Article(id=1322944063967724524, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200880, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1606233600000, receivedDateStr=2020-11-25, revisedDate=1609776000000, revisedDateStr=2021-01-05, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344043962, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344043962, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344043962, creator=13701087609, updateTime=1793344043962, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1500, endPage=1509, ext={EN=ArticleExt(id=1322944066446558191, articleId=1322944063967724524, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Influence of Heat Theat Treatment Process on Properties of Al—In—Mg—SnCe Anode Material, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

An Al—In—Mg—Sn—Ce alloy anode was prepared. The effect of annealing condition on the electrochemistry properties of the alloy anode was analyzed via the measurements of hydrogen evolution rate, polarization curve, electrochemical impedance and constant current discharge. The microstructure and corrosion morphology of the alloy anode were determined by electron probe microanalyzer and scanning electron microscopy. The results show that the annealing treatment has a certain effect on the number and size of precipitates on the alloy surface, thus improving the electrochemical activity and corrosion resistance of the alloy anode. Also, the Al—In—Mg—Sn—Ce alloy anode material has an excellent discharge performance in an actual use process when the annealing condition is 350℃ and 6 h. Tthe energy density is the maximum value, and its energy density is 4 837.64 W·h/kg and 3 283.62 W·h/kg when the aluminum alloy anode is discharged at the current density of 40 mA/cm2 and 100 mA/cm2, respectively.

, authors=Tianyu ZHAO1, Gang XIE1, 2, 3, Yagang YANG1, Xiaohua YU1, Rongxing LI1, Yonggang LI4, Qingfeng SHEN1, authorsList=Tianyu ZHAO, Gang XIE, Yagang YANG, Xiaohua YU, Rongxing LI, Yonggang LI, Qingfeng SHEN, authorCompany=null, correspAuthors=Qingfeng SHEN, authorNote=

ZHAO Tianyu (1986-), male, Master candidate. E-mail:

, correspAuthorsNote=
SHEN Qingfeng (1971-), male, Ph.D., Lecturer. E-mail:
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制备了Al—In—Mg—Sn—Ce五元铝合金阳极,通过极化曲线(Tafel)、电化学阻抗(EIS)、自腐蚀速率、放电性能等研究手段,研究了不同热处理工艺对铝合金阳极电化学性能及自腐蚀性能的影响;用电子探针显微分析仪对合金放电后的元素成分和表面微观形貌进行检测,并探讨了热处理工艺对铝阳极组织结构的影响。结果表明,退火处理对冷轧过的合金表面析出物的数量和大小有一定影响,提高了铝合金的电化学活性和耐蚀性。此外,在350℃保温6 h的退火条件下,Al—In—Mg—Sn—Ce合金阳极材料在实际使用过程中具有出色的放电性能,与其他退火温度条件相比,相关的性能参数得到了极大的改善。350℃保温6 h退火条件下的铝合金阳极在40 mA/cm2和100 mA/cm2电流密度放电时,能量密度最高,其能量密度分别为4837.64 Wh/kg和3283.62 Wh/kg。

, authors=赵天宇1, 谢刚1, 2, 3, 杨亚刚1, 俞小花1, 李荣兴1, 李永刚4, 沈庆峰1, authorsList=赵天宇, 谢刚, 杨亚刚, 俞小花, 李荣兴, 李永刚, 沈庆峰, authorCompany=null, correspAuthors=沈庆峰, authorNote=

赵天宇(1995—),男,硕士研究生。

, correspAuthorsNote=
沈庆峰(1976—),男,博士,讲师。
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赵天宇(1995—),男,硕士研究生。

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赵天宇(1995—),男,硕士研究生。

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热处理工艺对Al—In—Mg—Sn—Ce阳极材料性能的影响
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赵天宇 1 , 谢刚 1, 2, 3 , 杨亚刚 1 , 俞小花 1 , 李荣兴 1 , 李永刚 4 , 沈庆峰 1
硅酸盐学报 | 研究论文 2021,49(7): 1500-1509
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硅酸盐学报 |研究论文 2021 , 49 (7) : 1500 -1509
热处理工艺对Al—In—Mg—Sn—Ce阳极材料性能的影响
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赵天宇1 , 谢刚1, 2, 3, 杨亚刚1, 俞小花1, 李荣兴1, 李永刚4, 沈庆峰1
作者信息
  • 1.昆明理工大学冶金与能源工程学院,昆明 650093
  • 2.昆明冶金研究院有限公司,昆明 650503
  • 3.共伴生有色金属资源加压湿法冶金技术国家重点实验室,昆明 650503
  • 4.云南铜业科技发展股份有限公司,昆明 650101
通讯作者:
沈庆峰(1976—),男,博士,讲师。
作者简介:

