Article(id=1309639371951792765, tenantId=1146029695717560320, journalId=1146119893612605453, issueId=1309639371255542472, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1710172800000, receivedDateStr=2024-03-12, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1790171958195, onlineDateStr=2026-09-23, pubDate=1763568000000, pubDateStr=2025-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1790171958195, onlineIssueDateStr=2026-09-23, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1790171958195, creator=13701087609, updateTime=1790171958195, updator=13701087609, issue=Issue{id=1309639371255542472, tenantId=1146029695717560320, journalId=1146119893612605453, year='2025', volume='43', issue='11', pageStart='1421', pageEnd='1562', issueExtLink='null', onlineDate='null', pubDate='1763568000000', pubDateStr='2025-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1790171958030, creator='13701087609', updateTime=1790231751141, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1309890161824063505, tenantId=1146029695717560320, journalId=1146119893612605453, issueId=1309639371255542472, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1309890161824063506, tenantId=1146029695717560320, journalId=1146119893612605453, issueId=1309639371255542472, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1421, endPage=1427, ext={EN=ArticleExt(id=1309639372123759230, articleId=1309639371951792765, tenantId=1146029695717560320, journalId=1146119893612605453, language=EN, title=Preparation of phenolic compounds from straw pyrolysis volatiles through activated carbon catalytic reforming, columnId=null, journalTitle=Renewable Energy Resources, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Activated carbon was used as catalyst for the catalytic reforming of straw biomass (soybean straw, corn stalk) pyrolysis volatiles to phenolic compounds. The effect of catalysts on the yield, composition, and phenolic compound content of liquid products was investigated, and the catalytic mechanism of the catalysts was analyzed. The results showed that, after the catalytic reforming of volatiles by activated carbon, the liquid decreased in the products while the gas increased. The liquid yields of soybean straw and corn stalk were the highest at the pyrolysis temperature of 500 ℃, reaching 43.9% and 42.9%, respectively. After their volatiles were catalytically reformed by activated carbon, the liquid product yields were decreased to 30.1% and 37.9%, respectively. However, after catalytic reforming of volatiles, the aliphatics in the liquid products decreased while the aromatics increased. When the pyrolysis temperature was 500 ℃, the aromatic compounds in the soybean straw and corn stalk pyrolysis liquid products were increased by 10.0% and 9.7%, respectively. The content of phenolic compounds in the liquid products increased significantly, and the relative content of phenolic compounds reached 42.9% and 55.1%, respectively.

, authors=Feng Huang, Jing Xu, Jinxiao Dou, Jianglong Yu, authorsList=Feng Huang, Jing Xu, Jinxiao Dou, Jianglong Yu, authorCompany=null, correspAuthors=Jinxiao Dou, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1309639372312502911, articleId=1309639371951792765, tenantId=1146029695717560320, journalId=1146119893612605453, language=CN, title=活性炭催化重整秸秆热解挥发分制酚类化合物, columnId=0, journalTitle=可再生能源, columnName=, runingTitle=null, highlight=null, articleAbstract=

文章以活性炭为催化剂,催化秸秆类生物质(大豆秸秆、玉米秸秆)热解挥发分重整制酚类化合物,研究了催化剂对液体产物产率、液体产物组成及液体产物中酚类化合物含量的影响规律,并分析了催化剂的催化机理。研究结果表明:秸秆类生物质热解挥发分经活性炭催化重整后,气体产物产率增加、液体产物产率减小;当热解温度为500 ℃时,大豆秸秆和玉米秸秆热解的液体产物产率最大,分别为43.9%和42.9%,挥发分经活性炭催化重整后,液体产物产率分别降至30.1%和37.9%;但热解挥发分经催化重整后,液体产物中的脂肪族化合物占比降低,芳香族化合物占比升高,当热解温度为500 ℃时,大豆秸秆和玉米秸秆热解液体产物中芳香族化合物的相对含量分别增加了10.0%和9.7%,液体产物中酚类化合物的占比明显升高,最高相对含量分别达到42.9%和55.1%。

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黄峰(1982-),女,博士,副教授,主要从事煤和生物质热化学转化提质方面的研究。E-mail:

