Article(id=1322943629823706025, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200827, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1604332800000, receivedDateStr=2020-11-03, revisedDate=1610121600000, revisedDateStr=2021-01-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343940453, onlineDateStr=2026-10-30, pubDate=1618848000000, pubDateStr=2021-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343940453, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343940453, creator=13701087609, updateTime=1793343940453, updator=13701087609, issue=Issue{id=1322942545734546372, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='4', pageStart='605', pageEnd='806', issueExtLink='null', onlineDate='null', pubDate='1618848000000', pubDateStr='2021-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343681986, creator='13701087609', updateTime=1793345524324, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950273110508350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950273110508351, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=648, endPage=658, ext={EN=ArticleExt(id=1322943631136523179, articleId=1322943629823706025, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Influence of La³⁺ Doping on Structure and Electrical Properties of CaBi₂Nb₂O₉ Piezoceramics, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

La³⁺-doped Ca_1-xLa_xBi₂Nb₂O₉(CBN-xLa, x=0.00, 0.02, 0.04, 0.06, 0.08, 0.10) piezoceramics were synthesized by a solid-state reaction method. The crystal structure, microstructure, dielectric, piezoelectric and ferroelectric properties as well as high-temperature conductive mechanism of La³⁺-doped CBN ceramics were investigated. The results show that an appropriate amount of La³⁺ donor ion substituted for Ca²⁺ ion can optimize the crystal structure, decrease the grain size, reduce the oxygen vacancy, and effectively improve the electrical properties of CBN ceramics. The Ca_0.92La_0.08Bi₂Nb₂O₉ ceramics with the optimal performance (high piezoelectric coefficient (d₃₃=11.7 pC/N) and the Curie temperature (T_C=905℃), remanent polarization (2P_r=9.51 μC/cm²) and low dielectric loss, (tanδ=3.87% at 550℃)). After annealing, the piezoelectric properties of all the samples remain stable at 800℃. According to the complex impedance plots, the grain boundary and grain both contribute the impedance, and the conduction mechanism is closely related to oxygen vacancies. Moreover, La³⁺-doping can effectively improve the resistivity of CBN ceramics at high temperatures, indicating a potential application in high-temperature sensors.

, authors=Liwei HUANG, Xiangping JIANG, Chao CHEN, Xiaokun HUANG, Xin NIE, Jingdong XU, Hepeng WANG, Zeyun JIANG, authorsList=Liwei HUANG, Xiangping JIANG, Chao CHEN, Xiaokun HUANG, Xin NIE, Jingdong XU, Hepeng WANG, Zeyun JIANG, authorCompany=null, correspAuthors=Xiangping JIANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943631866332076, articleId=1322943629823706025, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=La³⁺掺杂对CaBi₂Nb₂O₉压电陶瓷结构与电学性能的影响, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用传统固相法制备Ca_1-xLa_xBi₂Nb₂O₉（CBN-xLa，x=0.00，0.02，0.04，0.06，0.08，0.10）陶瓷，研究了La³⁺掺杂对CaBi₂Nb₂O₉陶瓷的晶体结构、微观形貌、介电性能、压电及铁电性能以及高温导电机制的影响。结果表明，适量的La³⁺取代Ca²⁺优化了晶体结构，细化晶粒，通过施主掺杂降低了氧空位，有效地改善了CaBi₂Nb₂O₉陶瓷的电性能。其中Ca_0.92La_0.08Bi₂Nb₂O₉是最优组分，获得压电性能d₃₃、Curie温度T_C和剩余极化强度2P_r分别为11.7 pC/N、905℃和9.51 μC/cm²，并且在550℃条件下的tanδ为3.87%，退火处理后，所有组分样品在800℃条件下均保持较稳定压电性能。复阻抗谱表明阻抗是由晶粒晶界共同作用，导电机制与氧空位有密切关系，且La³⁺能有效提高高温电阻率，使得其在高温传感器中具有应用潜力。

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HUANG Liwei (1994-), male, Master candidate. E-mail: 1842434276@qq.com

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