矿制备复相耐火材料的结构与性能研究
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高杨 1 , 李炳蓉 1 , 王全勇 1 , 朱勇强 2 , 俞锦 1 , 涂宇 1 , 张威 1 , 孙云龙 1
铜业工程 | 矿冶固废资源综合利用与污染防治专题 2026,(4): 24-33
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铜业工程 |矿冶固废资源综合利用与污染防治专题 2026 , (4) : 24 -33
铜渣尾矿制备复相耐火材料的结构与性能研究
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高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

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高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

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高杨1 , 李炳蓉1 , 王全勇1, 朱勇强2, 俞锦1, 涂宇1, 张威1, 孙云龙1
作者信息
  • 1.江西铜业股份有限公司南昌研发中心,江西 南昌 330096
  • 2.江西铜业股份有限公司 贵溪冶炼厂,江西 鹰潭 335400
通讯作者:
孙云龙,高级工程师,E-mail:
李炳蓉,工程师,E-mail:
作者简介:

高杨(1993—),男,江苏扬州人,博士,工程师,研究方向:无机材料及固废综合利用,E-mail:

Structural Properties and Performance of Multi-Phase Refractory Materials Prepared from Copper Smelting Slag
Yang Gao1 , Bingrong Li1 , Quanyong Wang1, Yongqiang Zhu2, Jin Yu1, Yu Tu1, Wei Zhang1, Yunlong Sun1
Affiliations
  • 1.Jiangxi Copper Co.,Ltd.,Nanchang R&D Center,Nanchang 330096,China
  • 2.Guixi Smelter,Jiangxi Copper Co.,Ltd.,Guixi 335400,China
出版时间: 2026-08-28 doi: 10.3969/j.issn.1009-3842.2026.04.003
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本研究以铜冶炼渣选尾矿与废高铝砖为主要原料,制备了复相耐火材料。采用X射线衍射(XRD)和热重-质谱联用(TG-MS)方法分析了铜渣尾矿在烧结过程中的热化学行为;利用扫描电镜(SEM)、能谱分析(EDS)与XRD表征了复相耐火材料的微观结构及相转变过程。系统探讨了铜渣尾矿与废高铝砖添加量对材料力学性能和高温性能的影响机理。结果表明,铜渣尾矿中铁橄榄石的分解产物与废高铝砖中的氧化铝发生原位反应,最终形成铁铝晶间相-莫来石-刚玉复合晶相。当废高铝砖质量分数为40%、铜渣尾矿质量分数为10%时,所制备复相耐火材料的综合性能最优,抗压强度达110.4 MPa,0.2 MPa荷重软化温度为1 399 ℃,热震后强度保持率超过80%。该研究可为铜冶炼行业大宗固废——铜冶炼渣选尾矿与废高铝砖的高值化利用提供新的技术路径。

铜冶炼渣  /  耐火材料  /  相变  /  高温性能  /  力学性能

Multi-phase refractory materials were prepared using copper slag tailings and waste high-alumina bricks. Thermodynamic behavior of copper slag tailings during sintering was studied by XRD and TG-MS. Influence of copper slag tailing and waste high-alumina brick content on mechanical properties and high temperature properties of refractory materials were studied. Microstructure and phase transition process of multi-phase refractory materials were studied by SEM-EDS and XRD. Results showed that decomposition product of iron olivine in copper slag tailings reacted in-situ with alumina in waste high-alumina brick, and finally formed a mullite-corundum composite crystal phase combined with Fe-Al intercrystalline phase. When mass fraction of waste high-alumina brick and copper slag tailing was 40% and 10%, respectively, comprehensive performance of refractory material was the best. Compressive strength was 110.4 MPa, refractoriness under load reached 1 399 ℃, and strength retention rate after thermal shock was more than 80%. Research results provided a new prospective for high-value utilization of copper slag tailings and waste high-alumina bricks which are the main solid waste in copper smelting industry.

copper smelting slag  /  refractory material  /  phase transition  /  high-temperature property  /  mechanical property
高杨, 李炳蓉, 王全勇, 朱勇强, 俞锦, 涂宇, 张威, 孙云龙. 铜渣尾矿制备复相耐火材料的结构与性能研究. 铜业工程, 2026 , (4) : 24 -33 . DOI: 10.3969/j.issn.1009-3842.2026.04.003
Yang Gao, Bingrong Li, Quanyong Wang, Yongqiang Zhu, Jin Yu, Yu Tu, Wei Zhang, Yunlong Sun. Structural Properties and Performance of Multi-Phase Refractory Materials Prepared from Copper Smelting Slag[J]. Copper Engineering, 2026 , (4) : 24 -33 . DOI: 10.3969/j.issn.1009-3842.2026.04.003
  • 江西铜业技术研究院有限公司企业项目(YJYZX2025003; YJYZX2025005)
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doi: 10.3969/j.issn.1009-3842.2026.04.003
  • 接收时间:2026-05-20
  • 首发时间:2026-09-08
  • 出版时间:2026-08-28
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  • 收稿日期:2026-05-20
  • 修回日期:2026-06-17
基金
江西铜业技术研究院有限公司企业项目(YJYZX2025003; YJYZX2025005)
作者信息
    1.江西铜业股份有限公司南昌研发中心,江西 南昌 330096
    2.江西铜业股份有限公司 贵溪冶炼厂,江西 鹰潭 335400

通讯作者:

孙云龙,高级工程师,E-mail:
李炳蓉,工程师,E-mail:
参考文献
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https://castjournals.cast.org.cn/joweb/tygc/CN/10.3969/j.issn.1009-3842.2026.04.003
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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