Article(id=1322944284147712765, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210283, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1618588800000, receivedDateStr=2021-04-17, revisedDate=1622304000000, revisedDateStr=2021-05-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344096457, onlineDateStr=2026-10-30, pubDate=1634659200000, pubDateStr=2021-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344096457, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344096457, creator=13701087609, updateTime=1793344096457, updator=13701087609, issue=Issue{id=1322942849381183980, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='10', pageStart='2045', pageEnd='2312', issueExtLink='null', onlineDate='null', pubDate='1634659200000', pubDateStr='2021-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343754382, creator='13701087609', updateTime=1793345931656, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951981580562527, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951981584756832, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2172, endPage=2179, ext={EN=ArticleExt(id=1322944285640884991, articleId=1322944284147712765, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Properties of Boron Doped Graphene-Based Mesoporous Carbon, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The boron-doped mesoporous carbon (BMCs) and boron-doped graphene-based mesoporous carbon (BMC/GO) were synthesized by a solvent evaporation-induced self-assembly method with block copolymer F127 as a soft template, boric acid as a boron source, phenolic resin prepolymer carbon sources and graphene-oxide (GO) as modifiers. The structures of the materials were characterized by transmission electronic microscopy, X-ray diffrication, nitrogen adsorption-desorption, and X-ray photoelectric microscopy. The electrochemical properties of samples were tested by electrochemical workstation. The structural characterization shows that the as-prepared composite material BMC/GO-40 (the mass of GO suspension is 40%) exhibits a great specific surface areas (i.e., 462.5 m²/g), and the average pore size is approximately 5 nm. The boron element mainly exists in the framework of mesoporous carbon in two forms, i.e., BC₃ bonding and BCO₂/BC₂O bonding. Based on the results by electrochemical tests, the maximum specific capacitance can be obtained via the addition of an appropriate amount of boron doping and the adjustment of the composite amount of graphene oxide. The capacity of BMC/GO-40 sample is 167 F/g at a current density of 0.5 A/g.

, authors=Qianni GUO, Yulong XIE, Faping YE, Lifang GUO, Cuoji BEN, authorsList=Qianni GUO, Yulong XIE, Faping YE, Lifang GUO, Cuoji BEN, authorCompany=null, correspAuthors=Yulong XIE, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322944285838017281, articleId=1322944284147712765, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=硼掺杂石墨烯基介孔碳的制备及性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

以酚醛树脂为碳前驱体，硼酸为硼源，三嵌段共聚物F127为软模板，氧化石墨烯为改性剂，通过溶剂挥发诱导自组装法制备了硼掺杂介孔碳（BMCs）以及硼掺杂石墨烯基介孔碳材料复合材料（BMC/GOs）。通过扫描电子显微镜、透射电子显微镜、X射线光电子能谱仪等研究硼掺杂及氧化石墨烯复合对介孔碳结构的影响，利用电化学工作站研究硼掺杂及氧化石墨烯复合对介孔碳性能的影响。测试结果表明，所制备的复合材料BMC/GO-40（氧化石墨烯悬浮液质量为40 mg）的比表面积为462.5 m²/g，平均孔径为5.52 nm。硼元素以BC₃键和BCO₂/BC₂O键的形式存在于介孔碳中。电化学测试表明，通过适量硼掺杂以及调整氧化石墨烯复合量可获得最大比电容。在电流密度为0.5 A/g，样品BMC/GO-40容量达167 F/g。

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郭倩妮（1995—），女，硕士研究生。

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