Article(id=1304141627845530066, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141619603726817, articleNumber=null, orderNo=null, doi=10.3969/j.issn.1009-3842.2026.01.008, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1744128000000, receivedDateStr=2025-04-09, revisedDate=1757606400000, revisedDateStr=2025-09-12, acceptedDate=null, acceptedDateStr=null, onlineDate=1788861193858, onlineDateStr=2026-09-08, pubDate=1772208000000, pubDateStr=2026-02-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1788861193858, onlineIssueDateStr=2026-09-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1788861193858, creator=13701087609, updateTime=1788861193858, updator=13701087609, issue=Issue{id=1304141619603726817, tenantId=1146029695717560320, journalId=1303687303576780880, year='2026', volume='', issue='1', pageStart='1', pageEnd='154', issueExtLink='null', onlineDate='null', pubDate='1772208000000', pubDateStr='2026-02-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1788861191893, creator='13701087609', updateTime=1788924965522, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1304409105645465969, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141619603726817, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1304409105645465970, tenantId=1146029695717560320, journalId=1303687303576780880, issueId=1304141619603726817, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=90, endPage=96, ext={EN=ArticleExt(id=1304141628088799699, articleId=1304141627845530066, tenantId=1146029695717560320, journalId=1303687303576780880, language=EN, title=Effect of Composite Diffusion Sources on Magnetic Properties of Sintered NdFeB Magnets, columnId=1304141568877814747, journalTitle=Copper Engineering, columnName=Material Preparation and Process Engineering, runingTitle=null, highlight=null, articleAbstract=
Grain boundary diffusion technology has emerged as a pivotal approach to overcome bottlenecks of high cost and significant remanence loss in traditional single-alloy methods by precisely regulating the distribution of heavy rare earths (HREs), thereby markedly enhancing the coercivity of NdFeB magnets. This study proposed composite diffusion sources formed by blending Tb-Al-Cu HRE alloys with pure Nd powder at varying ratios, systematically investigating their diffusion modification effects on both HRE-free and HRE-containing substrates. Experimental results demonstrated that under optimal diffusion source ratios, the maximum coercivity enhancements for the two substrates reached 1.036 T and 0.959 T, respectively, with remanence attenuation controlled within 0.59 kGs and 0.43 kGs. When TbAlCu-to-pure-Nd ratio was 3∶2 (for HRE-free substrates) or 2∶3 (for HRE-containing substrates), the magnets exhibited optimal comprehensive performance, achieving 48UH and 45EH grade levels, respectively. Microstructural analysis revealed that HRE-free substrates developed increased grain boundary phases, refined grains, and core-shell structures after diffusion, while HRE-containing substrates showed a significant increase in non-magnetic grain boundary phases. By designing composite diffusion sources, this study achieved remarkable magnetic performance improvements with low HRE consumption, offering a novel strategy for the green preparation and resource-efficient utilization of high-performance NdFeB magnets.
, authors=Hongxiong LIU, Zhiheng WANG, Yanfeng LIU, Jun CAO, Qiaobo LIU, Qiang HUANG, Jinjin YANG, Yixin CHEN, authorsList=Hongxiong LIU, Zhiheng WANG, Yanfeng LIU, Jun CAO, Qiaobo LIU, Qiang HUANG, Jinjin YANG, Yixin CHEN, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304141628445315540, articleId=1304141627845530066, tenantId=1146029695717560320, journalId=1303687303576780880, language=CN, title=Tb-Al-Cu/Nd复合扩散源对烧结钕铁硼磁性能的影响, columnId=1304141569037198301, journalTitle=铜业工程, columnName=材料制备与加工工程, runingTitle=null, highlight=null, articleAbstract=
晶界扩散技术可以通过调控重稀土元素分布,显著提升钕铁硼磁体的矫顽力,是突破传统单合金法高成本、高剩磁损耗瓶颈的关键手段。本文提出以重稀土合金Tb-Al-Cu与纯钕粉按不同比例混合形成复合扩散源,系统研究了其对无重稀土基材与含重稀土基材的扩散效果。实验结果表明,在最佳比例扩散源下,两类基材最高矫顽力分别提升1.036 T与0.959 T,剩磁衰减量分别控制在0.59 kGs与0.43 kGs以内。当Tb-Al-Cu与纯钕粉质量比为3∶2(无重稀土基材)和2∶3(含重稀土基材)时,磁体综合性能最优,分别达到48UH与45EH牌号水平。微观分析表明,无重稀土基材扩散后晶界相增多并形成核壳结构,而含重稀土基材扩散后非磁晶界相明显增多。本研究通过复合扩散源设计,实现了低重稀土用量下磁性能的显著提升,为高性能钕铁硼的绿色制备与资源高效利用提供了新策略。
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刘宏雄(1997—),男,甘肃天水人,博士,工程师,研究方向:稀土永磁,E-mail:13621357626@163.com
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刘宏雄(1997—),男,甘肃天水人,博士,工程师,研究方向:稀土永磁,E-mail:13621357626@163.com
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