赵天宇(1995—),男,硕士研究生。

Influence of Heat Theat Treatment Process on Properties of Al—In—Mg—SnCe Anode Material
Tianyu ZHAO1 , Gang XIE1, 2, 3, Yagang YANG1, Xiaohua YU1, Rongxing LI1, Yonggang LI4, Qingfeng SHEN1
Affiliations
  • 1.Faculty of metallurgy and energy engineering, Kunming University of Science and Technology, Kunming 650093, China
  • 2.Kunming Metallurgical Research Institute Co., Ltd., Kunming 650503, China
  • 3.State key laboratory of Common associated non-ferrous metal resources pressure hydrometallurgy technology, Kunming 650503, China
  • 4.Yunnan Copper Technology Development Co. Ltd., Kunming, 650101, China
  • Corresponding Author:
    SHEN Qingfeng (1971-), male, Ph.D., Lecturer. E-mail:

    ZHAO Tianyu (1986-), male, Master candidate. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20200880
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制备了Al—In—Mg—Sn—Ce五元铝合金阳极,通过极化曲线(Tafel)、电化学阻抗(EIS)、自腐蚀速率、放电性能等研究手段,研究了不同热处理工艺对铝合金阳极电化学性能及自腐蚀性能的影响;用电子探针显微分析仪对合金放电后的元素成分和表面微观形貌进行检测,并探讨了热处理工艺对铝阳极组织结构的影响。结果表明,退火处理对冷轧过的合金表面析出物的数量和大小有一定影响,提高了铝合金的电化学活性和耐蚀性。此外,在350℃保温6 h的退火条件下,Al—In—Mg—Sn—Ce合金阳极材料在实际使用过程中具有出色的放电性能,与其他退火温度条件相比,相关的性能参数得到了极大的改善。350℃保温6 h退火条件下的铝合金阳极在40 mA/cm2和100 mA/cm2电流密度放电时,能量密度最高,其能量密度分别为4837.64 Wh/kg和3283.62 Wh/kg。

铝空气电池  /  热处理  /  铝阳极

An Al—In—Mg—Sn—Ce alloy anode was prepared. The effect of annealing condition on the electrochemistry properties of the alloy anode was analyzed via the measurements of hydrogen evolution rate, polarization curve, electrochemical impedance and constant current discharge. The microstructure and corrosion morphology of the alloy anode were determined by electron probe microanalyzer and scanning electron microscopy. The results show that the annealing treatment has a certain effect on the number and size of precipitates on the alloy surface, thus improving the electrochemical activity and corrosion resistance of the alloy anode. Also, the Al—In—Mg—Sn—Ce alloy anode material has an excellent discharge performance in an actual use process when the annealing condition is 350℃ and 6 h. Tthe energy density is the maximum value, and its energy density is 4 837.64 W·h/kg and 3 283.62 W·h/kg when the aluminum alloy anode is discharged at the current density of 40 mA/cm2 and 100 mA/cm2, respectively.

aluminum-air battery  /  heat treatment  /  aluminum anode
赵天宇, 谢刚, 杨亚刚, 俞小花, 李荣兴, 李永刚, 沈庆峰. 热处理工艺对Al—In—Mg—Sn—Ce阳极材料性能的影响. 硅酸盐学报, 2021 , 49 (7) : 1500 -1509 . DOI: 10.14062/j.issn.0454-5648.20200880
Tianyu ZHAO, Gang XIE, Yagang YANG, Xiaohua YU, Rongxing LI, Yonggang LI, Qingfeng SHEN. Influence of Heat Theat Treatment Process on Properties of Al—In—Mg—SnCe Anode Material[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1500 -1509 . DOI: 10.14062/j.issn.0454-5648.20200880
  • 国家自然科学基金面上项目:铝空气电池合金阳极电化学性能研究(51774160)
  • 云南省科技人才和平台计划项目(2017HA012)
  • 云南省万人计划(YNWR-QNBJ-2018-327)
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2021年第49卷第7期
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doi: 10.14062/j.issn.0454-5648.20200880
  • 接收时间:2020-11-25
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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  • 收稿日期:2020-11-25
  • 修回日期:2021-01-05
基金
国家自然科学基金面上项目:铝空气电池合金阳极电化学性能研究(51774160)
云南省科技人才和平台计划项目(2017HA012)
云南省万人计划(YNWR-QNBJ-2018-327)
作者信息
    1.昆明理工大学冶金与能源工程学院,昆明 650093
    2.昆明冶金研究院有限公司,昆明 650503
    3.共伴生有色金属资源加压湿法冶金技术国家重点实验室,昆明 650503
    4.云南铜业科技发展股份有限公司,昆明 650101

通讯作者:

沈庆峰(1976—),男,博士,讲师。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200880
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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