Article(id=1322944132754309341, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200967, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1608912000000, receivedDateStr=2020-12-26, revisedDate=1610294400000, revisedDateStr=2021-01-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344060362, onlineDateStr=2026-10-30, pubDate=1629388800000, pubDateStr=2021-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344060362, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344060362, creator=13701087609, updateTime=1793344060362, updator=13701087609, issue=Issue{id=1322942707957641522, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='8', pageStart='1519', pageEnd='1784', issueExtLink='null', onlineDate='null', pubDate='1629388800000', pubDateStr='2021-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343720664, creator='13701087609', updateTime=1793345848275, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951631859494962, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951631859494963, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1776, endPage=1784, ext={EN=ArticleExt(id=1322944134373310687, articleId=1322944132754309341, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

Collophanite fluorapatite particles were prepared as seed crystals with Ca2+ and F- ions, which were used to deeply purify low-concentration soluble inorganic phosphorus in water. The effects of combined reactants, reactant concentration, solution pH value and coexisting ions on the removal efficiency of phosphorus in water were investigated. To characterize the properties and clarify the mechanism of collophanite to remove soluble phosphates in water, the samples before and after pickling and phosphorus removal were characterized by scanning electron microscopy, transmission electron microscopy, thermoanalysis and Fourier transform infrared spectroscopy. Collophanite fluorapatite with calcium and fluorine exhibits the maximum phosphorus removal performance. The addition of Ca2+ ions significantly enhances the phosphorus removal efficiency, and F- ions with a low concentration have a slight effect on the phosphorus removal efficiency. Therefore, F- ions can be replaced by Ca2+ ions. When the initial concentration of phosphorus is 2 mg/L, pH value is > 6, and Ca2+ ions concentration is > 30 mg/L, the residual phosphorus concentration after the treatment is lower than 0.05 mg/L, thus meeting the Class Ⅱ standard of environmental tuality of water resource.

, authors=Linlin RU1, Tianhu CHEN1, Xuehua ZOU1, Dong CHEN1, Haibo LIU1, Yuhui LIU1, Shoucheng ZHU2, authorsList=Linlin RU, Tianhu CHEN, Xuehua ZOU, Dong CHEN, Haibo LIU, Yuhui LIU, Shoucheng ZHU, authorCompany=null, correspAuthors=Tianhu CHEN, authorNote=

RU Linlin (1997-), female, Master candidate. E-mail:

, correspAuthorsNote=
CHEN Tianhu (1962-), male, Ph. D, Professor. E-mail:
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以胶磷矿中氟磷灰石为晶种,外加Ca2+、F-源,通过磷灰石晶体加大生长的方式去除水中低浓度可溶性无机磷。实验考察了不同反应物组合、反应物浓度、溶液pH值、共存离子等因素对除磷效果的影响,并通过扫描电镜、透射电镜、热分析和红外光谱对胶磷矿除磷前后样品进行表征,查证胶磷矿固磷的机制。结果表明,磷灰石、Ca2+、F-三者共存除磷性能最佳,其中添加Ca2+对除磷效率有显著的增强作用,低浓度F-对提高除磷速率影响不大,可通过提高Ca2+浓度替代外加F-源的作用。当溶液中磷初始浓度为2 mg/L、pH值>6、Ca2+浓度不低于30 mg/L时,处理后残余磷浓度低于0.05 mg/L,满足地表水环境质量Ⅱ类标准。

, authors=汝琳琳1, 陈天虎1, 邹雪华1, 陈冬1, 刘海波1, 刘玉慧1, 朱守成2, authorsList=汝琳琳, 陈天虎, 邹雪华, 陈冬, 刘海波, 刘玉慧, 朱守成, authorCompany=null, correspAuthors=陈天虎, authorNote=

汝琳琳(1997—),女,硕士研究生。

, correspAuthorsNote=
陈天虎(1962—),男,博士,教授。
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胶磷矿氟磷灰石对水中低浓度磷的去除作用
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汝琳琳 1 , 陈天虎 1 , 邹雪华 1 , 陈冬 1 , 刘海波 1 , 刘玉慧 1 , 朱守成 2
硅酸盐学报 | 研究论文 2021,49(8): 1776-1784
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硅酸盐学报 |研究论文 2021 , 49 (8) : 1776 -1784
胶磷矿氟磷灰石对水中低浓度磷的去除作用
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汝琳琳1 , 陈天虎1 , 邹雪华1, 陈冬1, 刘海波1, 刘玉慧1, 朱守成2
作者信息
  • 1.合肥工业大学资源与环境工程学院,纳米矿物与污染控制安徽省重点实验室,合肥 230009
  • 2.污水净化与生态修复材料安徽省重点实验室,合肥 230009
通讯作者:
陈天虎(1962—),男,博士,教授。
作者简介:

