Article(id=1304141589585088601, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141567850213817, articleNumber=null, orderNo=null, doi=10.3969/j.issn.1009-3842.2026.03.013, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756051200000, receivedDateStr=2025-08-25, revisedDate=1767456000000, revisedDateStr=2026-01-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1788861184736, onlineDateStr=2026-09-08, pubDate=1782576000000, pubDateStr=2026-06-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1788861184736, onlineIssueDateStr=2026-09-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1788861184736, creator=13701087609, updateTime=1788861184736, updator=13701087609, issue=Issue{id=1304141567850213817, tenantId=1146029695717560320, journalId=1303687303576780880, year='2026', volume='', issue='3', pageStart='1', pageEnd='134', issueExtLink='null', onlineDate='null', pubDate='1782576000000', pubDateStr='2026-06-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1788861179554, creator='13701087609', updateTime=1788924930580, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1304408959088092087, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141567850213817, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1304408959088092088, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141567850213817, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=113, endPage=124, ext={EN=ArticleExt(id=1304141589815775322, articleId=1304141589585088601, tenantId=1146029695717560320, journalId=1303687303576780880, language=EN, title=Application of Ion Exchange Technology in Mine Discharge Water Softening, columnId=1304141579946586655, journalTitle=Copper Engineering, columnName=Mineral Processing and Process Mineralogy, runingTitle=null, highlight=null, articleAbstract=

In response to the high hardness of discharged water (350~900 mg/L CaCO3), seasonal water scarcity, and pipeline scaling risk at Wushan Copper Mine in Jiangxi, this study developed a softening and reuse process based on ion exchange resin. Laboratory-scale tests were conducted to select a domestic Zhengguang (working exchange capacity 550~600 mmol/L). Operating parameters were optimized (flow rate 12 m/h, regenerant concentration 6%~8% NaCl), and the feasibility was verified at an industrial scale of 120 m3/h. Results showed that the softened water hardness was stably controlled at 0~130 mg/L CaCO3, with a Ryznar stability index of 6.0~7.3. Regenerant salt consumption was 210~245 g/mol, and treatment cost per ton of water was 0.686 RMB/ton, of which the salt cost was 0.684 RMB/ton. Resin cost per cubic meter of softened water was 0.069 RMB/m3, and the average electricity cost for recycled water was 0.002 RMB/m3, comparable to current water intake cost. Concentrations of heavy metals in the regeneration waste complied with the GB 25467—2010 discharge standards (Pb<0.37 mg/L, Zn<0.45 mg/L). This technology addressed the production risk caused by seasonal water interruptions of the Nanyang River, achieved 100% wastewater reuse, and provided a solution for treating high-hardness mine wastewater.

, authors=Xugui Zhang, Jian Zhang, Ximing Li, Xinhao Xu, authorsList=Xugui Zhang, Jian Zhang, Ximing Li, Xinhao Xu, authorCompany=null, correspAuthors=Jian Zhang, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304141590226817115, articleId=1304141589585088601, tenantId=1146029695717560320, journalId=1303687303576780880, language=CN, title=离子交换技术在矿山外排水软化处理中的应用研究, columnId=1304141580147913249, journalTitle=铜业工程, columnName=矿物加工与工艺矿物学, runingTitle=null, highlight=null, articleAbstract=

针对江西铜业股份有限公司武山铜矿外排水硬度高(350~900 mg/L,CaCO3)、季节性水源短缺及管道结垢风险问题,通过实验室小试筛选出国产争光树脂(工作交换容量550~600 mmol/L),优化运行参数(流速12 m/h,再生液浓度6%~8% NaCl),并在120 m3/h工业规模验证其可行性。结果表明:软化水硬度稳定控制在0~130 mg/L (以CaCO3计),Ryznar稳定指数(RSI)6.0~7.3,再生盐耗210~245 g/mol。成本与现有取水方式相当,吨水处理成本为0.755元,其中:盐0.684元,树脂0.069元,电0.002元。再生废液中重金属浓度符合《GB 25467—2010》排放标准(Pb<0.37 mg/L,Zn<0.45 mg/L)。该技术可实现废水回用率100%,解决了南阳河季节性断流影响生产的问题,为高硬度矿山废水处理提供了解决方案。

, authors=张绪贵, 张健, 黎希明, 许新浩, authorsList=张绪贵, 张健, 黎希明, 许新浩, authorCompany=null, correspAuthors=张健, authorNote=

张绪贵(1983—),男,江西瑞昌人,本科,高级工程师,研究方向:给排水技术,E-mail:

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张健,工程师,E-mail:
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张绪贵(1983—),男,江西瑞昌人,本科,高级工程师,研究方向:给排水技术,E-mail:

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张绪贵(1983—),男,江西瑞昌人,本科,高级工程师,研究方向:给排水技术,E-mail:

