Article(id=1322943847612940757, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200640, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1598630400000, receivedDateStr=2020-08-29, revisedDate=1604332800000, revisedDateStr=2020-11-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343992269, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343992269, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343992269, creator=13701087609, updateTime=1793343992269, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1078, endPage=1090, ext={EN=ArticleExt(id=1322943848787345878, articleId=1322943847612940757, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Synthesis and Modification of Prussian Blue Analogue as Cathode Material for Sodium Ion Battery, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Studies on sodium-ion battery originated from the 1970s and 1980s, but it has not been paid much attention due to its low energy density. With the increasing shortage of lithium resources and the rising cost of lithium-ion battery preparation, sodium ion battery becomes a hot spot in the field of energy storage due to the abundant sodium resources, high energy conversion efficiency, long cycle life and good safety performance. Prussian blue analogues (PBAs) have excellent sodium storage properties due to their unique open framework structure, abundant sodium storage sites and large sodium ion migration channels. However, crystal water and structural defects are easy to occur in the synthesis process, leading to the decline of electrochemical properties. The structure and electrochemical characteristics of PBAs were introduced, and the preparation and modification methods were represented. In addition, the future development of PBAs as acathode for sodium ion battery was also prospected.

, authors=Cheng WEI1, Ningbo JIANG1, Lulu ZHANG1, 2, Xuelin YANG1, 2, authorsList=Cheng WEI, Ningbo JIANG, Lulu ZHANG, Xuelin YANG, authorCompany=null, correspAuthors=Lulu ZHANG, Xuelin YANG, authorNote=

WEI Cheng (1996-), female, Master candidate. E-mail:

, correspAuthorsNote=
ZHANG Lulu (1975-), female, Ph.D., Professor; E-mail:
YANG Xuelin (1973-), male, Ph.D., Professor.
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随着锂资源的日益紧缺,钠离子电池因具有钠资源丰富、能量转换效率高、循环寿命长、安全性能好等优势,又重新成为储能领域的研究热点。普鲁士蓝类化合物由于其独特的开放框架结构、丰富的储钠位点及较大的钠离子迁移通道,表现出优异的储钠性能。但该类材料在合成过程中容易产生结晶水及结构缺陷,导致材料电化学性能的显著下降。主要介绍了普鲁士蓝类化合物的结构特征及其电化学特性,综述了普鲁士蓝类化合物的制备及改性方法,并对其作为钠离子电池正极材料的未来发展进行了展望。

, authors=魏程1, 江宁波1, 张露露1, 2, 杨学林1, 2, authorsList=魏程, 江宁波, 张露露, 杨学林, authorCompany=null, correspAuthors=张露露, 杨学林, authorNote=

魏程(1996—),女,硕士研究生。

, correspAuthorsNote=
张露露(1975—),女,博士,教授;
杨学林(1973—),男,博士,教授。
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普鲁士蓝类化合物作为钠离子电池正极材料的研究进展
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魏程 1 , 江宁波 1 , 张露露 1, 2 , 杨学林 1, 2
硅酸盐学报 | 2021,49(6): 1078-1090
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硅酸盐学报 | 2021 , 49 (6) : 1078 -1090
普鲁士蓝类化合物作为钠离子电池正极材料的研究进展
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魏程1 , 江宁波1, 张露露1, 2 , 杨学林1, 2
作者信息
  • 1.三峡大学材料与化工学院,湖北 宜昌 443002
  • 2.三峡大学电气与新能源学院,湖北省新能源微电网协同创新中心,湖北 宜昌 443002
通讯作者:
张露露(1975—),女,博士,教授;
杨学林(1973—),男,博士,教授。
作者简介:

魏程(1996—),女,硕士研究生。

Research Progress on Synthesis and Modification of Prussian Blue Analogue as Cathode Material for Sodium Ion Battery
Cheng WEI1 , Ningbo JIANG1, Lulu ZHANG1, 2 , Xuelin YANG1, 2
Affiliations
  • 1.College of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, Hubei, China
  • 2.College of Electrical Engineering & New Energy, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang 443002, Hubei, China
  • Corresponding Author:
    ZHANG Lulu (1975-), female, Ph.D., Professor; E-mail:
    YANG Xuelin (1973-), male, Ph.D., Professor.

    WEI Cheng (1996-), female, Master candidate. E-mail:

出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200640
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随着锂资源的日益紧缺,钠离子电池因具有钠资源丰富、能量转换效率高、循环寿命长、安全性能好等优势,又重新成为储能领域的研究热点。普鲁士蓝类化合物由于其独特的开放框架结构、丰富的储钠位点及较大的钠离子迁移通道,表现出优异的储钠性能。但该类材料在合成过程中容易产生结晶水及结构缺陷,导致材料电化学性能的显著下降。主要介绍了普鲁士蓝类化合物的结构特征及其电化学特性,综述了普鲁士蓝类化合物的制备及改性方法,并对其作为钠离子电池正极材料的未来发展进行了展望。

钠离子电池  /  正极材料  /  普鲁士蓝类化合物

Studies on sodium-ion battery originated from the 1970s and 1980s, but it has not been paid much attention due to its low energy density. With the increasing shortage of lithium resources and the rising cost of lithium-ion battery preparation, sodium ion battery becomes a hot spot in the field of energy storage due to the abundant sodium resources, high energy conversion efficiency, long cycle life and good safety performance. Prussian blue analogues (PBAs) have excellent sodium storage properties due to their unique open framework structure, abundant sodium storage sites and large sodium ion migration channels. However, crystal water and structural defects are easy to occur in the synthesis process, leading to the decline of electrochemical properties. The structure and electrochemical characteristics of PBAs were introduced, and the preparation and modification methods were represented. In addition, the future development of PBAs as acathode for sodium ion battery was also prospected.

sodium ion battery  /  cathode material  /  Prussian blue analogues
魏程, 江宁波, 张露露, 杨学林. 普鲁士蓝类化合物作为钠离子电池正极材料的研究进展. 硅酸盐学报, 2021 , 49 (6) : 1078 -1090 . DOI: 10.14062/j.issn.0454-5648.20200640
Cheng WEI, Ningbo JIANG, Lulu ZHANG, Xuelin YANG. Research Progress on Synthesis and Modification of Prussian Blue Analogue as Cathode Material for Sodium Ion Battery[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1078 -1090 . DOI: 10.14062/j.issn.0454-5648.20200640
  • 国家自然科学基金(2072217; 51772169)
  • 国家重点研发计划(2018YFB0905400)
  • 湖北省技术创新专项重大项目(2019 AAA164)
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2021年第49卷第6期
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doi: 10.14062/j.issn.0454-5648.20200640
  • 接收时间:2020-08-29
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
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  • 收稿日期:2020-08-29
  • 修回日期:2020-11-03
基金
国家自然科学基金(2072217; 51772169)
国家重点研发计划(2018YFB0905400)
湖北省技术创新专项重大项目(2019 AAA164)
作者信息
    1.三峡大学材料与化工学院,湖北 宜昌 443002
    2.三峡大学电气与新能源学院,湖北省新能源微电网协同创新中心,湖北 宜昌 443002

通讯作者:

张露露(1975—),女,博士,教授;
杨学林(1973—),男,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200640
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2种不同金属材料的力学参数
科
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属数
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genus
种数
Number of
species
占总种数比例
Percentage of
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属
Genus
种数
Number of
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占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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