Article(id=1322944123933687990, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200868, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1605715200000, receivedDateStr=2020-11-19, revisedDate=1608652800000, revisedDateStr=2020-12-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344058259, onlineDateStr=2026-10-30, pubDate=1629388800000, pubDateStr=2021-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344058259, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344058259, creator=13701087609, updateTime=1793344058259, updator=13701087609, issue=Issue{id=1322942707957641522, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='8', pageStart='1519', pageEnd='1784', issueExtLink='null', onlineDate='null', pubDate='1629388800000', pubDateStr='2021-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343720664, creator='13701087609', updateTime=1793345848275, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951631859494962, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951631859494963, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1527, endPage=1542, ext={EN=ArticleExt(id=1322944124898377911, articleId=1322944123933687990, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Alumina on Structure and Chemical Durability of Borosilicate Glasses, columnId=1322942708590981427, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Functional Glass, runingTitle=null, highlight=null, articleAbstract=

The effect of alumina (Al₂O₃) on the chemical durability of borosilicate glasses, 70SiO₂-(20-x)B₂O₃-_xAl₂O₃-10Na₂O, x=0, 5, 10, 15 and 20 (molar fraction), in water, HCl and NaOH aqueous solutions, was investigated via liquid resistance tests. The chemical stability of aluminoborosilicate glass was discussed based on the glass structure, and the mechanism of chemical attack in different solutions was proposed. The results show that a significant enhancement in the chemical durability in water, HCl and NaOH aqueous solutions occurs after the incorporation of Al³⁺ into the oxide glass network. The structural analysis indicates that the relatively low chemical durability of the glass as x=0 is correlated to the presence of BO₄ with three and four non-bridging oxygen (NBO) in the melts. Consequently, the glass is eroded more quickly during the attack of the aqueous solutions, resulting in a porous glass surface. The chemical durability can be improved due to the addition of Al₂O₃ into the glass network, suppressing the formation of BO₄.

, authors=A Ali MOHAMED¹, Xiaofeng LIU², Jianrong QIU¹, authorsList=A Ali MOHAMED, Xiaofeng LIU, Jianrong QIU, authorCompany=null, correspAuthors=Jianrong QIU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322944125607215288, articleId=1322944123933687990, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=氧化铝添加对硼硅酸盐结构和化学耐久性的影响, columnId=1322942708762947893, journalTitle=硅酸盐学报, columnName=功能玻璃专题, runingTitle=null, highlight=null, articleAbstract=

通过耐液性试验，研究了添加Al₂O₃对硼硅酸盐玻璃[70SiO₂-（20-x）B₂O₃-xAl₂O₃-10Na₂O，x=0、5、10、15、20，摩尔分数]的抗水、盐酸和氢氧化钠水溶液腐蚀性能的影响，讨论了铝硅酸盐玻璃在不同化学结构下的化学侵蚀机理。结果表明：在氧化玻璃网络中加入Al³⁺后，该玻璃在水、HCl和NaOH水溶液中的化学耐久性显著提高；不含Al₂O₃的玻璃化学耐久性较差与熔融玻璃中存在含3个和4个非桥氧（NBO）的BO₄有关，在水溶液侵蚀后，玻璃被更快地侵蚀，形成多孔玻璃表面。在非晶态玻璃网络中添加Al₂O₃，抑制了BO₄的生成，提高了材料的化学耐久性。

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MOHAMED A Ali (1987-), Ph. D.. E-mail: mohamedali@zju.edu.cn

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MOHAMED A Ali (1987-), Ph. D.. E-mail: mohamedali@zju.edu.cn

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Mohamed A Ali（1987-），博士。

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Mohamed A Ali（1987-），博士。

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