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离子交换技术在矿山外排水软化处理中的应用研究
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张绪贵 , 张健 , 黎希明 , 许新浩
铜业工程 | 矿物加工与工艺矿物学 2026,(3): 113-124
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铜业工程 |矿物加工与工艺矿物学 2026 , (3) : 113 -124
离子交换技术在矿山外排水软化处理中的应用研究
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张绪贵 , 张健 , 黎希明, 许新浩
作者信息
  • 江西铜业股份有限公司 武山铜矿,江西 瑞昌 332200
通讯作者:
张健,工程师,E-mail:
作者简介:

张绪贵(1983—),男,江西瑞昌人,本科,高级工程师,研究方向:给排水技术,E-mail:

Application of Ion Exchange Technology in Mine Discharge Water Softening
Xugui Zhang , Jian Zhang , Ximing Li, Xinhao Xu
Affiliations
  • Electromechanical Workshop,Jiangxi Copper Group Wushan Copper Mine,Ruichang 332200,China
出版时间: 2026-06-28 doi: 10.3969/j.issn.1009-3842.2026.03.013
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针对江西铜业股份有限公司武山铜矿外排水硬度高(350~900 mg/L,CaCO3)、季节性水源短缺及管道结垢风险问题,通过实验室小试筛选出国产争光树脂(工作交换容量550~600 mmol/L),优化运行参数(流速12 m/h,再生液浓度6%~8% NaCl),并在120 m3/h工业规模验证其可行性。结果表明:软化水硬度稳定控制在0~130 mg/L (以CaCO3计),Ryznar稳定指数(RSI)6.0~7.3,再生盐耗210~245 g/mol。成本与现有取水方式相当,吨水处理成本为0.755元,其中:盐0.684元,树脂0.069元,电0.002元。再生废液中重金属浓度符合《GB 25467—2010》排放标准(Pb<0.37 mg/L,Zn<0.45 mg/L)。该技术可实现废水回用率100%,解决了南阳河季节性断流影响生产的问题,为高硬度矿山废水处理提供了解决方案。

离子交换  /  废水回用  /  硬度控制  /  再生盐耗  /  水质稳定指数  /  矿山废水

In response to the high hardness of discharged water (350~900 mg/L CaCO3), seasonal water scarcity, and pipeline scaling risk at Wushan Copper Mine in Jiangxi, this study developed a softening and reuse process based on ion exchange resin. Laboratory-scale tests were conducted to select a domestic Zhengguang (working exchange capacity 550~600 mmol/L). Operating parameters were optimized (flow rate 12 m/h, regenerant concentration 6%~8% NaCl), and the feasibility was verified at an industrial scale of 120 m3/h. Results showed that the softened water hardness was stably controlled at 0~130 mg/L CaCO3, with a Ryznar stability index of 6.0~7.3. Regenerant salt consumption was 210~245 g/mol, and treatment cost per ton of water was 0.686 RMB/ton, of which the salt cost was 0.684 RMB/ton. Resin cost per cubic meter of softened water was 0.069 RMB/m3, and the average electricity cost for recycled water was 0.002 RMB/m3, comparable to current water intake cost. Concentrations of heavy metals in the regeneration waste complied with the GB 25467—2010 discharge standards (Pb<0.37 mg/L, Zn<0.45 mg/L). This technology addressed the production risk caused by seasonal water interruptions of the Nanyang River, achieved 100% wastewater reuse, and provided a solution for treating high-hardness mine wastewater.

ion exchange  /  wastewater reuse  /  hardness control  /  regeneration salt consumption  /  water quality stability index  /  mining wastewater
张绪贵, 张健, 黎希明, 许新浩. 离子交换技术在矿山外排水软化处理中的应用研究. 铜业工程, 2026 , (3) : 113 -124 . DOI: 10.3969/j.issn.1009-3842.2026.03.013
Xugui Zhang, Jian Zhang, Ximing Li, Xinhao Xu. Application of Ion Exchange Technology in Mine Discharge Water Softening[J]. Copper Engineering, 2026 , (3) : 113 -124 . DOI: 10.3969/j.issn.1009-3842.2026.03.013
  • 江西铜业股份有限公司武山铜矿外排水软化工业应用关键技术研究项目(WTYJ2022004)
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doi: 10.3969/j.issn.1009-3842.2026.03.013
  • 接收时间:2025-08-25
  • 首发时间:2026-09-08
  • 出版时间:2026-06-28
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  • 收稿日期:2025-08-25
  • 修回日期:2026-01-04
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江西铜业股份有限公司武山铜矿外排水软化工业应用关键技术研究项目(WTYJ2022004)
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    江西铜业股份有限公司 武山铜矿,江西 瑞昌 332200

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张健,工程师,E-mail:
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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