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Its performance under actual field conditions, however, remains insufficiently documented. Swelling and heavy-metal adsorption behaviors of PMB and sodium bentonite (NaB) were systematically compared under varied contaminant solutions. The hydraulic performance of polymer-modified bentonite-sand (PMB-S) and sodium bentonite-sand (NaB-S) mixtures was evaluated. Furthermore, the feasibility of using in situ phosphate mine waste as a substrate material in PMB-based barriers was discussed. Results show that across the pH range of 2 to 12, PMB always maintains a free swelling index greater than 50 mL/2 g, significantly higher than that of NaB. Additionally, its adsorption performance for Pb2+ and Cu2+ is superior to that of NaB, with the removal rates increasing by 58.42% and 61.31%, respectively, particularly in acidic environments. The hydraulic conductivity of PMB-S is significantly lower than that of NaB-S, and may consistently achieve values below 1×10-8 cm/s in most contaminated environments. The mixtures of PMB with three phosphate mine wastes have comparable hydraulic performance to PMB-S, confirming its feasibility as a barrier material. 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articleAbstract=聚合物改性膨润土(PMB)因其低渗透性和优异的抗盐能力,已成为工业固废防渗领域的研究热点。然而,目前关于PMB在真实尾矿库服役环境中的研究与应用仍较有限。系统比较PMB与钠基膨润土(NaB)在不同污染环境下的膨胀性和重金属吸附性能,评估聚合物改性膨润土-砂(PMB-S)与NaB-砂(NaB-S)混合物的渗透性能,并进一步探讨磷矿现场弃渣作为基质材料与PMB混合用于防渗的可行性。结果表明,PMB在pH 2~pH 12范围内自由膨胀指数始终>50 mL/2 g,显著高于NaB;同时,其对Pb2+和Cu2+的吸附性能也优于NaB,尤其在酸性环境下,去除率分别提高58.42%和61.31%。PMB-S混合物的渗透系数明显低于NaB-S,且在多数污染环境下可稳定低于1×10-8 cm/s。PMB与三种磷矿弃渣混合物的渗透性能与PMB-S接近,验证弃渣作为防渗基质材料的可行性。通过在强碱性铅锌矿和强酸性磷石膏尾矿库开展原位防渗工程示范,进一步验证PMB-S在实际工况下的防渗与污染阻隔性能。, correspAuthors=杨微, authorNote=杨微(1986—),女,博士,教授。主要从事环境岩土工程的研究。 2: 何逸飞(1999—),男,硕士研究生。主要从事环境岩土工程的研究。 何逸飞: 任孟健(1996—),男,硕士,工程师。主要从事环境岩土工程的研究。 2: 陈仁朋(1972—),男,博士,教授。主要从事岩土体土拱效应、城市地下空间开发技术、交通岩土工程技术等研究。 任孟健: 王瀚霖(1989—),男,博士,教授。主要从事岩土体土拱效应、城市地下空间开发技术、交通岩土工程技术等研究。 陈仁朋: 袁平(1981—),男,学士,高级工程师。主要从事冶金矿山尾矿库的研究。 2: 郭承晖(1985—),男,学士。主要从事冶金矿山尾矿库的研究。, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=+NpKsJb9rzwp/G29Zq6DVw==, pdfFileSize=6417167, 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土木工程学报
| 岩土力学与地基基础 2026, 59(1): 87-99
聚合物改性膨润土-砂混合物防渗工程应用初探
全屏
杨微, 何逸飞, 任孟健, 陈仁朋, 王瀚霖, 袁平, 郭承晖
作者信息
Preliminary study on the engineering application of polymer-modified bentonite-sand mixtures for seepage control
Affiliations
doi: 10.15951/j.tmgcxb.25060359
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聚合物改性膨润土(PMB)因其低渗透性和优异的抗盐能力,已成为工业固废防渗领域的研究热点。然而,目前关于PMB在真实尾矿库服役环境中的研究与应用仍较有限。系统比较PMB与钠基膨润土(NaB)在不同污染环境下的膨胀性和重金属吸附性能,评估聚合物改性膨润土-砂(PMB-S)与NaB-砂(NaB-S)混合物的渗透性能,并进一步探讨磷矿现场弃渣作为基质材料与PMB混合用于防渗的可行性。结果表明,PMB在pH 2~pH 12范围内自由膨胀指数始终>50 mL/2 g,显著高于NaB;同时,其对Pb2+和Cu2+的吸附性能也优于NaB,尤其在酸性环境下,去除率分别提高58.42%和61.31%。PMB-S混合物的渗透系数明显低于NaB-S,且在多数污染环境下可稳定低于1×10-8 cm/s。PMB与三种磷矿弃渣混合物的渗透性能与PMB-S接近,验证弃渣作为防渗基质材料的可行性。通过在强碱性铅锌矿和强酸性磷石膏尾矿库开展原位防渗工程示范,进一步验证PMB-S在实际工况下的防渗与污染阻隔性能。
聚合物改性膨润土
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膨胀特性
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吸附性能
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渗透系数
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原位试验
Polymer-modified bentonite (PMB) has been extensively investigated for industrial waste containment due to its low hydraulic conductivity and salt resistance. Its performance under actual field conditions, however, remains insufficiently documented. Swelling and heavy-metal adsorption behaviors of PMB and sodium bentonite (NaB) were systematically compared under varied contaminant solutions. The hydraulic performance of polymer-modified bentonite-sand (PMB-S) and sodium bentonite-sand (NaB-S) mixtures was evaluated. Furthermore, the feasibility of using in situ phosphate mine waste as a substrate material in PMB-based barriers was discussed. Results show that across the pH range of 2 to 12, PMB always maintains a free swelling index greater than 50 mL/2 g, significantly higher than that of NaB. Additionally, its adsorption performance for Pb2+ and Cu2+ is superior to that of NaB, with the removal rates increasing by 58.42% and 61.31%, respectively, particularly in acidic environments. The hydraulic conductivity of PMB-S is significantly lower than that of NaB-S, and may consistently achieve values below 1×10-8 cm/s in most contaminated environments. The mixtures of PMB with three phosphate mine wastes have comparable hydraulic performance to PMB-S, confirming its feasibility as a barrier material. Furthermore, field demonstrations in alkaline lead-zinc and acidic phosphogypsum tailings validate the robust hydraulic and contaminant barrier properties of PMB-S under actual conditions.
polymer-modified bentonite
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swelling characteristics
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adsorption properties
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hydraulic conductivity
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in-situ test
杨微, 何逸飞, 任孟健, 陈仁朋, 王瀚霖, 袁平, 郭承晖.
聚合物改性膨润土-砂混合物防渗工程应用初探.
土木工程学报,
2026
, 59
(1)
: 87
-99
.
DOI: 10.15951/j.tmgcxb.25060359
.
Preliminary study on the engineering application of polymer-modified bentonite-sand mixtures for seepage control[J].
China Civil Engineering Journal ,
2026
, 59
(1)
: 87
-99
.
DOI: 10.15951/j.tmgcxb.25060359
2026年第59卷第1期
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doi: 10.15951/j.tmgcxb.25060359
接收时间:2024-06-11
首发时间:2026-05-08
https://castjournals.cast.org.cn/joweb/tmgcxb/CN/10.15951/j.tmgcxb.25060359
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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