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窦金孝(1986-),男,博士,副教授,硕士生导师,主要从事煤和生物质的综合利用技术研究。E-mail:
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活性炭催化重整秸秆热解挥发分制酚类化合物
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黄峰 , 徐静 , 窦金孝 , 余江龙
可再生能源 | 2025,43(11): 1421-1427
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可再生能源 | 2025 , 43 (11) : 1421 -1427
活性炭催化重整秸秆热解挥发分制酚类化合物
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黄峰 , 徐静, 窦金孝 , 余江龙
作者信息
  • 辽宁科技大学 化学工程学院,先进煤焦化技术辽宁省重点实验室,辽宁 鞍山 114051
通讯作者:
窦金孝(1986-),男,博士,副教授,硕士生导师,主要从事煤和生物质的综合利用技术研究。E-mail:
作者简介:

黄峰(1982-),女,博士,副教授,主要从事煤和生物质热化学转化提质方面的研究。E-mail:

Preparation of phenolic compounds from straw pyrolysis volatiles through activated carbon catalytic reforming
Feng Huang , Jing Xu, Jinxiao Dou , Jianglong Yu
Affiliations
  • Key Laboratory for Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
出版时间: 2025-11-20
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文章以活性炭为催化剂,催化秸秆类生物质(大豆秸秆、玉米秸秆)热解挥发分重整制酚类化合物,研究了催化剂对液体产物产率、液体产物组成及液体产物中酚类化合物含量的影响规律,并分析了催化剂的催化机理。研究结果表明:秸秆类生物质热解挥发分经活性炭催化重整后,气体产物产率增加、液体产物产率减小;当热解温度为500 ℃时,大豆秸秆和玉米秸秆热解的液体产物产率最大,分别为43.9%和42.9%,挥发分经活性炭催化重整后,液体产物产率分别降至30.1%和37.9%;但热解挥发分经催化重整后,液体产物中的脂肪族化合物占比降低,芳香族化合物占比升高,当热解温度为500 ℃时,大豆秸秆和玉米秸秆热解液体产物中芳香族化合物的相对含量分别增加了10.0%和9.7%,液体产物中酚类化合物的占比明显升高,最高相对含量分别达到42.9%和55.1%。

秸秆  /  活性炭  /  催化重整  /  液体产物  /  酚类化合物

Activated carbon was used as catalyst for the catalytic reforming of straw biomass (soybean straw, corn stalk) pyrolysis volatiles to phenolic compounds. The effect of catalysts on the yield, composition, and phenolic compound content of liquid products was investigated, and the catalytic mechanism of the catalysts was analyzed. The results showed that, after the catalytic reforming of volatiles by activated carbon, the liquid decreased in the products while the gas increased. The liquid yields of soybean straw and corn stalk were the highest at the pyrolysis temperature of 500 ℃, reaching 43.9% and 42.9%, respectively. After their volatiles were catalytically reformed by activated carbon, the liquid product yields were decreased to 30.1% and 37.9%, respectively. However, after catalytic reforming of volatiles, the aliphatics in the liquid products decreased while the aromatics increased. When the pyrolysis temperature was 500 ℃, the aromatic compounds in the soybean straw and corn stalk pyrolysis liquid products were increased by 10.0% and 9.7%, respectively. The content of phenolic compounds in the liquid products increased significantly, and the relative content of phenolic compounds reached 42.9% and 55.1%, respectively.

straw  /  activated carbon  /  catalytic reforming  /  liquid products  /  phenolic compounds
黄峰, 徐静, 窦金孝, 余江龙. 活性炭催化重整秸秆热解挥发分制酚类化合物. 可再生能源, 2025 , 43 (11) : 1421 -1427 .
Feng Huang, Jing Xu, Jinxiao Dou, Jianglong Yu. Preparation of phenolic compounds from straw pyrolysis volatiles through activated carbon catalytic reforming[J]. Renewable Energy Resources, 2025 , 43 (11) : 1421 -1427 .
  • 辽宁省教育厅面上项目(JYTMS20230960)
  • 国家自然科学基金面上项目(22078141)
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  • 接收时间:2024-03-12
  • 首发时间:2026-09-23
  • 出版时间:2025-11-20
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  • 收稿日期:2024-03-12
基金
辽宁省教育厅面上项目(JYTMS20230960)
国家自然科学基金面上项目(22078141)
作者信息
    辽宁科技大学 化学工程学院,先进煤焦化技术辽宁省重点实验室,辽宁 鞍山 114051

通讯作者:

窦金孝(1986-),男,博士,副教授,硕士生导师,主要从事煤和生物质的综合利用技术研究。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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