汝琳琳(1997—),女,硕士研究生。

Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water
Linlin RU1 , Tianhu CHEN1 , Xuehua ZOU1, Dong CHEN1, Haibo LIU1, Yuhui LIU1, Shoucheng ZHU2
Affiliations
  • 1.Laboratory of Nano minerals and Environmental Materials, School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China
  • 2.Key Laboratory of Wastewater Purification and Ecological Restoration Materials in Anhui Province, Hefei 230009, China
  • Corresponding Author:
    CHEN Tianhu (1962-), male, Ph. D, Professor. E-mail:

    RU Linlin (1997-), female, Master candidate. E-mail:

出版时间: 2021-08-20 doi: 10.14062/j.issn.0454-5648.20200967
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以胶磷矿中氟磷灰石为晶种,外加Ca2+、F-源,通过磷灰石晶体加大生长的方式去除水中低浓度可溶性无机磷。实验考察了不同反应物组合、反应物浓度、溶液pH值、共存离子等因素对除磷效果的影响,并通过扫描电镜、透射电镜、热分析和红外光谱对胶磷矿除磷前后样品进行表征,查证胶磷矿固磷的机制。结果表明,磷灰石、Ca2+、F-三者共存除磷性能最佳,其中添加Ca2+对除磷效率有显著的增强作用,低浓度F-对提高除磷速率影响不大,可通过提高Ca2+浓度替代外加F-源的作用。当溶液中磷初始浓度为2 mg/L、pH值>6、Ca2+浓度不低于30 mg/L时,处理后残余磷浓度低于0.05 mg/L,满足地表水环境质量Ⅱ类标准。

胶磷矿  /  磷灰石  /  晶种  /  深度除磷  /  磷回收

Collophanite fluorapatite particles were prepared as seed crystals with Ca2+ and F- ions, which were used to deeply purify low-concentration soluble inorganic phosphorus in water. The effects of combined reactants, reactant concentration, solution pH value and coexisting ions on the removal efficiency of phosphorus in water were investigated. To characterize the properties and clarify the mechanism of collophanite to remove soluble phosphates in water, the samples before and after pickling and phosphorus removal were characterized by scanning electron microscopy, transmission electron microscopy, thermoanalysis and Fourier transform infrared spectroscopy. Collophanite fluorapatite with calcium and fluorine exhibits the maximum phosphorus removal performance. The addition of Ca2+ ions significantly enhances the phosphorus removal efficiency, and F- ions with a low concentration have a slight effect on the phosphorus removal efficiency. Therefore, F- ions can be replaced by Ca2+ ions. When the initial concentration of phosphorus is 2 mg/L, pH value is > 6, and Ca2+ ions concentration is > 30 mg/L, the residual phosphorus concentration after the treatment is lower than 0.05 mg/L, thus meeting the Class Ⅱ standard of environmental tuality of water resource.

collophanite  /  apatite  /  crystal seed  /  depth phosphorus removal  /  phosphorus recovery
汝琳琳, 陈天虎, 邹雪华, 陈冬, 刘海波, 刘玉慧, 朱守成. 胶磷矿氟磷灰石对水中低浓度磷的去除作用. 硅酸盐学报, 2021 , 49 (8) : 1776 -1784 . DOI: 10.14062/j.issn.0454-5648.20200967
Linlin RU, Tianhu CHEN, Xuehua ZOU, Dong CHEN, Haibo LIU, Yuhui LIU, Shoucheng ZHU. Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (8) : 1776 -1784 . DOI: 10.14062/j.issn.0454-5648.20200967
  • 国家自然科学基金项目(41072035; 41702043)
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2021年第49卷第8期
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doi: 10.14062/j.issn.0454-5648.20200967
  • 接收时间:2020-12-26
  • 首发时间:2026-10-30
  • 出版时间:2021-08-20
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  • 收稿日期:2020-12-26
  • 修回日期:2021-01-11
基金
国家自然科学基金项目(41072035; 41702043)
作者信息
    1.合肥工业大学资源与环境工程学院,纳米矿物与污染控制安徽省重点实验室,合肥 230009
    2.污水净化与生态修复材料安徽省重点实验室,合肥 230009

通讯作者:

陈天虎(1962—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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