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runingTitle=null, highlight=null, articleAbstract=以自制的硝酸锌共晶溶剂(nitro-DES)为硝化试剂,合成了Ag/g-C3N4光催化剂,在温和的非酸体系中与苯甲醚硝化反应制备得到二硝基苯甲醚(DNAN); 采用X射线粉末衍射(XRD)、紫外光漫反射光谱(UV-Vis DRS)、红外光谱(IR)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)与能量色散X射线(EDX)光谱等对Ag/g-C3N4光催化剂进行表征,并对光催化硝化制备二硝基苯甲醚(DNAN)的机理进行了预测。结果表明,以等摩尔比配制的硝酸锌与氯化胆碱可自发形成一种低熔点的透明极性溶剂,便于可见光能量的输入与传递,同时提供硝化反应的硝基来源; 贵金属的掺杂可显著提高C3N4的光催化活性,以氙灯模拟太阳光、反应温度为55℃、光照时间为3h,即可使90%以上苯甲醚转化为DNAN,根据自由基抑制实验,推测其中涉及氮氧自由基为中间体的硝化机理。, authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, 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硝酸锌共晶溶剂中光催化合成DNAN
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梁栋 , 樊晓欣 , 李柔静 , 李彦乐 , 朱泰胜 , 陈蓓 , 李永祥 , 朱娜
火炸药学报 | 2025,48(1):
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火炸药学报 2025 , 48 (1) :
硝酸锌共晶溶剂中光催化合成DNAN
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梁栋, 樊晓欣, 李柔静, 李彦乐, 朱泰胜, 陈蓓, 李永祥, 朱娜
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Photosynthesis of DNAN within Zinc Nitrate-containing Deep Eutectic Solvent
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以自制的硝酸锌共晶溶剂(nitro-DES)为硝化试剂,合成了Ag/g-C3N4光催化剂,在温和的非酸体系中与苯甲醚硝化反应制备得到二硝基苯甲醚(DNAN); 采用X射线粉末衍射(XRD)、紫外光漫反射光谱(UV-Vis DRS)、红外光谱(IR)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)与能量色散X射线(EDX)光谱等对Ag/g-C3N4光催化剂进行表征,并对光催化硝化制备二硝基苯甲醚(DNAN)的机理进行了预测。结果表明,以等摩尔比配制的硝酸锌与氯化胆碱可自发形成一种低熔点的透明极性溶剂,便于可见光能量的输入与传递,同时提供硝化反应的硝基来源; 贵金属的掺杂可显著提高C3N4的光催化活性,以氙灯模拟太阳光、反应温度为55℃、光照时间为3h,即可使90%以上苯甲醚转化为DNAN,根据自由基抑制实验,推测其中涉及氮氧自由基为中间体的硝化机理。
应用化学  /  共晶溶剂  /  DES  /  硝酸锌  /  二硝基苯甲醚  /  DNAN  /  光催化  /  g-C3N4  /  熔铸炸药
梁栋, 樊晓欣, 李柔静, 李彦乐, 朱泰胜, 陈蓓, 李永祥, 朱娜. 硝酸锌共晶溶剂中光催化合成DNAN. 火炸药学报, 2025 , 48 (1) .
. Photosynthesis of DNAN within Zinc Nitrate-containing Deep Eutectic Solvent[J]. Chinese Journal of Explosives & Propellants, 2025 , 48 (1) .

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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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